Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 5, Problem 5.10P
Interpretation Introduction

(a)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(b)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(c)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

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The name of the parent six-membered sulfur-containing heterocycle is thiane. It is numbered beginning at sulfur. Multiple incorporation of sulfur in the ring is indicated by the prefixes di-, tri-, and so on. (a) How many methyl-substituted thianes are there? Which ones are chiral? (b) Write structural formulas for 1,4-dithiane and 1,3,5-trithiane. (c) Which dithiane isomer (1,2-, 1,3-, or 1,4-) is a disulfide?(d) Draw the two most stable conformations of the sulfoxide derived from thiane.
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