General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
expand_more
expand_more
format_list_bulleted
Concept explainers
Videos
Question
Chapter 5, Problem 5.110P
Interpretation Introduction
Interpretation:
The number of molecules and the number of moles present in the glass of 250 g of water are to be determined.
Concept introduction:
The total number of molecules is determined by the multiplication of the total number of moles with the number of a molecule present in a mole.
This relation is given as-
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
Theoretical
mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 5 Solutions
General, Organic, & Biological Chemistry
Ch. 5.1 - Use the molecular art to identify the process as a...Ch. 5.1 - Use the molecular art to identify the process as a...Ch. 5.1 - Label the reactants and products, and indicate how...Ch. 5.1 - One term in a balanced chemical equation contained...Ch. 5.2 - Write a balanced equation for each reaction....Ch. 5.2 - Write a balanced equation for the following...Ch. 5.2 - Write a balanced equation for the reaction of...Ch. 5.2 - Balance each chemical equation. Al+H2SO4Al2(...Ch. 5.3 - Write a balanced equation for the reaction...Ch. 5.3 - Classify each reaction as a combination or...
Ch. 5.3 - Classify each reaction as a single replacement or...Ch. 5.3 - Classify each reaction as a combination,...Ch. 5.3 - Fill in the needed reactants or products for each...Ch. 5.4 - Identify the species that is oxidized and the...Ch. 5.4 - Identify the species that is oxidized and the...Ch. 5.4 - Prob. 5.16PCh. 5.5 - How many items are contained in one mole of (a)...Ch. 5.5 - How many carbon atoms are contained in each of the...Ch. 5.5 - How many molecules are contained in each of the...Ch. 5.5 - How many moles of water contain each of the...Ch. 5.6 - Calculate the formula weight of each ionic...Ch. 5.6 - The unmistakable odor of a freshly cut cucumber is...Ch. 5.6 - Prob. 5.23PCh. 5.6 - Calculate the number of grams contained in each of...Ch. 5.6 - How many moles are contained in each of the...Ch. 5.6 - How many molecules are contained in two 500.-mg...Ch. 5.7 - Use the balanced equation for the reaction of N2...Ch. 5.7 - Use the balanced equation in Sample Problem 5.15...Ch. 5.8 - Prob. 5.29PCh. 5.8 - Using the balanced equation for the combustion of...Ch. 5.8 - Prob. 5.31PCh. 5.8 - Use the balanced equation, N2+O22NO, to answer the...Ch. 5.9 - Prob. 5.33PCh. 5.9 - Prob. 5.34PCh. 5.9 - The synthetic antiviral drug Tamiflu, currently...Ch. 5.10 - Consider the reaction of hydrogen and nitrogen to...Ch. 5.10 - Using the balanced equation for the reaction of H2...Ch. 5.10 - Using the balanced equation, 3H2(g)+N2(g)2NH3(g),...Ch. 5.10 - Using the balanced equation, N2(g)+O2(g)2NO(g),...Ch. 5.10 - Prob. 5.41PCh. 5.10 - Prob. 5.42PCh. 5 - Prob. 5.43PCh. 5 - Prob. 5.44PCh. 5 - How many atoms of each element are drawn on each...Ch. 5 - How many atoms of each element are drawn on each...Ch. 5 - Use the molecular art to write a balanced equation...Ch. 5 - Prob. 5.48PCh. 5 - Balance each equation. a....Ch. 5 - Balance each equation. a....Ch. 5 - Prob. 5.51PCh. 5 - Prob. 5.52PCh. 5 - Prob. 5.53PCh. 5 - Prob. 5.54PCh. 5 - For the reaction depicted in the molecular art:...Ch. 5 - Prob. 5.56PCh. 5 - Prob. 5.57PCh. 5 - Prob. 5.58PCh. 5 - Classify the reaction depicted in the molecular...Ch. 5 - Classify the reaction depicted in the molecular...Ch. 5 - Classify each reaction as combination,...Ch. 5 - Classify each reaction as combination,...Ch. 5 - Fill in the needed reactant or product for each of...Ch. 5 - Fill in the needed reactant or product for each of...Ch. 5 - Identify the species that is oxidized and the...Ch. 5 - Identify the species that is oxidized and the...Ch. 5 - Prob. 5.67PCh. 5 - Rechargeablenickel-cadmium batteries are used in...Ch. 5 - The reaction of hydrogen (H2) with acetylene...Ch. 5 - Prob. 5.70PCh. 5 - Calculate the formula weight and molar mass of...Ch. 5 - Calculate the formula weight and molar mass of...Ch. 5 - L-Dopa is a drug used to treat Parkinson’s...Ch. 5 - Niacin, vitamin B3, is found in soybeans, which...Ch. 5 - Which quantity has the greater mass? 1 mol of Fe...Ch. 5 - Prob. 5.76PCh. 5 - Mescaline is a hallucinogen in peyote, a cactus...Ch. 5 - Prob. 5.78PCh. 5 - How many grams are contained in 5.00 mol of each...Ch. 5 - How many grams are contained in 0.50 mol of each...Ch. 5 - Prob. 5.81PCh. 5 - How many moles are contained in each number of...Ch. 5 - Prob. 5.83PCh. 5 - Prob. 5.84PCh. 5 - Prob. 5.85PCh. 5 - Prob. 5.86PCh. 5 - Using the balanced equation for the combustion of...Ch. 5 - Sodium metal (Na) reacts violently when added to...Ch. 5 - Prob. 5.89PCh. 5 - Prob. 5.90PCh. 5 - What is the percent yield of B in a reaction that...Ch. 5 - What is the percent yield of B in a reaction that...Ch. 5 - The reaction of methane (CH4) with Cl2forms...Ch. 5 - Methanol (CH4O), which is used as a fuel in...Ch. 5 - Consider the given reaction mixture that contains...Ch. 5 - Consider the reaction of A2 and B2 to form A2B,...Ch. 5 - Prob. 5.97PCh. 5 - Prob. 5.98PCh. 5 - Prob. 5.99PCh. 5 - Prob. 5.100PCh. 5 - The local anesthetic ethyl chloride ( C2H5Cl,...Ch. 5 - The solvent dichloromethane (, molar mass 84.93...Ch. 5 - Answer the following questions about the...Ch. 5 - Answer the following questions about diethyl ether...Ch. 5 - Prob. 5.105PCh. 5 - Prob. 5.106PCh. 5 - Prob. 5.107PCh. 5 - Prob. 5.108PCh. 5 - Prob. 5.109PCh. 5 - Prob. 5.110PCh. 5 - DDT, a pesticide that kills disease-carrying...Ch. 5 - Prob. 5.112PCh. 5 - TCDD, also called dioxin...Ch. 5 - Prob. 5.114CP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Synthesis of ZybanⓇ: 1. Write a mechanism for the bromination of m-chloropropiophenone. Br₂ CH2Cl2 Cl Br 2. Give the expected m/z (to a round number) for the molecular ion from the product above (including isotopic peaks). 