Chemistry in Context
8th Edition
ISBN: 9780073522975
Author: American Chemical Society
Publisher: McGraw-Hill Education
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Chapter 3, Problem 8Q
Understanding Earth’s energy balance is essential to understanding the issue of global warming. For example, the solar energy striking Earth’s surface averages 168 watts per square meter (W/m2), but the energy leaving Earth’s surface averages 390 W/m2. Why isn’t Earth cooling rapidly?
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2 (g) + 3H2 (g) = 2NH3 (g) AG⁰ = -34. KJ
Now suppose a reaction vessel is filled with 8.06 atm of nitrogen (N2) and 2.58 atm of ammonia (NH3) at 106. °C. Answer the following questions about this
system:
?
rise
Under these conditions, will the pressure of N2 tend to rise or fall?
☐ x10
fall
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of N2 will tend to rise, can that be
changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of N2 will tend to fall, can that be changed to a tendency to rise
by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
☐
atm
☑
5
00.
18
Ar
Chapter 3 Solutions
Chemistry in Context
Ch. 3.1 - Prob. 3.3YTCh. 3.1 - You Decide Evaporating Coal Mines Writing in the...Ch. 3.2 - Prob. 3.6SCCh. 3.3 - Prob. 3.9YTCh. 3.4 - Prob. 3.10CTCh. 3.6 - Skill Building Isotopes of Nitrogen Nitrogen (N2)...Ch. 3.6 - You Decide Marshmallows and Pennies Avogadros...Ch. 3.7 - You Decide Checking Carbon from Cars A...Ch. 3.8 - Prob. 3.19YTCh. 3.8 - Prob. 3.20CT
Ch. 3.8 - Prob. 3.21CTCh. 3.9 - Prob. 3.22CTCh. 3.9 - Prob. 3.23YTCh. 3.9 - Prob. 3.24CTCh. 3.10 - Prob. 3.26CTCh. 3.10 - Prob. 3.27CTCh. 3.11 - Prob. 3.29CTCh. 3.11 - Prob. 3.30YTCh. 3.11 - Prob. 3.31YTCh. 3.11 - Prob. 3.32CTCh. 3.11 - You Decide Climate Change Insurance? Mitigation of...Ch. 3.11 - Prob. 3.34SCCh. 3.11 - Prob. 3.35CTCh. 3 - Prob. 3.1CTCh. 3 - The chapter concluded with a quote from John...Ch. 3 - Prob. 2QCh. 3 - Prob. 3QCh. 3 - Prob. 5QCh. 3 - a. It is estimated that 29 megajoules per square...Ch. 3 - Consider Figure 4.23. a. How does the present...Ch. 3 - Understanding Earths energy balance is essential...Ch. 3 - Explain each of these observations. a. A car...Ch. 3 - Prob. 10QCh. 3 - Draw the Lewis structure and name the molecular...Ch. 3 - Draw the Lewis structure and name the molecular...Ch. 3 - a. Draw the Lewis structure for methanol (wood...Ch. 3 - a. Draw the Lewis structure for ethene (ethylene),...Ch. 3 - Prob. 15QCh. 3 - Prob. 16QCh. 3 - Prob. 17QCh. 3 - Prob. 18QCh. 3 - Termites possess enzymes that allow them to break...Ch. 3 - Consider Figure 4.4. a. Which sector has the...Ch. 3 - Silver has an atomic number of 47. a. Give the...Ch. 3 - Silver only has two naturally occurring isotopes:...Ch. 3 - a. Calculate the average mass in grams of an...Ch. 3 - Prob. 24QCh. 3 - Prob. 25QCh. 3 - The total mass of carbon in living systems is...Ch. 3 - Prob. 27QCh. 3 - Prob. 28QCh. 3 - Prob. 29QCh. 3 - Prob. 30QCh. 3 - The Arctic has been called our canary in the coal...Ch. 3 - Do you think the comment made in the cartoon is...Ch. 3 - Prob. 33QCh. 3 - Prob. 34QCh. 3 - Over the last 20 years, about 120 billion tons of...Ch. 3 - Prob. 36QCh. 3 - Prob. 37QCh. 3 - Prob. 38QCh. 3 - Ethanol, C2H5OH, can be produced from sugars and...Ch. 3 - Prob. 40QCh. 3 - Prob. 41QCh. 3 - Prob. 42QCh. 3 - Prob. 43QCh. 3 - Prob. 44QCh. 3 - Prob. 45QCh. 3 - Prob. 46QCh. 3 - Prob. 47QCh. 3 - Prob. 48QCh. 3 - Prob. 49QCh. 3 - Prob. 50QCh. 3 - Former vice president Al Gore writes in his 2006...Ch. 3 - Prob. 52QCh. 3 - Prob. 53QCh. 3 - Data taken over time reveal an increase in CO2 in...Ch. 3 - In the energy industry, 1 standard cubic foot...Ch. 3 - Prob. 56QCh. 3 - A solar oven is a low-tech, low-cost device for...Ch. 3 - In 2005, the European Union adopted a...Ch. 3 - The world community responded differently to the...
