Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Textbook Question
Chapter 4, Problem 27P
Write the structure(s) of the simplest
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Give an example of a 3,4-unsaturated aldehyde molecule with a total of 16 carbons, with at least one aromatic group and one alkyl group. Name this example you gave according to the IUPAC system.
Give the structural formula (condensed or skeletal) of the given IUPAC names of saturated hydrocarbons.
1) 2-methyl-3-oxohept-4-enoic acid
2) 4-chloro-2-oxohexanoyl chloride
3) 4-nitro-4-propoxybut-1-ene
4) 1-hydroxyhex-5-yn-2-one
5) 1-methylpropyl 3-amino-3-(1-methylpropoxy)propanoate
6) 1-ethoxy-3-mercaptohexane-2-thione
2. Write bond-line structural formulas for (a.) two primary alcohols, (b.) a secondary alcohol, and (c.) atertiary alcohol—all having the molecular formula C4H10O.
Chapter 4 Solutions
Organic Chemistry
Ch. 4 - Prob. 1PPCh. 4 - Which structure does not represent...Ch. 4 - Prob. 3PPCh. 4 - Draw bond-line formulas for all of the isomers of...Ch. 4 - Prob. 5PPCh. 4 - Draw bond-line formulas and give IUPAC...Ch. 4 - Draw bond-line formulas and give IUPAC...Ch. 4 - Practice Problem 4.8 Give names for the following...Ch. 4 - Prob. 9PPCh. 4 - Prob. 10PP
Ch. 4 - Prob. 11PPCh. 4 - Give the structures and IUPAC names for all the...Ch. 4 - Prob. 13PPCh. 4 - Practice Problem 4.14 Show by a calculation (using...Ch. 4 - Practice Problem 4.15 Write structures for the cis...Ch. 4 - Practice Problem 4.16
(a) Write structural...Ch. 4 - Practice Problem 4.17 Write a conformational...Ch. 4 - Practice Problem 4.18
(a) Write the two...Ch. 4 - Prob. 19PPCh. 4 - Practice Problem 4.20 (a) What is the index of...Ch. 4 - Practice Problem 4.21
Zingiberene, a fragrant...Ch. 4 - Practice Problem 4.22 Carbonyl groups also count...Ch. 4 - Prob. 23PCh. 4 - Give systematic IUPAC names for each of the...Ch. 4 - Prob. 25PCh. 4 - Write the structure and give the IUPAC systema.tic...Ch. 4 - 4.27. Write the structure(s) of the simplest...Ch. 4 - Prob. 28PCh. 4 - 4.29. Write structures for the following...Ch. 4 - Prob. 30PCh. 4 - A spiro ring junction is one where two rings that...Ch. 4 - 4.32. Tell what is meant by a homologous series...Ch. 4 - Four different cycloalkenes will all yield...Ch. 4 - 4.34. (a) Three different alkenes yield...Ch. 4 - Prob. 35PCh. 4 - Prob. 36PCh. 4 - 4.37. Write the structures of two chair...Ch. 4 - Prob. 38PCh. 4 - Without referring to tables, decide which member...Ch. 4 - Prob. 40PCh. 4 - 4.41. Which compound would you expect to be the...Ch. 4 - Prob. 42PCh. 4 - 4.43. Write the two chair conformations of each of...Ch. 4 - Provide an explanation for the surprising fact...Ch. 4 - Prob. 45PCh. 4 - 4.46. Specify the missing compounds and/or...Ch. 4 - Consider the cis and trans isomers of...Ch. 4 - Prob. 48PCh. 4 - Open the energy-minimized 3D Molecular Models on...Ch. 4 - 4.50. Open the 3D Molecular Models on the book’s...Ch. 4 - 4.51. Open the 3D Molecular Model on the book’s...Ch. 4 - 1. The predominant conformation for D-glucose is...Ch. 4 - Prob. 2LGPCh. 4 - When 1,2-dimethylcyclohexene is allowed to react...Ch. 4 - Prob. 4LGP
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- A saturated acyclic hydrocarbon has the molecular formula of CxH₂x2. A hydrocarbon can be classified as unsaturated if it has fewer hydrogens than a saturated formula would predict. Classify the following hydrocarbon skeletal structure as saturated or unsaturated. A) saturated B) unsaturatedarrow_forwardGive the structure of each of the following compounds. b) 1-butyl-4-propylcyclohexanearrow_forward4. Without consulting tables, arrange the following alkenes in order of increasing boiling point.arrow_forward
- 14. One way of naming ethers is to name the two alkyl groups attached to the oxygen atom in alphabetical order and add the word ether. If the two alkyl groups are the same, we use the prefix di-, for example, as in dimethyl ether. Write bond-line structural formulas for (a.) diethyl ether, (b.) ethyl propyl ether, and (c.) ethyl isopropyl ether. What name would give to OMe (d) (e) and (f) CH;OCGH5?arrow_forwardFUNCTIONAL GROUP IUPAC NAME STRUCTURAL FORMULA CH3 CH;CH;CH3 CH,CH, CH;CH, CH3 + CH2C – NH2 CH3arrow_forward2.) Draw 1 isomer of the compounds in item no. 3, and state the type of isomerism. Example: 2-hydroxy-pentanal OH Structure: Isomer: он Type of isomerism: Functional Isomerismarrow_forward
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- Give the structure and correct IUPAC name of each.arrow_forwardGive the structure corresponding to each IUPAC name (a) 3-ethyl-3-methyloctane (b) 2,3,4,5-tetramethyldecanearrow_forwardCharacterize EACH of the three given statements as being TRUE or FALSE and then indicate the collective true - false status of the statements using the choices. (1) Alcohols have higher boiling points than alkanes of similar molecular mass because of hydrogen bonding. (2) Polyols have similar boiling points to tertiary alcohols. (3) Primary and secondary alcohols give the same type of product when subjected to mild oxidizing agents. Group of answer choices All three statements are true. Two of the three statements are true. Only one of the statements is true. None of the statements are true.arrow_forward
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