(a) Interpretation: The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown. Concept Introduction: The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

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Answer 1

Question

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)

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Answer 2

Question

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

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Answer 3

Question

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

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Answer 4

Question

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

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Answer 5

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Answer 6

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Answer 7

Chapter 26, Problem 26.51AP

Interpretation Introduction

(a)

Interpretation:

The hydrogen bond complementarity that results from pairing of imine isomer of C with A is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The hydrogen bond complementarity that results from pairing of enol isomer of T with G is to be shown.

Concept Introduction:

The DNA structure is formed by the base pairing of nucleotides. The complementarity rule of DNA states that A will always make two hydrogen bonds with T and G always makes three hydrogen bonds with C. Any change in the structure of nucleotide changes the hydrogen bond pairing of nucleotide, which results in mutation in DNA structure.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 26 - Prob. 26.1P Ch. 26 - Prob. 26.2P Ch. 26 - Prob. 26.3P Ch. 26 - Prob. 26.4P Ch. 26 - Prob. 26.5P Ch. 26 - Prob. 26.6P Ch. 26 - Prob. 26.7P Ch. 26 - Prob. 26.8P Ch. 26 - Prob. 26.9P Ch. 26 - Prob. 26.10P

Solution Summary: The author illustrates the hydrogen bond complementarity that results from pairing of imine isomer of C with A.

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Chapter 26 Solutions