Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Textbook Question
Chapter 3, Problem 52E
How long is the object measured with the rulers shown? The ruler is calibrated in inches. Explain why you selected the number of digits in your length values.
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Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
Chapter 3 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 3 - Equivalency, conversion factor, solving...Ch. 3 - Metric system, SI units, derived unit, base unitCh. 3 - Prob. 3CLECh. 3 - Prob. 4CLECh. 3 - Prob. 5CLECh. 3 - Write the following numbers in scientific...Ch. 3 - Prob. 2ECh. 3 - Write the following numbers in ordinary decimal...Ch. 3 - Write the ordinary form of the following numbers:...Ch. 3 - Prob. 5E
Ch. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Complete the following operations:...Ch. 3 - Prob. 12ECh. 3 - What is the mathematical criterion for two...Ch. 3 - Sixty seconds and minute are equivalent...Ch. 3 - Write the equivalency for each conversion...Ch. 3 - Write the equivalency for each conversion...Ch. 3 - Write the equivalency and both conversion factors...Ch. 3 - Write the equivalency and both conversion factors...Ch. 3 - Prob. 19ECh. 3 - Prob. 20ECh. 3 - How long will it take to travel the 406 miles...Ch. 3 - A student who is driving home for the holidays...Ch. 3 - How many minutes does it take a car traveling 88...Ch. 3 - How many days are in 89 weeks?Ch. 3 - What will be the cost in dollars for nails for a...Ch. 3 - A student working for Stop and Shop is packing...Ch. 3 - An American tourist in Mexico was startled to see...Ch. 3 - How many nickels should you receive in exchange...Ch. 3 - How many weeks are in a decade?Ch. 3 - How many seconds are in the month of January?Ch. 3 - List at least two measurements that would be...Ch. 3 - List at least two measurements that would be made...Ch. 3 - A woman stands on a scale in an elevator in a tall...Ch. 3 - A person can pick up a large rock that is...Ch. 3 - What is the metric unit of length?Ch. 3 - What is the metric unit of mass?Ch. 3 - Kilo buck is a slang expression for a sum of...Ch. 3 - What is the difference between the terms kilo unit...Ch. 3 - One milliliter is equal to how many liters?Ch. 3 - How many centimeters are in a meter?Ch. 3 - Which unit, megagrams or grams, would be more...Ch. 3 - What is the name of the unit whose symbol is nm?...Ch. 3 - a 5.74 cg to g, b 1.41 kg to g, c 4.54 x 108 cg to...Ch. 3 - a 15.3 kg to g and mg, b 80.5 g to kg and mg, c...Ch. 3 - a 21.7 m to cm, b 517 m to km, c 0.666 km to cmCh. 3 - a 90.4 mm to m and cm, b 11.9 m to mm and cm, c...Ch. 3 - a 494 cm3 to mL, b 1.91 L to mL, c 874 cm3 to LCh. 3 - a 90.8 mL to L and cm3, b 16.9 L to mL and cm3, c...Ch. 3 - a 7.11 hg to g, b 5.27 x 107 m to pm, c 3.63 x 106...Ch. 3 - a 0.194 Gg to g, b 5.66 nm to m, c 0.00481 Mm to...Ch. 3 - State the volume of liquid in each graduated...Ch. 3 - How long is the object measured with the rulers...Ch. 3 - The same volume of liquid is in each measuring...Ch. 3 - Why is the length of the line in the illustration...Ch. 3 - Prob. 55ECh. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - a 52.20 mL helium, b 17.963 g nitrogen, c 78.45 mg...Ch. 3 - A moving-van crew picks up the following items: a...Ch. 3 - A solution is prepared by dissolving 2.86 grams of...Ch. 3 - Prob. 61ECh. 3 - An empty beaker has a mass of 94.33 grams. After...Ch. 3 - The mole is the SI unit for the amount of a...Ch. 3 - Exactly 1 liter of a solution contains 31.4 grams...Ch. 3 - An empty beaker with a mass of 42.3 g is filled...Ch. 3 - Use the definition density ; mass 4 volume to...Ch. 3 - 0.0715 gal = _____ c m 3 2.27 x 10 4 mL = _____ g...Ch. 3 - 19.3 L = _____ gal 0 .461 qt = _____ LCh. 3 - A popular breakfast cereal comes in a box...Ch. 3 - A copy of your chemistry textbook is found to have...Ch. 3 - The payload of a small pickup truck is 1450 pounds...Ch. 3 - The Hope diamond is the worlds largest blue...Ch. 3 - There is 115 mg of calcium in a 100-g serving of...Ch. 3 - The largest recorded difference of weight between...Ch. 3 - An Austrian boxer reads 69.1 kg when he steps on a...Ch. 3 - A woman gives birth to a 7.5-lb baby. How would a...Ch. 3 - The height of Angel Falls in Venezuela is 979 m....Ch. 3 - A penny is found to have a length of 1.97...Ch. 