Introductory Chemistry: An Active Learning Approach
6th Edition
ISBN: 9781305079250
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Chapter 3, Problem 46E
(a) 90.4 mm to m and cm, (b) 11.9 m to mm and cm, (c) 53.6 cm to mm and m
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
system:
rise
Under these conditions, will the pressure of NH 3 tend to rise or fall?
☐ x10
fall
Х
Is it possible to reverse this tendency by adding H₂?
In other words, if you said the pressure of NH 3 will tend to rise, can that
be changed to a tendency to fall by adding H₂? Similarly, if you said the
pressure of NH3 will tend to fall, can that be changed to a tendency to
rise by adding H₂?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of H₂ needed to reverse it.
Round your answer to 2 significant digits.
yes
no
atm
00.
18
Ar
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
Write the chemical formulas of the species that will act as acids in the 'acids' row, the formulas of the species that will act as bases in the 'bases' row, and the
formulas of the species that will act as neither acids nor bases in the 'other' row.
You will find it useful to keep in mind that HF is a weak acid.
2.2 mol of NaOH is added to
1.0 L of a 1.4M HF
solution.
acids:
П
bases:
Х
other: ☐
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acids:
0.51 mol of KOH is added to
1.0 L of a solution that is
bases:
1.3M in both HF and NaF.
other: ☐
00.
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
N2O4 (g) 2NO2 (g)
AG⁰ = 5.4 kJ
Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system:
rise
Under these conditions, will the pressure of N2O4 tend to rise or fall?
x10
fall
Is it possible to reverse this tendency by adding NO2?
In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
rise by adding NO2?
If you said the tendency can be reversed in the second question, calculate
the minimum pressure of NO 2 needed to reverse it.
Round your answer to 2 significant digits.
yes
no
0.42 atm
☑
5
0/5
?
مله
Ar
Chapter 3 Solutions
Introductory Chemistry: An Active Learning Approach
Ch. 3 - Equivalency, conversion factor, solving...Ch. 3 - Metric system, SI units, derived unit, base unitCh. 3 - Prob. 3CLECh. 3 - Prob. 4CLECh. 3 - Prob. 5CLECh. 3 - Write the following numbers in scientific...Ch. 3 - Prob. 2ECh. 3 - Write the following numbers in ordinary decimal...Ch. 3 - Write the ordinary form of the following numbers:...Ch. 3 - Prob. 5E
Ch. 3 - Prob. 6ECh. 3 - Prob. 7ECh. 3 - Prob. 8ECh. 3 - Prob. 9ECh. 3 - Prob. 10ECh. 3 - Complete the following operations:...Ch. 3 - Prob. 12ECh. 3 - What is the mathematical criterion for two...Ch. 3 - Sixty seconds and minute are equivalent...Ch. 3 - Write the equivalency for each conversion...Ch. 3 - Write the equivalency for each conversion...Ch. 3 - Write the equivalency and both conversion factors...Ch. 3 - Write the equivalency and both conversion factors...Ch. 3 - Prob. 19ECh. 3 - Prob. 20ECh. 3 - How long will it take to travel the 406 miles...Ch. 3 - A student who is driving home for the holidays...Ch. 3 - How many minutes does it take a car traveling 88...Ch. 3 - How many days are in 89 weeks?Ch. 3 - What will be the cost in dollars for nails for a...Ch. 3 - A student working for Stop and Shop is packing...Ch. 3 - An American tourist in Mexico was startled to see...Ch. 3 - How many nickels should you receive in exchange...Ch. 3 - How many weeks are in a decade?Ch. 3 - How many seconds are in the month of January?Ch. 3 - List at least two measurements that would be...Ch. 3 - List at least two measurements that would be made...Ch. 3 - A woman stands on a scale in an elevator in a tall...Ch. 3 - A person can pick up a large rock that is...Ch. 3 - What is the metric unit of length?Ch. 3 - What is the metric unit of mass?Ch. 3 - Kilo buck is a slang expression for a sum of...Ch. 3 - What is the difference between the terms kilo unit...Ch. 3 - One milliliter is equal to how many