Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Textbook Question
Chapter 3, Problem 89E
Energy conservationists suggest that air conditioners should be set so that they do not turn on until the temperature tops 78 °F. What is the Celsius equivalent of this temperature?
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Don't used hand raiting
Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Chapter 3 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 3 - Equivalency, conversion factor, solving...Ch. 3 - Metric system, SI units, derived unit, base unitCh. 3 - Prob. 3CLECh. 3 - Prob. 4CLECh. 3 - Prob. 5CLECh. 3 - Write the following numbers in scientific...Ch. 3 - Prob. 2ECh. 3 - Write the following numbers in ordinary decimal...Ch. 3 - Write the ordinary form of the following numbers:...Ch. 3 - Prob. 5E
Ch. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Complete the following operations:...Ch. 3 - Prob. 12ECh. 3 - What is the mathematical criterion for two...Ch. 3 - Sixty seconds and minute are equivalent...Ch. 3 - Write the equivalency for each conversion...Ch. 3 - Write the equivalency for each conversion...Ch. 3 - Write the equivalency and both conversion factors...Ch. 3 - Write the equivalency and both conversion factors...Ch. 3 - Prob. 19ECh. 3 - Prob. 20ECh. 3 - How long will it take to travel the 406 miles...Ch. 3 - A student who is driving home for the holidays...Ch. 3 - How many minutes does it take a car traveling 88...Ch. 3 - How many days are in 89 weeks?Ch. 3 - What will be the cost in dollars for nails for a...Ch. 3 - A student working for Stop and Shop is packing...Ch. 3 - An American tourist in Mexico was startled to see...Ch. 3 - How many nickels should you receive in exchange...Ch. 3 - How many weeks are in a decade?Ch. 3 - How many seconds are in the month of January?Ch. 3 - List at least two measurements that would be...Ch. 3 - List at least two measurements that would be made...Ch. 3 - A woman stands on a scale in an elevator in a tall...Ch. 3 - A person can pick up a large rock that is...Ch. 3 - What is the metric unit of length?Ch. 3 - What is the metric unit of mass?Ch. 3 - Kilo buck is a slang expression for a sum of...Ch. 3 - What is the difference between the terms kilo unit...Ch. 3 - One milliliter is equal to how many liters?Ch. 3 - How many centimeters are in a meter?Ch. 3 - Which unit, megagrams or grams, would be more...Ch. 3 - What is the name of the unit whose symbol is nm?...Ch. 3 - a 5.74 cg to g, b 1.41 kg to g, c 4.54 x 108 cg to...Ch. 3 - a 15.3 kg to g and mg, b 80.5 g to kg and mg, c...Ch. 3 - a 21.7 m to cm, b 517 m to km, c 0.666 km to cmCh. 3 - a 90.4 mm to m and cm, b 11.9 m to mm and cm, c...Ch. 3 - a 494 cm3 to mL, b 1.91 L to mL, c 874 cm3 to LCh. 3 - a 90.8 mL to L and cm3, b 16.9 L to mL and cm3, c...Ch. 3 - a 7.11 hg to g, b 5.27 x 107 m to pm, c 3.63 x 106...Ch. 3 - a 0.194 Gg to g, b 5.66 nm to m, c 0.00481 Mm to...Ch. 3 - State the volume of liquid in each graduated...Ch. 3 - How long is the object measured with the rulers...Ch. 3 - The same volume of liquid is in each measuring...Ch. 3 - Why is the length of the line in the illustration...Ch. 3 - Prob. 55ECh. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - a 52.20 mL helium, b 17.963 g nitrogen, c 78.45 mg...Ch. 3 - A moving-van crew picks up the following items: a...Ch. 3 - A solution is prepared by dissolving 2.86 grams of...Ch. 3 - Prob. 61ECh. 3 - An empty beaker has a mass of 94.33 grams. After...Ch. 3 - The mole is the SI unit for the amount of a...Ch. 3 - Exactly 1 liter of a solution contains 31.4 grams...Ch. 3 - An empty beaker with a mass of 42.3 g is filled...Ch. 3 - Use the definition density ; mass 4 volume to...Ch. 3 - 0.0715 gal = _____ c m 3 2.27 x 10 4 mL = _____ g...Ch. 3 - 19.3 L = _____ gal 0 .461 qt = _____ LCh. 3 - A popular breakfast cereal comes in a box...Ch. 3 - A copy of your chemistry textbook is found to have...Ch. 3 - The payload of a small pickup truck is 1450 pounds...Ch. 3 - The Hope diamond is the worlds largest blue...Ch. 3 - There is 115 mg of calcium in a 100-g serving of...Ch. 3 - The largest recorded difference of weight between...Ch. 3 - An Austrian boxer reads 69.1 kg when he steps on a...Ch. 3 - A woman gives birth to a 7.5-lb baby. How would a...Ch. 3 - The height of Angel Falls in Venezuela is 979 m....Ch. 3 - A penny is found to have a length of 1.97...Ch. 3 - The Willis Tower in Chicago is 1451 feet tall. How...Ch. 3 - What is the length of the Mississippi River in...Ch. 3 - The summit of Mount Everest is 29, 029 ft above...Ch. 3 - One of the smallest brilliant-cut diamonds ever...Ch. 3 - An office building is heated by oil-fired burners...Ch. 3 - A gas can is found to have a volume of 9.10...Ch. 3 - Celsius Fahrenheit Kelvin 69 -29 111 36 358 -141Ch. 3 - Celsius Fahrenheit Kelvin 40 590 -13 229 440 -314Ch. 3 - Normal body temperature is 98.6 F. What is this...Ch. 3 - In the winter, a heated home in the Northeast...Ch. 3 - Energy conservationists suggest that air...Ch. 3 - The milting point of an unknown solid is...Ch. 3 - The worlds highest shade temperature was recorded...Ch. 3 - The boiling point of a liquid is calculated to be...Ch. 3 - Prob. 93ECh. 3 - Prob. 94ECh. 3 - Prob. 95ECh. 3 - Prob. 96ECh. 3 - Prob. 97ECh. 3 - Prob. 98ECh. 3 - Prob. 99ECh. 3 - Prob. 100ECh. 3 - Prob. 101ECh. 3 - Rank the substances in the photograph from least...Ch. 3 - Calculate the density of benzene, a liquid used in...Ch. 3 - A general chemistry student found a chunk of metal...Ch. 3 - Densities of gases are usually measured in grams...Ch. 3 - Prob. 106ECh. 3 - Ether, a well-known anesthetic, has a density of...Ch. 3 - Prob. 108ECh. 3 - Determine the mass of 2.0 L rubbing alcohol, which...Ch. 3 - Calculate the volume occupied by 15.4 grams of...Ch. 3 - The mass of the liquid in the graduated cylinder...Ch. 3 - Prob. 112ECh. 3 - Distinguish precisely and in scientific terms the...Ch. 3 - Determine whether each statement that follows is...Ch. 3 - How tall are you in a meters; b decimeters; c...Ch. 3 - What do you weigh in a milligrams; b grams; c...Ch. 3 - Standard printer and copier paper is the United...Ch. 3 - The density of aluminium is 2.7 g/cm3. An ecology...Ch. 3 - What is the average density of a single marble...Ch. 3 - A woman has just given birth to a bouncing 6 lb, 7...Ch. 3 - A students drivers license lists her height as 5...Ch. 3 - How many grams of milk are in a 12.0 fluid-ounce...Ch. 3 - The fuel tank in an automobile has a capacity of...Ch. 3 - A welcome rainfall caused the temperature to drop...Ch. 3 - At high noon on the lunar equator the temperature...Ch. 3 - A recipe calls for a quarter cup of butter....Ch. 3 - Prob. 127ECh. 3 - In Active Example 3-29 you calculated that you...Ch. 3 - Write each of the following in scientific...Ch. 3 - Write each of the following numbers in ordinary...Ch. 3 - Prob. 3PECh. 3 - Prob. 4PECh. 3 - How many seconds are in 12 minutes?Ch. 3 - Prob. 6PECh. 3 - Prob. 7PECh. 3 - Prob. 8PECh. 3 - Prob. 9PECh. 3 - Prob. 10PECh. 3 - Prob. 11PECh. 3 - Prob. 12PECh. 3 - What is the volume of liquid in the buret in the...Ch. 3 - Prob. 14PECh. 3 - Round off each of the following quantities to two...Ch. 3 - Prob. 16PECh. 3 - At a certain temperature, 0.878 g of a pure liquid...Ch. 3 - Prob. 18PECh. 3 - Prob. 19PECh. 3 - Prob. 20PECh. 3 - Prob. 21PECh. 3 - Prob. 22PECh. 3 - Prob. 23PECh. 3 - Prob. 24PECh. 3 - The mass of a 50.00-milliliter sample of methanol...Ch. 3 - Prob. 26PECh. 3 - Determine the mass in kilograms of a lead brick...Ch. 3 - Prob. 28PECh. 3 - Prob. 29PE
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