3 - The Willis Tower in Chicago is 1451 feet tall. How...Ch. 3 - What is the length of the Mississippi River in...Ch. 3 - The summit of Mount Everest is 29, 029 ft above...Ch. 3 - One of the smallest brilliant-cut diamonds ever...Ch. 3 - An office building is heated by oil-fired burners...Ch. 3 - A gas can is found to have a volume of 9.10...Ch. 3 - Celsius Fahrenheit Kelvin 69 -29 111 36 358 -141Ch. 3 - Celsius Fahrenheit Kelvin 40 590 -13 229 440 -314Ch. 3 - Normal body temperature is 98.6 F. What is this...Ch. 3 - In the winter, a heated home in the Northeast...Ch. 3 - Energy conservationists suggest that air...Ch. 3 - The milting point of an unknown solid is...Ch. 3 - The worlds highest shade temperature was recorded...Ch. 3 - The boiling point of a liquid is calculated to be...Ch. 3 - Prob. 93ECh. 3 - Prob. 94ECh. 3 - Prob. 95ECh. 3 - Prob. 96ECh. 3 - Prob. 97ECh. 3 - Prob. 98ECh. 3 - Prob. 99ECh. 3 - Prob. 100ECh. 3 - Prob. 101ECh. 3 - Rank the substances in the photograph from least...Ch. 3 - Calculate the density of benzene, a liquid used in...Ch. 3 - A general chemistry student found a chunk of metal...Ch. 3 - Densities of gases are usually measured in grams...Ch. 3 - Prob. 106ECh. 3 - Ether, a well-known anesthetic, has a density of...Ch. 3 - Prob. 108ECh. 3 - Determine the mass of 2.0 L rubbing alcohol, which...Ch. 3 - Calculate the volume occupied by 15.4 grams of...Ch. 3 - The mass of the liquid in the graduated cylinder...Ch. 3 - Prob. 112ECh. 3 - Distinguish precisely and in scientific terms the...Ch. 3 - Determine whether each statement that follows is...Ch. 3 - How tall are you in a meters; b decimeters; c...Ch. 3 - What do you weigh in a milligrams; b grams; c...Ch. 3 - Standard printer and copier paper is the United...Ch. 3 - The density of aluminium is 2.7 g/cm3. An ecology...Ch. 3 - What is the average density of a single marble...Ch. 3 - A woman has just given birth to a bouncing 6 lb, 7...Ch. 3 - A students drivers license lists her height as 5...Ch. 3 - How many grams of milk are in a 12.0 fluid-ounce...Ch. 3 - The fuel tank in an automobile has a capacity of...Ch. 3 - A welcome rainfall caused the temperature to drop...Ch. 3 - At high noon on the lunar equator the temperature...Ch. 3 - A recipe calls for a quarter cup of butter....Ch. 3 - Prob. 127ECh. 3 - In Active Example 3-29 you calculated that you...Ch. 3 - Write each of the following in scientific...Ch. 3 - Write each of the following numbers in ordinary...Ch. 3 - Prob. 3PECh. 3 - Prob. 4PECh. 3 - How many seconds are in 12 minutes?Ch. 3 - Prob. 6PECh. 3 - Prob. 7PECh. 3 - Prob. 8PECh. 3 - Prob. 9PECh. 3 - Prob. 10PECh. 3 - Prob. 11PECh. 3 - Prob. 12PECh. 3 - What is the volume of liquid in the buret in the...Ch. 3 - Prob. 14PECh. 3 - Round off each of the following quantities to two...Ch. 3 - Prob. 16PECh. 3 - At a certain temperature, 0.878 g of a pure liquid...Ch. 3 - Prob. 18PECh. 3 - Prob. 19PECh. 3 - Prob. 20PECh. 3 - Prob. 21PECh. 3 - Prob. 22PECh. 3 - Prob. 23PECh. 3 - Prob. 24PECh. 3 - The mass of a 50.00-milliliter sample of methanol...Ch. 3 - Prob. 26PECh. 3 - Determine the mass in kilograms of a lead brick...Ch. 3 - Prob. 28PECh. 3 - Prob. 29PE
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- Nonearrow_forwardPart II. Given below are the 'H-NMR spectrum at 300 MHz in CDC13 and mass spectrum using electron ionization of compound Brian. The FTIR of the said compound showed a strong peak at 1710 cm"). Determine the following: (a) molecular Formula and Degree of unsaturation of compound Brian (b) Basing on the given H-NMR spectrum tabulate the following (i) chemical shifts (ii) integration, ciii) multiplicity and (iv) interferences made for each signal (c) Draw the structure of compound Brian. ) ΕΙ 43 41 27 71 114 (M+) Hmmm 20 30 40 50 60 70 80 90 100 110 120 1H NMR spectrum 300 MHz in CDCl3 2.0 alle 1.0arrow_forwardThe iron-iron carbide phase diagram. In the diagram, the letter L indicates that it is a liquid. Indicate what its components are. Temperature (°C) 1600 10 Composition (at% C) 15 25 1538°C -1493°C 8 1400 1200 1394°C y+L L 2500 1147°C y. Austenite 2.14 4.30 2000 1000 912°C y + Fe3C 800ㅏ 0.76 0.022 600 a, Ferrite a + Fe3C 400 0 (Fe) Composition (wt% C) 727°C 1500 Cementite (Fe3C) 1000 6 6.70 Temperature (°F)arrow_forward
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