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- i need help with the followingarrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NO(g) +Cl₂ (g) = 2NOC1 (g) AGº = -41. kJ Now suppose a reaction vessel is filled with 8.90 atm of chlorine (C12) and 5.71 atm of nitrosyl chloride (NOC1) at 1075. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. atm ☑ 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HCN is a weak acid. acids: 0.29 mol of NaOH is added to 1.0 L of a 1.2M HCN solution. bases: ☑ other: 0.09 mol of HCl is added to acids: 1.0 L of a solution that is bases: 0.3M in both HCN and KCN. other: 0,0,... ? 00. 18 Ar 日arrow_forward
- Identifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: 0.2 mol of KOH is added to 1.0 L of a 0.5 M HF solution. bases: Х other: ☐ acids: 0.10 mol of HI is added to 1.0 L of a solution that is 1.4M in both HF and NaF. bases: other: ☐ 0,0,... ด ? 18 Ararrow_forwardIdentifying the major species in weak acid or weak base equilibria The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that NH3 is a weak base. acids: ☐ 1.8 mol of HCl is added to 1.0 L of a 1.0M NH3 bases: ☐ solution. other: ☐ 0.18 mol of HNO3 is added to 1.0 L of a solution that is 1.4M in both NH3 and NH₁Br. acids: bases: ☐ other: ☐ 0,0,... ? 000 18 Ar B 1arrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NH3 (g) = N2 (g) +3H₂ —N2 (g) AGº = 34. kJ Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this system: rise Under these conditions, will the pressure of NH 3 tend to rise or fall? ☐ x10 fall Х Is it possible to reverse this tendency by adding H₂? In other words, if you said the pressure of NH 3 will tend to rise, can that be changed to a tendency to fall by adding H₂? Similarly, if you said the pressure of NH3 will tend to fall, can that be changed to a tendency to rise by adding H₂? If you said the tendency can be reversed in the second question, calculate the minimum pressure of H₂ needed to reverse it. Round your answer to 2 significant digits. yes no atm 00. 18 Ar 무ㅎ ?arrow_forward
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- Identifying the major species in weak acid or weak base equilibria Your answer is incorrect. • Row 2: Your answer is incorrect. • Row 3: Your answer is incorrect. • Row 6: Your answer is incorrect. 0/5 The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at equilibrium. You can leave out water itself. Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the formulas of the species that will act as neither acids nor bases in the 'other' row. You will find it useful to keep in mind that HF is a weak acid. acids: HF 0.1 mol of NaOH is added to 1.0 L of a 0.7M HF solution. bases: 0.13 mol of HCl is added to 1.0 L of a solution that is 1.0M in both HF and KF. Exponent other: F acids: HF bases: F other: K 1 0,0,... ? 000 18 Ararrow_forwardUsing reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ararrow_forwardHighlight each glycosidic bond in the molecule below. Then answer the questions in the table under the drawing area. HO- HO- -0 OH OH HO NG HO- HO- OH OH OH OH NG OHarrow_forward
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