Organic Chemistry-Package(Custom)
4th Edition
ISBN: 9781259141089
Author: SMITH
Publisher: MCG
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Textbook Question
Chapter 3, Problem 3.21P
a. Identify the functional groups in the ball-and-stick model of elemicin, a compound partly responsible f or the flavor and fragrance of nutmeg.
b. Draw a skeletal structure of a constitutional isomer of elemicin that should have a higher boiling point and melting point.
c. Label all electrophilic carbon atoms.
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a.Identify the functional groups in the ball-and-stick model of elemicin, a compound partly responsible for the flavor and fragrance of nutmeg.
b. Draw a skeletal structure of a constitutional isomer of elemicin that should have a higher boiling point and melting point.
c. Label all electrophilic carbon atoms.
2. The structure of caffeine is shown here. With the help of your textbook or the functional
group table on the back cover of your laboratory manual, complete the following:
A Place a circle around each of the methyl
CH3
groups.
B. Place a box around the alkene functional
CH3
group. (There is only one.)
C. Place a triangle around one of the
carbonyl groups.
D. Draw a single arrow pointing toward a
nitrogen that is involved in
functional
N.
an amine
N.
group.
E. Draw a double arrow pointing toward a
nitrogen that is involved in
functional
CH3
an amide
Caffeine
group.
(b).
B. For each of the following, draw a líne structure of a molecule that contains the given functional
groups and is consistent with the given molecular formula. Calculate the HDI (hydrogen deficiency
index) and label the functional groups.
Chapter 3 Solutions
Organic Chemistry-Package(Custom)
Ch. 3 - Prob. 3.1PCh. 3 - Prob. 3.2PCh. 3 - Draw the structure of a compound fitting each...Ch. 3 - Draw structures that fit each description and name...Ch. 3 - What types of intermolecular forces are present in...Ch. 3 - Prob. 3.6PCh. 3 - Explain why the boiling point of propanamide, is...Ch. 3 - Predict which compound in each pair has the higher...Ch. 3 - Prob. 3.9PCh. 3 - Prob. 3.10P
Ch. 3 - a Label the hydrophobic and hydrophilic portions...Ch. 3 - Prob. 3.12PCh. 3 - Prob. 3.13PCh. 3 - Prob. 3.14PCh. 3 - Prob. 3.15PCh. 3 - Nonactin and valinomycin each contain only two...Ch. 3 - Prob. 3.17PCh. 3 - Problem 3.26 Label the electrophilic and...Ch. 3 - Problem 3.27 Considering only electron density,...Ch. 3 - The fact that sweet-tasting carbohydrates like...Ch. 3 - 3.29
Identify the functional groups in the...Ch. 3 - Prob. 3.22PCh. 3 - 3.32 Identify the functional groups in each...Ch. 3 - Draw the seven constitutional isomers having...Ch. 3 - 3.33 Identify each functional group located in the...Ch. 3 - Draw seven constitutional isomers with molecular...Ch. 3 - Prob. 3.27PCh. 3 - Prob. 3.28PCh. 3 - Prob. 3.29PCh. 3 - Intramolecular force of attraction are often...Ch. 3 - 3.40 (a) Draw four compounds with molecular...Ch. 3 - Prob. 3.32PCh. 3 - Explain why CH3CH2NHCH3 has higher boiling point...Ch. 3 - Prob. 3.34PCh. 3 - Prob. 3.35PCh. 3 - Explain the observed trend in the melting points...Ch. 3 - Prob. 3.37PCh. 3 - Prob. 3.38PCh. 3 - Prob. 3.39PCh. 3 - 3.48 Explain why diethylether and have similar...Ch. 3 - Prob. 3.41PCh. 3 - 3.50 Predict the solubility of each of the...Ch. 3 - Prob. 3.43PCh. 3 - Prob. 3.44PCh. 3 - THC is the active component in marijuana, and...Ch. 3 - Prob. 3.46PCh. 3 - Prob. 3.47PCh. 3 - Prob. 3.48PCh. 3 - Label the electrophilic and nucleophilic sites in...Ch. 3 - By using only electron density arguments,...Ch. 3 - Prob. 3.51PCh. 3 - Prob. 3.52PCh. 3 - Prob. 3.53PCh. 3 - Prob. 3.54PCh. 3 - Prob. 3.55PCh. 3 - Recall from section 1.10B that there is restricted...
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