Concept explainers
(a)
Interpretation:
To draw the Lewis structure of a molecule in which carbon atom is bonded by a double bond to an other carbon atom.
Concept Introduction:
A covalent bond is formed by sharing of same number of electrons between two atoms to complete their octet. Atoms taking part in covalent bond formation may share one, two or three electron pairs thus forming single, double and triple bond respectively.
Lewis structure of a molecule can be determined as-
- 1.Calculate the total number of valence electrons.(T.V.E. = a).
Sum up all the electrons of all atoms present in the molecule.
If the molecule is an anion, add the same number of electrons as the charge present on the ion.
If it is a cation, subtract the same number of electrons as the charge present on the ion.
2. Calculate the total number of electrons required for each atom to have a complete octet or doublet for hydrogen (b).
3. Therefore number of bonds formed =
4.Remaining electrons are called as lone pairs.
5.Assign formal charges to atoms.
(b)
Interpretation:
To draw the Lewis structure of a molecule in which carbon atom is bonded by a double bond to an oxygen atom.
Concept Introduction:
A covalent bond is formed by sharing of same number of electrons between two atoms to complete their octet. Atoms taking part in covalent bond formation may share one, two or three electron pairs thus forming single, double and triple bond respectively.
Lewis structure of a molecule can be determined as-
- 1. Calculate the total number of valence electrons.(T.V.E. = a).
Sum up all the electrons of all atoms present in the molecule.
If the molecule is an anion, add the same number of electrons as the charge present on the ion.
If it is a cation, subtract the same number of electrons as the charge present on the ion.
2. Calculate the total number of electrons required for each atom to have a complete octet or doublet for Hydrogen.(b).
3. Therefore number of bonds formed =
4. Remaining electrons are called as lone pairs.
5. Assign formal charges to atoms.
(c)
Interpretation:
To draw the Lewis structure for a molecule in which carbon atom is bonded by a double bond to a nitrogen atom.
Concept Introduction:
A covalent bond is formed by sharing of same number of electrons between two atoms to complete their octet. Atoms taking part in covalent bond formation may share one, two or three electron pairs thus forming single, double and triple bond respectively.
Lewis structure of a molecule can be determined as-
- 1. Calculate the total number of valence electrons.(T.V.E. = a).
Sum up all the electrons of all atoms present in the molecule.
If the molecule is an anion, add the same number of electrons as the charge present on the ion.
If it is a cation, subtract the same number of electrons as the charge present on the ion.
2. Calculate the total number of electrons required for each atom to have a complete octet or doublet for Hydrogen.(b).
3. Therefore number of bonds formed =
4. Remaining electrons are called as lone pairs.
5. Assign formal charges to atoms.
Want to see the full answer?
Check out a sample textbook solutionChapter 3 Solutions
Student Solutions Manual for Bettelheim/Brown/Campbell/Farrell/Torres' Introduction to General, Organic and Biochemistry, 11th
- 3-119 Perchloroethylene, which is a liquid at room temperature, is one of the most widely used solvents for commercial dry cleaning. It is sold for this purpose under several trade names, including Perciene®. Does this molecule have polar bonds? Is it a polar molecule? Does it have a dipole?arrow_forward3-89 Is it possible for a molecule to have no polar bonds and yet have a dipole? Explain.arrow_forward3-41 Describe the structure of sodium chloride in the solid state.arrow_forward
- 3-122 Some of the following structural formulas are incorrect because they contain one or more atoms that do not have their normal number of covalent bonds. Which structural formulas are incorrect, and which atom or atoms in each have the incorrect number of bonds?arrow_forward3-110 Name and write the formula for the fluorine containing compound present in fluoridated tooth pastes and dental gels.arrow_forward3-120 Vinyl chloride is the starting material for the production of poly(vinyl chloride), abbreviated PVC. Its recycling code is “V”. The major use of PVC is for tubing in residential and commercial construction (Section 12-7). (a) Complete the Lewis structure for vinyl chloride by showing all unshared pairs of electrons. (b) Predict the HCH, HCC, and ClCH bond angles in this molecule. (c) Does vinyl chloride have polar bonds? Is it a polar molecule? Does it have a dipole?arrow_forward
- 3-25 Why are carbon and silicon reluctant to form ionic bonds?arrow_forward3-106 Consider the structure of Penicillin G shown below, an antibiotic used to treat bacterial infections caused by gram-positive organisms, derived from Penicillium fungi: (a) Identify the various types of geometries present in each central atom using VSEPR theory. (b) Determine the various relative bond angles associated with each central atom using VSEPR theory (c) Which is the most poiar bond in Penicillin G? (d) Would you predict Penicillin G to be polar or nonpolar?arrow_forward3-107 Ephedrine, a molecule at one time found in the dietary supplement ephedra, has been linked to adverse health reactions, such as heart attacks, strokes, and heart palpitations. The use of ephedra in dietary supplements is now banned by the FDA. (a) Which is the most polar bond in ephedra? (b) Would you predict ephedra to be polar or nonpolar?arrow_forward
- 3-68 Draw a Lewis structure of a covalent compound in which nitrogen has: (a) Three single bonds and one unshared pair of electrons (b) One single bond, one double bond, and one unshared pair of electrons (c) One triple bond and one unshared pair of electronsarrow_forward3-109 Until several years ago, the two chlorofluorocarbons (CFCs) most widely used as heat transfer media in refrigeration systems were Freon-li (trichloro fluoromethane, CC13F) and Freon-12 (dichiorodi fluoromethane, CCl2F2). Draw a three-dimensional representation of each molecule and indicate the Direction of it.s polarity.arrow_forward3-127 Amoxicillin is an antibiotic used to treat bacterial infections caused by susceptible microorganisms. Consider the skeletal structure of amoxicillin (y refer to the structure at bottom of page). Where all the bonded atoms are shown but double bonds, triple bonds, and/or lone pairs are missing: (a) Complete the structure of amoxicillin. (b) Identify the various types of geometries present in each central atom using VSEPR theory (e) Determine the various relative bond angles as sociated with each central atom using VSEPR theory. (d) What is the most polar bond in Amoxicillin? (e) Would you predict amoxicillin to be polar or nonpolar? (f) Is amoxicillin expected to possess resonance? Explain why or why not. V Chemical structure for problem 3-127arrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning