Introduction To General, Organic, And Biochemistry
12th Edition
ISBN: 9781337571357
Author: Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher: Cengage Learning
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Chapter 3, Problem 87P
Interpretation Introduction
Interpretation:
To estimate the
Concept Introduction:
The sum of the atomic radii of the two atoms of a bond gives the distance between those two atoms. This is nothing but the bond length. This is measured in picometers.
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Which of the following bonds are polar? Which is the more electronegative atom in
cach polar bond?
(a) B-F
(b) Cl-CI
(c) Se-O
(d) H–I
Arrange the bonds in cach of the following sets in order of inereasing polarity:
(a) C-F, O–F, Be-F; (b) 0-CI, S-Br, C-P;
(c) C-S, B–F, N-0.
Part B
The dipole moment (u) of HBr (a polar covalent molecule) is 0.844D (debye), and its percent ionic character is 12.5 % . Estimate the bond length of the H Br bond in picometers.
Note that
• 1D= 3.34 x 10-30 C .m and
• in a bond with 100% ionic character, Q = 1.6 x 10-19 C.
Express your answer to two significant figures and include the appropriate units.
HA
?
r= 5.3 • 1018
pm
Not too confident
Chapter 3 Solutions
Introduction To General, Organic, And Biochemistry
Ch. 3.1 - Problem 3-1 Show how the following chemical...Ch. 3.3 - Problem 3-2 Judging from their relative positions...Ch. 3.4 - Problem 3-3 Write the formulas for the ionic...Ch. 3.5 - Problem 3-4 Name these binary ionic compounds: (a)...Ch. 3.5 - Prob. 3.5QCCh. 3.5 - Problem 3-6 Give each binary compound a systematic...Ch. 3.5 - Problem 3-7 Name these ionic compounds, each of...Ch. 3.6 - Prob. 3.8QCCh. 3.6 - Prob. 3.9QCCh. 3.6 - Prob. 3.10QC
Ch. 3.6 - Prob. 3.11QCCh. 3.7 - Prob. 3.12QCCh. 3.8 - Prob. 3.13QCCh. 3.8 - Prob. 3.14QCCh. 3.9 - Problem 3-15 Predict all bond angles for these...Ch. 3.10 - Problem 3-16 Which of these molecules are polar?...Ch. 3 - 3-17 Answer true or false. (a) The octet rule...Ch. 3 - 3-18 How many electrons must each atom gain or...Ch. 3 - 3-19 Show how each chemical change obeys the octet...Ch. 3 - 3-20 Show how each chemical change obeys the octet...Ch. 3 - 3-21 Write the formula for the most stable ion...Ch. 3 - 3-22 Why is Li- not a stable ion?Ch. 3 - 3-23 Predict which ions are stable: (a) (b) (c)...Ch. 3 - 3-24 Predict which ions are stable: (a) Br2- (b)...Ch. 3 - 3-25 Why are carbon and silicon reluctant to form...Ch. 3 - 3-26 Table 3-2 shows the following ions of copper:...Ch. 3 - 3-27 Answer true or false. (a) For Group lA and...Ch. 3 - 3-28 Name each polyatomic ion. (a) HCO3- (b) NO2-...Ch. 3 - 3-29 Answer true or false. (a) According to the...Ch. 3 - Prob. 14PCh. 3 - 3-31 Why does electronegativity generally increase...Ch. 3 - 3-32 Judging from their relative positions in the...Ch. 3 - Prob. 17PCh. 3 - 3-34 Which of these bonds is the most polar? The...Ch. 3 - 3-35 Classify each bond as nonpolar covalent,...Ch. 3 - 3-36 Classify each bond as nonpolar covalent,...Ch. 3 - 3-37 Answer true or false. (a) An ionic bond is...Ch. 3 - 3-38 Complete the chart by writing formulas for...Ch. 3 - 3-39 Write a formula for the ionic compound formed...Ch. 3 - Prob. 24PCh. 3 - 3-41 Describe the structure of sodium chloride in...Ch. 3 - 3-42 What is the charge on each ion in these...Ch. 3 - 3-43 Write the formula for the compound formed...Ch. 3 - 3-44 Write the formula for the ionic