Chemical Principles: The Quest for Insight
7th Edition
ISBN: 9781464183959
Author: Peter Atkins, Loretta Jones, Leroy Laverman
Publisher: W. H. Freeman
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Chapter 3, Problem 3I.5E
(a)
Interpretation Introduction
Interpretation:
Whether alloy is interstitial or substitutional has to be determined.
Concept Introduction:
Alloys are formed from combination of metal with other elements. It retains the properties of metal but affects their crystalline structure. Examples of alloys are stainless steel, brass, bronze, and white gold.
(b)
Interpretation Introduction
Interpretation:
Change in properties of iron because of nitriding has to be determined.
Concept Introduction:
Refer to part (a).
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Indicate the processes in the dismutation of Cu2O.
1. Consider these three reactions as the elementary steps in the mechanism for a chemical reaction.
2600
2400
2200
2000
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1400
1200
1000
800
Potential Energy (kJ)
600
400
200
0
-200-
-400
-600-
-800
(i) Cl₂ (g) + Pt(s) → 2Cl (g) + Pt(s)
(ii) Cl (g)+ CO (g) + Pt (s) → CICO (g) + Pt (s)
Ea = 1550 kJ
Ea = 2240 kJ
(iii) Cl (g) + CICO (g) → Cl₂CO (g)
Ea
= 2350 kJ
AH=-950 kJ
ΔΗ = 575 ΚΙ
AH=-825 kJ
a. Draw the potential energy diagram for the reaction. Label the data points for clarity.
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Reaction Progress
b. What is the overall chemical equation?
c. What is the overall change in enthalpy for the above chemical reaction?
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draw the enolate anion and the carbonyl that would be needed to make this product through an aldol addition reaction.
Chapter 3 Solutions
Chemical Principles: The Quest for Insight
Ch. 3 - Prob. 3A.1ASTCh. 3 - Prob. 3A.1BSTCh. 3 - Prob. 3A.2ASTCh. 3 - Prob. 3A.2BSTCh. 3 - Prob. 3A.3ASTCh. 3 - Prob. 3A.3BSTCh. 3 - Prob. 3A.1ECh. 3 - Prob. 3A.2ECh. 3 - Prob. 3A.3ECh. 3 - Prob. 3A.4E
Ch. 3 - Prob. 3A.5ECh. 3 - Prob. 3A.6ECh. 3 - Prob. 3A.7ECh. 3 - Prob. 3A.8ECh. 3 - Prob. 3A.9ECh. 3 - Prob. 3A.10ECh. 3 - Prob. 3B.1ASTCh. 3 - Prob. 3B.1BSTCh. 3 - Prob. 3B.2ASTCh. 3 - Prob. 3B.2BSTCh. 3 - Prob. 3B.3ASTCh. 3 - Prob. 3B.3BSTCh. 3 - Prob. 3B.4ASTCh. 3 - Prob. 3B.4BSTCh. 3 - Prob. 3B.5ASTCh. 3 - Prob. 3B.5BSTCh. 3 - Prob. 3B.6ASTCh. 3 - Prob. 3B.6BSTCh. 3 - Prob. 3B.7ASTCh. 3 - Prob. 3B.7BSTCh. 3 - Prob. 3B.8ASTCh. 3 - Prob. 3B.8BSTCh. 