liters?Ch. 3 - How many centimeters are in a meter?Ch. 3 - Which unit, megagrams or grams, would be more...Ch. 3 - What is the name of the unit whose symbol is nm?...Ch. 3 - a 5.74 cg to g, b 1.41 kg to g, c 4.54 x 108 cg to...Ch. 3 - a 15.3 kg to g and mg, b 80.5 g to kg and mg, c...Ch. 3 - a 21.7 m to cm, b 517 m to km, c 0.666 km to cmCh. 3 - a 90.4 mm to m and cm, b 11.9 m to mm and cm, c...Ch. 3 - a 494 cm3 to mL, b 1.91 L to mL, c 874 cm3 to LCh. 3 - a 90.8 mL to L and cm3, b 16.9 L to mL and cm3, c...Ch. 3 - a 7.11 hg to g, b 5.27 x 107 m to pm, c 3.63 x 106...Ch. 3 - a 0.194 Gg to g, b 5.66 nm to m, c 0.00481 Mm to...Ch. 3 - State the volume of liquid in each graduated...Ch. 3 - How long is the object measured with the rulers...Ch. 3 - The same volume of liquid is in each measuring...Ch. 3 - Why is the length of the line in the illustration...Ch. 3 - Prob. 55ECh. 3 - Prob. 56ECh. 3 - Prob. 57ECh. 3 - a 52.20 mL helium, b 17.963 g nitrogen, c 78.45 mg...Ch. 3 - A moving-van crew picks up the following items: a...Ch. 3 - A solution is prepared by dissolving 2.86 grams of...Ch. 3 - Prob. 61ECh. 3 - An empty beaker has a mass of 94.33 grams. After...Ch. 3 - The mole is the SI unit for the amount of a...Ch. 3 - Exactly 1 liter of a solution contains 31.4 grams...Ch. 3 - An empty beaker with a mass of 42.3 g is filled...Ch. 3 - Use the definition density ; mass 4 volume to...Ch. 3 - 0.0715 gal = _____ c m 3 2.27 x 10 4 mL = _____ g...Ch. 3 - 19.3 L = _____ gal 0 .461 qt = _____ LCh. 3 - A popular breakfast cereal comes in a box...Ch. 3 - A copy of your chemistry textbook is found to have...Ch. 3 - The payload of a small pickup truck is 1450 pounds...Ch. 3 - The Hope diamond is the worlds largest blue...Ch. 3 - There is 115 mg of calcium in a 100-g serving of...Ch. 3 - The largest recorded difference of weight between...Ch. 3 - An Austrian boxer reads 69.1 kg when he steps on a...Ch. 3 - A woman gives birth to a 7.5-lb baby. How would a...Ch. 3 - The height of Angel Falls in Venezuela is 979 m....Ch. 3 - A penny is found to have a length of 1.97...Ch. 3 - The Willis Tower in Chicago is 1451 feet tall. How...Ch. 3 - What is the length of the Mississippi River in...Ch. 3 - The summit of Mount Everest is 29, 029 ft above...Ch. 3 - One of the smallest brilliant-cut diamonds ever...Ch. 3 - An office building is heated by oil-fired burners...Ch. 3 - A gas can is found to have a volume of 9.10...Ch. 3 - Celsius Fahrenheit Kelvin 69 -29 111 36 358 -141Ch. 3 - Celsius Fahrenheit Kelvin 40 590 -13 229 440 -314Ch. 3 - Normal body temperature is 98.6 F. What is this...Ch. 3 - In the winter, a heated home in the Northeast...Ch. 3 - Energy conservationists suggest that air...Ch. 3 - The milting point of an unknown solid is...Ch. 3 - The worlds highest shade temperature was recorded...Ch. 3 - The boiling point of a liquid is calculated to be...Ch. 3 - Prob. 93ECh. 3 - Prob. 94ECh. 3 - Prob. 95ECh. 3 - Prob. 96ECh. 3 - Prob. 97ECh. 3 - Prob. 98ECh. 3 - Prob. 99ECh. 3 - Prob. 100ECh. 3 - Prob. 101ECh. 3 - Rank the substances in the photograph from least...Ch. 3 - Calculate the density of benzene, a liquid used in...Ch. 3 - A general chemistry student found a chunk of metal...Ch. 3 - Densities of gases are usually measured in grams...Ch. 3 - Prob. 106ECh. 3 - Ether, a well-known anesthetic, has a density of...Ch. 3 - Prob. 108ECh. 3 - Determine the mass of 2.0 L rubbing alcohol, which...Ch. 3 - Calculate the volume occupied by 15.4 grams of...Ch. 3 - The mass of the liquid in the graduated cylinder...Ch. 3 - Prob. 112ECh. 3 - Distinguish precisely and in scientific terms the...Ch. 3 - Determine whether each statement that follows is...Ch. 3 - How tall are you in a meters; b decimeters; c...Ch. 3 - What do you weigh in a milligrams; b grams; c...Ch. 3 - Standard printer and copier paper is the United...Ch. 3 - The density of aluminium is 2.7 g/cm3. 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