3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardSynthesis of Ibuprofen-Part 2: 1. Some pain relievers including ibuprofen (MotrinⓇ) and naproxen (Aleve®) are "α-arylpropanoic acids." Look up the structure of naproxen (AleveⓇ), another a-arylpropionic acid. Using the same reactions that we used for making ibuprofen, show how to make naproxen from the compound below. Show all intermediates and reagents in your synthesis. Show how you would prepare ibuprofen starting from p-isobutylbenzene rather than p-isobutylacetophenenone. What reaction steps would need to change/add? 3. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardAcid Catalyzed Aromatization of Carvone: 1. Starting with the ketone, below, draw a mechanism for the reaction to give the phenol as shown. H2SO4 HO- H₂O 2. Why do we use CDCl instead of CHCl, for acquiring our NMR spectra? 3. Why does it not matter which enantiomer of carvone is used for this reaction? What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forward
- Assign this H NMRarrow_forwardPlease complete these blanks need that asaparrow_forwardNitration of Methyl Benzoate: 1. Predict the major product for the reaction below AND provide a mechanism. Include ALL resonance structures for the intermediate. C(CH3)3 NO₂* ? 2. Assuming the stoichiometry is 1:1 for the reaction above, what volume of concentrated nitric acid would be required to mononitrate 0.50 grams of the compound above? What product(s) might you expect if you nitrated phenol instead of methyl benzoate? Explain your reasoning. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forward
- Sodium Borohydride Reduction (continued on the next page): 1. Draw the product of each of the reactions below and give the formula mass to the nearest whole number. ? (1) NaBH (2) acid (1) NaBD4 (2) acid ? 2. In mass spectra, alcohols typically break as shown in equation 8 in chapter 11 (refer to your lab manual). The larger group is generally lost and this gives rise to the base peak in the mass spectrum. For the products of each of the reactions in question # 1, draw the ion corresponding to the base peak for that product and give its mass to charge ratio (m/z). 3. Given the reaction below, calculate how many mg of 1-phenyl-1-butanol that can be produced using 31 mg NaBH4 and an excess of butyrophenone. 4. + NaBH4 OH (after workup with dilute HCI) What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardAspirin from Wintergreen: 1. In isolating the salicylic acid, why is it important to press out as much of the water as possible? Write a step-by-step mechanism for the esterification of salicylic acid with acetic anhydride catalyzed by concentrated H₂SO4. 3. Calculate the exact monoisotopic mass of aspirin showing your work. What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forwardSynthesis of Ibuprofen-Part 1: 1. What characteristic absorption band changes would you expect in the IR spectrum on going from p-isobutylacetophenone to 1-(4-isobutylphenyl)-ethanol and then to 1-(4-isobutylphenyl)-1-choroethane as you did in the experiment today? Give approximate wavenumbers associated with each functional group change. Given that the mechanism of the chlorination reaction today involves formation of a benzylic carbocation, explain why the following rearranged product is not formed. محرم محمد 3. Why do we use dilute HCl for the first step of the reaction today and concentrated HCI for the second step? What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What other impurities are present in your product and how do you know?arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
World of Chemistry, 3rd editionChemistryISBN:9781133109655Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCostePublisher:Brooks / Cole / Cengage Learning
Living By Chemistry: First Edition TextbookChemistryISBN:9781559539418Author:Angelica StacyPublisher:MAC HIGHER
ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage Learning
Introductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
World of Chemistry, 3rd edition
Chemistry
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Brooks / Cole / Cengage Learning
Living By Chemistry: First Edition Textbook
Chemistry
ISBN:9781559539418
Author:Angelica Stacy
Publisher:MAC HIGHER
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Introductory Chemistry: An Active Learning Approa...
Chemistry
ISBN:9781305079250
Author:Mark S. Cracolice, Ed Peters
Publisher:Cengage Learning
Step by Step Stoichiometry Practice Problems | How to Pass ChemistryMole Conversions Made Easy: How to Convert Between Grams and Moles; Author: Ketzbook;https://www.youtube.com/watch?v=b2raanVWU6c;License: Standard YouTube License, CC-BY