(a) Interpretation: The name of compound using Roman numeral to show the charge on a transition metal ion should be identified. Concept Introduction: The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows: 1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Question

1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on the LC-MS printout. How much different are they? 2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit, explain what each of these is and why they are present. 3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by calculating the accurate monoisotopic mass. 4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source. 5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one point of extra credit, see if you can identify this molecule as well and confirm by…

Answer 1

Question

Chapter 3, Problem 3.118P

Interpretation Introduction

(a)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(b)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(c)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(d)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(e)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(f)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

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1. Calculate the accurate monoisotopic mass (using all 1H, 12C, 14N, 160 and 35CI) for your product using the table in your lab manual. Don't include the Cl, since you should only have [M+H]*. Compare this to the value you see on the LC-MS printout. How much different are they? 2. There are four isotopic peaks for the [M+H]* ion at m/z 240, 241, 242 and 243. For one point of extra credit, explain what each of these is and why they are present. 3. There is a fragment ion at m/z 184. For one point of extra credit, identify this fragment and confirm by calculating the accurate monoisotopic mass. 4. The UV spectrum is also at the bottom of your printout. For one point of extra credit, look up the UV spectrum of bupropion on Google Images and compare to your spectrum. Do they match? Cite your source. 5. For most of you, there will be a second chromatographic peak whose m/z is 74 (to a round number). For one point of extra credit, see if you can identify this molecule as well and confirm by…

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can you draw each step on a piece of a paper please this is very confusing to me

Answer 2

Question

Chapter 3, Problem 3.118P

Interpretation Introduction

(a)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(b)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(c)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(d)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(e)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(f)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

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Answer 3

Question

Chapter 3, Problem 3.118P

Interpretation Introduction

(a)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(b)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(c)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(d)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(e)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(f)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

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Answer 4

Question

Chapter 3, Problem 3.118P

Interpretation Introduction

(a)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(b)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(c)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(d)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(e)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(f)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

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Answer 5

Chapter 3, Problem 3.118P

Interpretation Introduction

(a)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(b)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(c)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(d)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(e)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Interpretation Introduction

(f)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 6

Chapter 3, Problem 3.118P

Interpretation Introduction

(a)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 7

Chapter 3, Problem 3.118P

Interpretation Introduction

(a)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The name of compound using Roman numeral to show the charge on a transition metal ion should be identified.

Concept Introduction:

The name of the compound written by writing the name of cation followed by the name of anion with either suffix -ate or -ide depending upon the group to which the atom belongs. The name of the cation is written same as the name of metal. The charge on the metal atom is its oxidation state and it can be written in roman numeral as follows:

1-(I), 2-(II), 3-(III), 4-(IV) and so on.

Answer 18

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Answer 19

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Answer 20

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Answer 23

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Answer 24

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Answer 25

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Answer 29

Ch. 3.2 - Problem 3-1 Show how the following chemical...Ch. 3.4 - Problem 3-2 Judging from their relative positions...Ch. 3.5 - Problem 3-3 Write the formulas for the ionic...Ch. 3.6 - Problem 3-4 Name these binary ionic compounds: (a)...Ch. 3.6 - Prob. 3.5P Ch. 3.6 - Problem 3-6 Give each binary compound a systematic...Ch. 3.6 - Problem 3-7 Name these ionic compounds, each of...Ch. 3.7 - Prob. 3.8P Ch. 3.7 - Prob. 3.9P Ch. 3.7 - Prob. 3.10P

Solution Summary: The author explains the name of the compound using Roman numeral to show the charge on a transition metal ion.

Chapter 3 Solutions