Organic Chemistry, Ebook And Single-course Homework Access
Organic Chemistry, Ebook And Single-course Homework Access
6th Edition
ISBN: 9781319085841
Author: LOUDON
Publisher: MAC HIGHER
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Chapter 26, Problem 26.21P
Interpretation Introduction

(a)

Interpretation:

The structure of deoxythymidine monophosphate (dTMP) is to be drawn.

Concept introduction:

The compound, deoxythymidine monophosphate (dTMP) is used as the monomer in DNA molecule. This compound is also termed as thymidylic acid. Deoxythymidine monophosphate is an ester of phosphoric acid which contains nucleoside thymidine.

Interpretation Introduction

(b)

Interpretation:

The structure of GDP is to be drawn.

Concept introduction:

The full form of GDP is guanosine diphosphate. This compound is a pyrophosphoric acid’ ester attached to a nucleoside guanosine. This compound contains a pentose sugar ribose, pyrophosphate group and a nucleobase guanine.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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