Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 5, Problem 5.36AP
Interpretation Introduction

(a)

Interpretation:

The reason as to why the different condition of the given reaction gives different product distribution is to be stated.

Concept introduction:

The addition of one or more than one halogen atom in an alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this, the halogen is added to C=C the bond of the alkene to form haloalkane.

Interpretation Introduction

(b)

Interpretation:

The mechanisms for the formation of different products are to be predicted.

Concept introduction:

The addition of one or more than one halogen atom in an alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this, the halogen is added to C=C the bond of the alkene to form haloalkane.

Interpretation Introduction

(c)

Interpretation:

The condition that gives faster bromination reaction is to be identified.

Concept introduction:

The addition of one or more than one halogen atom in an alkene is known as halogenation reaction. The pathway of the halogenation reaction depends on the structure of the substrate. In this, the halogen is added to C=C the bond of the alkene to form haloalkane.

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(b) Addition of HBr to the alkene in the presence of peroxide form radical intermediates. Based on the following reaction, use the curved arrows to HBr B (preferred product) ROOR (i) show the initiation step of this reaction. (ii) draw the possible structures of the two radicals formed in the propagation step. (ii) explain the formation of the preferred product B.
Blackboard 个→ X乙 Show Timer * Question Completion Status: (b). The alkyl halide 1-bromo-1,2-dimethylcyclohexane (A) undergoes dehydrohalogenation reaction when treated with methanol (CH3OH) as a nucleophile give a mixture of products, alkenes B and C. When the concentration of the alkyl halide is doubled, the rate of the reaction is doubles; the rate of product formation also doubles. However, when the concentration of the ethanol is doubled, the rate of the reaction is not affected (i) What is the mechanism responsible for this elimination reaction? (ii) Write the equation for the rate of the reaction (ii) Draw the structure of alkyl halide A
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