compound...Ch. 3 - 3-45 Which formulas are not correct? For each that...Ch. 3 - 3-46 Which formulas are not correct? For each that...Ch. 3 - 3-47 Answer true or false. (a) The name of a...Ch. 3 - 3-48 Potassium chloride and potassium bicarbonate...Ch. 3 - Prob. 33PCh. 3 - 3-50 Name the polyatomic ion(s) in each compound....Ch. 3 - 3-51 Write the formulas for the ions present in...Ch. 3 - Prob. 36PCh. 3 - 3-53 Write formulas for the following ionic...Ch. 3 - 3-54 Write formulas for the following ionic...Ch. 3 - Prob. 39PCh. 3 - 3-56 How many covalent bonds are normally formed...Ch. 3 - 3-57 What is: (a) A single bond? (b) A double...Ch. 3 - 3-58 In Section 2-3B, we saw that there are seven...Ch. 3 - Prob. 43PCh. 3 - Prob. 44PCh. 3 - Prob. 45PCh. 3 - Prob. 46PCh. 3 - 3-63 What is the difference between (a) a bromine...Ch. 3 - 3-64 Acetylene (C2H2), hydrogen cyanide (HCN), and...Ch. 3 - Prob. 49PCh. 3 - 3-66 Why can’t second-row elements have more than...Ch. 3 - 3-67 Why does nitrogen have three bonds and one...Ch. 3 - 3-68 Draw a Lewis structure of a covalent compound...Ch. 3 - Prob. 53PCh. 3 - 3-70 Draw a Lewis structure of a covalent compound...Ch. 3 - Prob. 55PCh. 3 - Prob. 56PCh. 3 - Prob. 57PCh. 3 - 3-74 Answer true or false. (a) A binary covalent...Ch. 3 - Prob. 59PCh. 3 - Prob. 60PCh. 3 - 3-77 Ozone, O3, is an unstable blue gas with a...Ch. 3 - 3-78 Nitrous oxide, N20, laughing gas, is a...Ch. 3 - 3-79 Answer true or false. (a) The letters VSEPR...Ch. 3 - Prob. 64PCh. 3 - Prob. 65PCh. 3 - 3-82 Hydrogen and nitrogen combine in different...Ch. 3 - Prob. 67PCh. 3 - Prob. 68PCh. 3 - Prob. 69PCh. 3 - Prob. 70PCh. 3 - 3-87 Consider the molecule boron trffluoride, BF3....Ch. 3 - Prob. 72PCh. 3 - 3-89 Is it possible for a molecule to have no...Ch. 3 - Prob. 74PCh. 3 - Prob. 75PCh. 3 - Prob. 76PCh. 3 - Prob. 77PCh. 3 - Prob. 78PCh. 3 - Prob. 79PCh. 3 - Prob. 80PCh. 3 - Prob. 81PCh. 3 - Prob. 82PCh. 3 - 3-99 Knowing what you do about covalent bonding in...Ch. 3 - Prob. 84PCh. 3 - Prob. 85PCh. 3 - Prob. 86PCh. 3 - Prob. 87PCh. 3 - Prob. 88PCh. 3 - 3-105 Consider the structure of Vitamin E shown...Ch. 3 - 3-106 Consider the structure of Penicillin G shown...Ch. 3 - 3-107 Ephedrine, a molecule at one time found in...Ch. 3 - Prob. 92PCh. 3 - 3-109 Until several years ago, the two...Ch. 3 - 3-110 Name and write the formula for the fluorine...Ch. 3 - Prob. 95PCh. 3 - Prob. 96PCh. 3 - Prob. 97PCh. 3 - Prob. 98PCh. 3 - Prob. 99PCh. 3 - Prob. 100PCh. 3 - Prob. 101PCh. 3 - Prob. 102PCh. 3 - 3-119 Perchloroethylene, which is a liquid at room...Ch. 3 - 3-120 Vinyl chloride is the starting material for...Ch. 3 - 3-121 Tetrafluoroethylene is the starting material...Ch. 3 - 3-122 Some of the following structural formulas...Ch. 3 - 3-123 Sodium borohydride, NaBH4, has found wide...Ch. 3 - Prob. 108PCh. 3 - Prob. 109PCh. 3 - Prob. 110PCh. 3 - Prob. 111PCh. 3 - Prob. 112PCh. 3 - Consider the structure of Fluoxetine (or Prozac)...Ch. 3 - Consider the structure of lipoic acid shown below,...Ch. 3 - Prob. 115P
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- 3-87 Consider the molecule boron trffluoride, BF3. (a) Write a Lewis structure for BF3. (b) Predict the FBF bond angles using the VSEPR model. (c) Does BF3 have polar bonds? Is it a polar molecule?arrow_forward3-106 Consider the structure of Penicillin G shown below, an antibiotic used to treat bacterial infections caused by gram-positive organisms, derived from Penicillium fungi: (a) Identify the various types of geometries present in each central atom using VSEPR theory. (b) Determine the various relative bond angles associated with each central atom using VSEPR theory (c) Which is the most poiar bond in Penicillin G? (d) Would you predict Penicillin G to be polar or nonpolar?arrow_forward3-120 Vinyl chloride is the starting material for the production of poly(vinyl chloride), abbreviated PVC. Its recycling code is “V”. The major use of PVC is for tubing in residential and commercial construction (Section 12-7). (a) Complete the Lewis structure for vinyl chloride by showing all unshared pairs of electrons. (b) Predict the HCH, HCC, and ClCH bond angles in this molecule. (c) Does vinyl chloride have polar bonds? Is it a polar molecule? Does it have a dipole?arrow_forward
- 3-109 Until several years ago, the two chlorofluorocarbons (CFCs) most widely used as heat transfer media in refrigeration systems were Freon-li (trichloro fluoromethane, CC13F) and Freon-12 (dichiorodi fluoromethane, CCl2F2). Draw a three-dimensional representation of each molecule and indicate the Direction of it.s polarity.arrow_forward3-31 Why does electronegativity generally increase going from left to right across a row of the Periodic Table?arrow_forward3-105 Consider the structure of Vitamin E shown below, which is found most abundantly in wheat germ oil, sunflower, and safflower oils: (a) Identify the various types of geometries present in each central atom using VSEPR theory. (b) Determine the various relative bond angles as sociated with each central atom using VSEPR theory. (c) Which is the most polar bond in Vitamin E? (d) Would you predict Vitamin E to be polar or nonpolar?arrow_forward
- 3-66 Why can’t second-row elements have more than eight electrons in their valence shells? That is, why does the octet rule work for second-row elements?arrow_forward3-121 Tetrafluoroethylene is the starting material for the production of poly(tetrafluoroethylene), PTFE, a polymer that is widely used for the preparation of nonstick coatings on kitchenware (Section 12-7). The most widely known trade name for this product is Teflon®. (a) Complete the Lewis structure for tetrafluoroeth ylene by showing all unshared pairs of electrons. (b) Predict the FCF and FCC bond angles in this molecule. (c) Does tetrafluoroethylene have polar bonds? Is it a polar molecule? Does it have a dipole?arrow_forward2-98 Explain how the ionization energy of atoms changes when proceeding down a group of the Periodic Table and explain why this change occurs.arrow_forward
- 3-119 Perchloroethylene, which is a liquid at room temperature, is one of the most widely used solvents for commercial dry cleaning. It is sold for this purpose under several trade names, including Perciene®. Does this molecule have polar bonds? Is it a polar molecule? Does it have a dipole?arrow_forwardBased on the concept of formal charge, what is the central atom in (a) HCN (do not include H as a possibility)? b) NOCI (Cl is always a terminal atom)?arrow_forward3-68 Draw a Lewis structure of a covalent compound in which nitrogen has: (a) Three single bonds and one unshared pair of electrons (b) One single bond, one double bond, and one unshared pair of electrons (c) One triple bond and one unshared pair of electronsarrow_forward
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