(a) Interpretation: The reason as to why pyridine is miscible in water and pyrrole is slightly soluble in water is to be stated. Concept introduction: The tendency of the solid to dissolve in the solvent is known as solubility. Pyridine is a six-membered heterocyclic aromatic ring where, a nitrogen atom is placed instead of a carbon atom. Pyrrole is a five-membered heterocyclic aromatic ring where a nitrogen atom is placed instead of a carbon atom.

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Answer 1

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Chapter 26, Problem 26.6P

Interpretation Introduction

(a)

Interpretation:

The reason as to why pyridine is miscible in water and pyrrole is slightly soluble in water is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Pyridine is a six-membered heterocyclic aromatic ring where, a nitrogen atom is placed instead of a carbon atom. Pyrrole is a five-membered heterocyclic aromatic ring where a nitrogen atom is placed instead of a carbon atom.

Interpretation Introduction

(b)

Interpretation:

Whether the imidazole has high or low water solubility is to be stated. The reason for the correct option is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Imidazole is a five-membered heterocyclic aromatic ring with two nitrogen atom is placed at C1 and C3 positions. It contains two types of nitrogen atom one is pyrrole type and one is pyridine type.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10

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Answer 2

Question

Chapter 26, Problem 26.6P

Interpretation Introduction

(a)

Interpretation:

The reason as to why pyridine is miscible in water and pyrrole is slightly soluble in water is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Pyridine is a six-membered heterocyclic aromatic ring where, a nitrogen atom is placed instead of a carbon atom. Pyrrole is a five-membered heterocyclic aromatic ring where a nitrogen atom is placed instead of a carbon atom.

Interpretation Introduction

(b)

Interpretation:

Whether the imidazole has high or low water solubility is to be stated. The reason for the correct option is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Imidazole is a five-membered heterocyclic aromatic ring with two nitrogen atom is placed at C1 and C3 positions. It contains two types of nitrogen atom one is pyrrole type and one is pyridine type.

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Answer 3

Question

Chapter 26, Problem 26.6P

Interpretation Introduction

(a)

Interpretation:

The reason as to why pyridine is miscible in water and pyrrole is slightly soluble in water is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Pyridine is a six-membered heterocyclic aromatic ring where, a nitrogen atom is placed instead of a carbon atom. Pyrrole is a five-membered heterocyclic aromatic ring where a nitrogen atom is placed instead of a carbon atom.

Interpretation Introduction

(b)

Interpretation:

Whether the imidazole has high or low water solubility is to be stated. The reason for the correct option is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Imidazole is a five-membered heterocyclic aromatic ring with two nitrogen atom is placed at C1 and C3 positions. It contains two types of nitrogen atom one is pyrrole type and one is pyridine type.

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Answer 4

Question

Chapter 26, Problem 26.6P

Interpretation Introduction

(a)

Interpretation:

The reason as to why pyridine is miscible in water and pyrrole is slightly soluble in water is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Pyridine is a six-membered heterocyclic aromatic ring where, a nitrogen atom is placed instead of a carbon atom. Pyrrole is a five-membered heterocyclic aromatic ring where a nitrogen atom is placed instead of a carbon atom.

Interpretation Introduction

(b)

Interpretation:

Whether the imidazole has high or low water solubility is to be stated. The reason for the correct option is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Imidazole is a five-membered heterocyclic aromatic ring with two nitrogen atom is placed at C1 and C3 positions. It contains two types of nitrogen atom one is pyrrole type and one is pyridine type.

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Answer 5

Chapter 26, Problem 26.6P

Interpretation Introduction

(a)

Interpretation:

The reason as to why pyridine is miscible in water and pyrrole is slightly soluble in water is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Pyridine is a six-membered heterocyclic aromatic ring where, a nitrogen atom is placed instead of a carbon atom. Pyrrole is a five-membered heterocyclic aromatic ring where a nitrogen atom is placed instead of a carbon atom.

Interpretation Introduction

(b)

Interpretation:

Whether the imidazole has high or low water solubility is to be stated. The reason for the correct option is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Imidazole is a five-membered heterocyclic aromatic ring with two nitrogen atom is placed at C1 and C3 positions. It contains two types of nitrogen atom one is pyrrole type and one is pyridine type.

Answer 6

Chapter 26, Problem 26.6P

Interpretation Introduction

(a)

Interpretation:

The reason as to why pyridine is miscible in water and pyrrole is slightly soluble in water is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Pyridine is a six-membered heterocyclic aromatic ring where, a nitrogen atom is placed instead of a carbon atom. Pyrrole is a five-membered heterocyclic aromatic ring where a nitrogen atom is placed instead of a carbon atom.

Answer 7

Chapter 26, Problem 26.6P

Interpretation Introduction

(a)

Interpretation:

The reason as to why pyridine is miscible in water and pyrrole is slightly soluble in water is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Pyridine is a six-membered heterocyclic aromatic ring where, a nitrogen atom is placed instead of a carbon atom. Pyrrole is a five-membered heterocyclic aromatic ring where a nitrogen atom is placed instead of a carbon atom.

Answer 8

Interpretation Introduction

(b)

Interpretation:

Whether the imidazole has high or low water solubility is to be stated. The reason for the correct option is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Imidazole is a five-membered heterocyclic aromatic ring with two nitrogen atom is placed at C1 and C3 positions. It contains two types of nitrogen atom one is pyrrole type and one is pyridine type.

Answer 9

Interpretation Introduction

(b)

Interpretation:

Whether the imidazole has high or low water solubility is to be stated. The reason for the correct option is to be stated.

Concept introduction:

The tendency of the solid to dissolve in the solvent is known as solubility. Imidazole is a five-membered heterocyclic aromatic ring with two nitrogen atom is placed at C1 and C3 positions. It contains two types of nitrogen atom one is pyrrole type and one is pyridine type.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 26 - Prob. 26.1P Ch. 26 - Prob. 26.2P Ch. 26 - Prob. 26.3P Ch. 26 - Prob. 26.4P Ch. 26 - Prob. 26.5P Ch. 26 - Prob. 26.6P Ch. 26 - Prob. 26.7P Ch. 26 - Prob. 26.8P Ch. 26 - Prob. 26.9P Ch. 26 - Prob. 26.10P

Solution Summary: The author explains that pyridine is miscible in water due to the availability of lone pair of electrons.

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Chapter 26 Solutions