3 - Prob. 3B.1ECh. 3 - Prob. 3B.2ECh. 3 - Prob. 3B.5ECh. 3 - Prob. 3B.6ECh. 3 - Prob. 3B.9ECh. 3 - Prob. 3B.10ECh. 3 - Prob. 3B.11ECh. 3 - Prob. 3B.12ECh. 3 - Prob. 3B.13ECh. 3 - Prob. 3B.14ECh. 3 - Prob. 3B.15ECh. 3 - Prob. 3B.16ECh. 3 - Prob. 3B.17ECh. 3 - Prob. 3B.18ECh. 3 - Prob. 3B.19ECh. 3 - Prob. 3B.20ECh. 3 - Prob. 3B.21ECh. 3 - Prob. 3B.22ECh. 3 - Prob. 3B.23ECh. 3 - Prob. 3B.24ECh. 3 - Prob. 3B.25ECh. 3 - Prob. 3B.26ECh. 3 - Prob. 3B.27ECh. 3 - Prob. 3B.28ECh. 3 - Prob. 3B.29ECh. 3 - Prob. 3B.30ECh. 3 - Prob. 3B.31ECh. 3 - Prob. 3B.32ECh. 3 - Prob. 3B.33ECh. 3 - Prob. 3B.34ECh. 3 - Prob. 3B.35ECh. 3 - Prob. 3B.36ECh. 3 - Prob. 3B.37ECh. 3 - Prob. 3B.38ECh. 3 - Prob. 3B.39ECh. 3 - Prob. 3B.40ECh. 3 - Prob. 3B.41ECh. 3 - Prob. 3B.42ECh. 3 - Prob. 3C.1ASTCh. 3 - Prob. 3C.1BSTCh. 3 - Prob. 3C.2ASTCh. 3 - Prob. 3C.2BSTCh. 3 - Prob. 3C.3ASTCh. 3 - Prob. 3C.3BSTCh. 3 - Prob. 3C.1ECh. 3 - Prob. 3C.2ECh. 3 - Prob. 3C.3ECh. 3 - Prob. 3C.4ECh. 3 - Prob. 3C.5ECh. 3 - Prob. 3C.6ECh. 3 - Prob. 3C.7ECh. 3 - Prob. 3C.8ECh. 3 - Prob. 3C.9ECh. 3 - Prob. 3C.10ECh. 3 - Prob. 3C.11ECh. 3 - Prob. 3C.12ECh. 3 - Prob. 3C.13ECh. 3 - Prob. 3C.14ECh. 3 - Prob. 3C.15ECh. 3 - Prob. 3C.16ECh. 3 - Prob. 3D.1ASTCh. 3 - Prob. 3D.1BSTCh. 3 - Prob. 3D.2ASTCh. 3 - Prob. 3D.2BSTCh. 3 - Prob. 3D.1ECh. 3 - Prob. 3D.2ECh. 3 - Prob. 3D.3ECh. 3 - Prob. 3D.4ECh. 3 - Prob. 3D.5ECh. 3 - Prob. 3D.6ECh. 3 - Prob. 3D.7ECh. 3 - Prob. 3D.8ECh. 3 - Prob. 3D.9ECh. 3 - Prob. 3D.10ECh. 3 - Prob. 3D.11ECh. 3 - Prob. 3D.12ECh. 3 - Prob. 3D.13ECh. 3 - Prob. 3D.14ECh. 3 - Prob. 3D.15ECh. 3 - Prob. 3D.16ECh. 3 - Prob. 3D.17ECh. 3 - Prob. 3D.18ECh. 3 - Prob. 3E.1ASTCh. 3 - Prob. 3E.1BSTCh. 3 - Prob. 3E.1ECh. 3 - Prob. 3E.2ECh. 3 - Prob. 3E.3ECh. 3 - Prob. 3E.4ECh. 3 - Prob. 3E.5ECh. 3 - Prob. 3E.6ECh. 3 - Prob. 3E.7ECh. 3 - Prob. 3E.8ECh. 3 - Prob. 3E.9ECh. 3 - Prob. 3E.10ECh. 3 - Prob. 3E.13ECh. 3 - Prob. 3E.14ECh. 3 - Prob. 3F.1ASTCh. 3 - Prob. 3F.1BSTCh. 3 - Prob. 3F.2ASTCh. 3 - Prob. 3F.2BSTCh. 3 - Prob. 3F.3ASTCh. 3 - Prob. 3F.3BSTCh. 3 - Prob. 3F.1ECh. 3 - Prob. 3F.2ECh. 3 - Prob. 3F.3ECh. 3 - Prob. 3F.4ECh. 3 - Prob. 3F.5ECh. 3 - Prob. 3F.6ECh. 3 - Prob. 3F.7ECh. 3 - Prob. 3F.8ECh. 3 - Prob. 3F.9ECh. 3 - Prob. 3F.10ECh. 3 - Prob. 3F.11ECh. 3 - Prob. 3F.12ECh. 3 - Prob. 3F.13ECh. 3 - Prob. 3F.14ECh. 3 - Prob. 3F.15ECh. 3 - Prob. 3F.16ECh. 3 - Prob. 3F.17ECh. 3 - Prob. 3F.18ECh. 3 - Prob. 3F.19ECh. 3 - Prob. 3F.20ECh. 3 - Prob. 3F.21ECh. 3 - Prob. 3F.22ECh. 3 - Prob. 3G.1ECh. 3 - Prob. 3G.2ECh. 3 - Prob. 3G.3ECh. 3 - Prob. 3G.4ECh. 3 - Prob. 3G.5ECh. 3 - Prob. 3G.6ECh. 3 - Prob. 3G.7ECh. 3 - Prob. 3G.8ECh. 3 - Prob. 3G.9ECh. 3 - Prob. 3G.10ECh. 3 - Prob. 3G.11ECh. 3 - Prob. 3G.12ECh. 3 - Prob. 3G.13ECh. 3 - Prob. 3G.14ECh. 3 - Prob. 3G.15ECh. 3 - Prob. 3G.16ECh. 3 - Prob. 3G.17ECh. 3 - Prob. 3G.18ECh. 3 - Prob. 3H.1ASTCh. 3 - Prob. 3H.1BSTCh. 3 - Prob. 3H.2ASTCh. 3 - Prob. 3H.2BSTCh. 