(a) Interpretation: The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn. Concept introduction: The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

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Answer 1

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

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Assign all the carbons

C 5 4 3 CI 2 the Righ B A 5 4 3 The Lich. OH 10 4 5 3 1 LOOP- -147.52 T 77.17 -45.36 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm B -126.25 77.03 200 190 180 170 160 150 140 130 120 110 100 90 80 70 60 50 40 30 20 10 ppm 200 190 180 170 160 150 140 130 120 110 100 90 80 TO LL <-50.00 70 60 50 40 30 20 10 ppm 45.06 30.18 -26.45 22.36 --0.00 45.07 7.5 1.93 2.05 -30.24 -22.36 C A 7 8 5 ° 4 3 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 1.0 ppm 9 8 5 4 3 ཡི་ OH 10 2 7.5 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 5 4 3 2 that th 7 I 7.0 6.5 6.0 5.5 5.0 4.5 4.0 3.5 3.0 2.5 2.0 1.5 115 2.21 4.00 1.0 ppm 6.96 2.76 5.01 1.0 ppm 6.30 1.00

Answer 2

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

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Answer 3

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

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Answer 4

Question

Definition Definition Chemical process in which one or more monomers combine to produce a very large chain-like molecule called a polymer. The functional groups present on the monomers and their steric effects are responsible for polymerization through a sequence of reactions that vary in complexity. There exists a stable covalent chemical bond between monomers that sets apart polymerization from other processes.

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

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Answer 5

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Answer 6

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Answer 7

Chapter 5, Problem 5.46AP

Interpretation Introduction

(a)

Interpretation:

The structure of polystyrene, the polymer obtained from the free-radical polymerization of styrene is to be drawn.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The way by which the structure of the polymer product differ from the one in part (a) if a few percent of 1,4−divinylbenzene is added in the mixture is to be stated.

Concept introduction:

The repeated bonding of monomer units lead to the formation of polymer. They are mainly synthesized through condensation or addition reaction of monomer units.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Prob. 5.3P Ch. 5 - Prob. 5.4P Ch. 5 - Prob. 5.5P Ch. 5 - Prob. 5.6P Ch. 5 - Prob. 5.7P Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that the structure of polystyrene, obtained from the free-radical polymerization, is shown in Figure 3.

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