(a) Interpretation: The alkene and the method by which formation of given alcohol take place is to be predicted. Concept introduction: Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule. Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

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Answer 1

Question

Chapter 5, Problem 5.10P

Interpretation Introduction

(a)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(b)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(c)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

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The name of the parent six-membered sulfur-containing heterocycle is thiane. It is numbered beginning at sulfur. Multiple incorporation of sulfur in the ring is indicated by the prefixes di-, tri-, and so on. (a) How many methyl-substituted thianes are there? Which ones are chiral? (b) Write structural formulas for 1,4-dithiane and 1,3,5-trithiane. (c) Which dithiane isomer (1,2-, 1,3-, or 1,4-) is a disulfide?(d) Draw the two most stable conformations of the sulfoxide derived from thiane.

(a) How will you convert:(i) Benzene to acetophenone (ii) Propanone to 2-Methylpropan-2-ol(b) Give reasons :(i) Electrophilic substitution in benzoic acid takes place at meta position.(ii) Carboxylic acids are higher boiling liquids than aldehydes, ketones and alcohols of comparable molecular masses.(iii) Propanal is more reactive than propanone in nucleophilic addition reactions.

1. Deduce the structure of each compound from the information given. All unknowns in this problem have molecular formula C8H12. (a) Upon catalytic hydrogenation, unknown W gives cyclooctane. Ozonolysis of W, followed by reduction with dimethylsulfide, gives octanedioic acid, HOOC—(CH2)6—COOH. Draw the structure of W. (b) Upon catalytic hydrogenation, unknown X gives cyclooctane. Ozonolysis of X, followed by reduction with dimethyl sulfide, gives two equivalents of butanedial, O=CH—CH2CH2—CH=O. Draw the structure of X.

Answer 2

Question

Chapter 5, Problem 5.10P

Interpretation Introduction

(a)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(b)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(c)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

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Answer 3

Question

Chapter 5, Problem 5.10P

Interpretation Introduction

(a)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(b)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(c)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

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Answer 4

Question

Chapter 5, Problem 5.10P

Interpretation Introduction

(a)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(b)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(c)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

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Answer 5

Chapter 5, Problem 5.10P

Interpretation Introduction

(a)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(b)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Interpretation Introduction

(c)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Answer 6

Chapter 5, Problem 5.10P

Interpretation Introduction

(a)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Answer 7

Chapter 5, Problem 5.10P

Interpretation Introduction

(a)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The alkene and the method by which formation of given alcohol take place is to be predicted.

Concept introduction:

Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols. This type of reaction follows Markovnikov’s rule.

Hydroboration reaction is a two-step reaction, which involves conversion of alkene into alcohol. This type of reaction follows anti-Markovnikov’s rule.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 5 - Prob. 5.1P Ch. 5 - Prob. 5.2P Ch. 5 - Prob. 5.3P Ch. 5 - Prob. 5.4P Ch. 5 - Prob. 5.5P Ch. 5 - Prob. 5.6P Ch. 5 - Prob. 5.7P Ch. 5 - Prob. 5.8P Ch. 5 - Prob. 5.9P Ch. 5 - Prob. 5.10P

Solution Summary: The author explains that Oxymercuration-reduction is one of the methods used to convert alkenes into alcohols, and Hydroboration reaction is a two-step reaction.

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