3 - Prob. 3H.3ASTCh. 3 - Prob. 3H.3BSTCh. 3 - Prob. 3H.4ASTCh. 3 - Prob. 3H.4BSTCh. 3 - Prob. 3H.5ASTCh. 3 - Prob. 3H.5BSTCh. 3 - Prob. 3H.1ECh. 3 - Prob. 3H.2ECh. 3 - Prob. 3H.3ECh. 3 - Prob. 3H.4ECh. 3 - Prob. 3H.5ECh. 3 - Prob. 3H.6ECh. 3 - Prob. 3H.7ECh. 3 - Prob. 3H.8ECh. 3 - Prob. 3H.9ECh. 3 - Prob. 3H.10ECh. 3 - Prob. 3H.11ECh. 3 - Prob. 3H.12ECh. 3 - Prob. 3H.13ECh. 3 - Prob. 3H.14ECh. 3 - Prob. 3H.15ECh. 3 - Prob. 3H.16ECh. 3 - Prob. 3H.17ECh. 3 - Prob. 3H.19ECh. 3 - Prob. 3H.20ECh. 3 - Prob. 3H.23ECh. 3 - Prob. 3H.24ECh. 3 - Prob. 3H.25ECh. 3 - Prob. 3H.26ECh. 3 - Prob. 3H.27ECh. 3 - Prob. 3H.28ECh. 3 - Prob. 3H.29ECh. 3 - Prob. 3H.30ECh. 3 - Prob. 3H.31ECh. 3 - Prob. 3H.32ECh. 3 - Prob. 3H.33ECh. 3 - Prob. 3H.34ECh. 3 - Prob. 3H.35ECh. 3 - Prob. 3H.36ECh. 3 - Prob. 3I.1ASTCh. 3 - Prob. 3I.1BSTCh. 3 - Prob. 3I.2ASTCh. 3 - Prob. 3I.2BSTCh. 3 - Prob. 3I.3ASTCh. 3 - Prob. 3I.3BSTCh. 3 - Prob. 3I.4ASTCh. 3 - Prob. 3I.4BSTCh. 3 - Prob. 3I.1ECh. 3 - Prob. 3I.2ECh. 3 - Prob. 3I.3ECh. 3 - Prob. 3I.4ECh. 3 - Prob. 3I.5ECh. 3 - Prob. 3I.6ECh. 3 - Prob. 3I.7ECh. 3 - Prob. 3I.8ECh. 3 - Prob. 3I.11ECh. 3 - Prob. 3I.12ECh. 3 - Prob. 3I.13ECh. 3 - Prob. 3I.14ECh. 3 - Prob. 3I.15ECh. 3 - Prob. 3I.16ECh. 3 - Prob. 3J.1ASTCh. 3 - Prob. 3J.1BSTCh. 3 - Prob. 3J.2ASTCh. 3 - Prob. 3J.2BSTCh. 3 - Prob. 3J.3ASTCh. 3 - Prob. 3J.3BSTCh. 3 - Prob. 3J.1ECh. 3 - Prob. 3J.2ECh. 3 - Prob. 3J.3ECh. 3 - Prob. 3J.4ECh. 3 - Prob. 3J.5ECh. 3 - Prob. 3J.6ECh. 3 - Prob. 3J.7ECh. 3 - Prob. 3J.8ECh. 3 - Prob. 3J.9ECh. 3 - Prob. 3J.10ECh. 3 - Prob. 3J.11ECh. 3 - Prob. 3J.12ECh. 3 - Prob. 3J.13ECh. 3 - Prob. 3J.14ECh. 3 - Prob. 3J.15ECh. 3 - Prob. 3J.16ECh. 3 - Prob. 3.1ECh. 3 - Prob. 3.2ECh. 3 - Prob. 3.3ECh. 3 - Prob. 3.4ECh. 3 - Prob. 3.5ECh. 3 - Prob. 3.6ECh. 3 - Prob. 3.7ECh. 3 - Prob. 3.8ECh. 3 - Prob. 3.9ECh. 3 - Prob. 3.10ECh. 3 - Prob. 3.11ECh. 3 - Prob. 3.12ECh. 3 - Prob. 3.13ECh. 3 - Prob. 3.15ECh. 3 - Prob. 3.18ECh. 3 - Prob. 3.19ECh. 3 - Prob. 3.23ECh. 3 - Prob. 3.24ECh. 3 - Prob. 3.25ECh. 3 - Prob. 3.26ECh. 3 - Prob. 3.27ECh. 3 - Prob. 3.29ECh. 3 - Prob. 3.31ECh. 3 - Prob. 3.32ECh. 3 - Prob. 3.35ECh. 3 - Prob. 3.36ECh. 3 - Prob. 3.37ECh. 3 - Prob. 3.38ECh. 3 - Prob. 3.40ECh. 3 - Prob. 3.41ECh. 3 - Prob. 3.42ECh. 3 - Prob. 3.45ECh. 3 - Prob. 3.47ECh. 3 - Prob. 3.49ECh. 3 - Prob. 3.50ECh. 3 - Prob. 3.51ECh. 3 - Prob. 3.53ECh. 3 - Prob. 3.54ECh. 3 - Prob. 3.55ECh. 3 - Prob. 3.56ECh. 3 - Prob. 3.57ECh. 3 - Prob. 3.58ECh. 3 - Prob. 3.59ECh. 3 - Prob. 3.60ECh. 3 - Prob. 3.61ECh. 3 - Prob. 3.62ECh. 3 - Prob. 3.63ECh. 3 - Prob. 3.64ECh. 3 - Prob. 3.65ECh. 3 - Prob. 3.66ECh. 3 - Prob. 3.67ECh. 3 - Prob. 3.68E
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