(a) Interpretation: The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown. Concept Introduction: The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

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Answer 1

Question

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

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Questions 4 and 5

For a titration of 40.00 mL of 0.0500 M oxalic acid H2C2O4 with 0.1000 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin;2) 15 mL; 3) 20 mL; 4) 25 mL; 5) 40 mL; 6) 50 mL. Ka1 = 5.90×10^-2, Ka2 = 6.50×10^-5 for oxalic acid.

Predict the major organic product(s), if any, of the following reactions. Assume all reagents are in excess unless otherwise indicated.

Answer 2

Question

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

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Answer 3

Question

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

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Answer 4

Question

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

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Answer 5

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Answer 6

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Answer 7

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Answer 10

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Answer 12

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Answer 13

Ch. 26 - Prob. 26.1P Ch. 26 - Prob. 26.2P Ch. 26 - Prob. 26.3P Ch. 26 - Prob. 26.4P Ch. 26 - Prob. 26.5P Ch. 26 - Prob. 26.6P Ch. 26 - Prob. 26.7P Ch. 26 - Prob. 26.8P Ch. 26 - Prob. 26.9P Ch. 26 - Prob. 26.10P

Solution Summary: The author illustrates the hydrogen bond complementarity that results from pairing of imine isomer of C with A.

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Chapter 26 Solutions