Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 2.6, Problem 24P
- a. Which of the halide ions (F−, Cl−, Br−, and I−) is the most stable base?
- b. Which is the least stable base?
- c. Which is the strongest base?
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a. Which of the halide ions (F - , Cl - , Br - , and I - ) is the most stable base? b. Which is the least stable base?
In each row of the table, select the stronger base.
N.
CH3
N.
CI
t
N.
Which is the more stable base? a. Br− or I− b. CH3O− or CH3S− c. CH3CH2O− or CH3COO− d. H2C CH or HC C− e. FCH2CH2COO− or CH2CH2COO- f. CLCH2CH2O- or CL2CHCH2O-
Chapter 2 Solutions
Essential Organic Chemistry, Global Edition
Ch. 2.1 - Which of the following are not acids? CH3COOH CO2...Ch. 2.1 - Draw the products of the acidbase reaction when a....Ch. 2.1 - a.What is the conjugate acid of each of the...Ch. 2.2 - a. Which is a stronger acid, one with a pKa of 5.2...Ch. 2.2 - Prob. 5PCh. 2.2 - Antacids are compounds that neutralize stomach...Ch. 2.2 - Are the following body fluids acidic or basic? a....Ch. 2.3 - Draw the conjugate acid of each of the following:...Ch. 2.3 - a. Write an equation showing CH3OH reacting as an...Ch. 2.3 - Prob. 10P
Ch. 2.3 - a. Which is a stronger base, CH3COO or HCOO? (The...Ch. 2.3 - Using the pKa values in Section 2.3, rank the...Ch. 2.4 - Prob. 13PCh. 2.5 - Prob. 14PCh. 2.5 - Ethyne has a pKa value of 25, water has a pKa...Ch. 2.5 - Which of the following bases can remove a proton...Ch. 2.6 - List the ions (CH3, NH2, HO, and F) in order from...Ch. 2.6 - List the carbanions shown in the margin in order...Ch. 2.6 - Which is a stronger acid?Ch. 2.6 - a. Draw the products of the following reactions: A...Ch. 2.6 - List the halide ions (F, Cl, Br, and I) in order...Ch. 2.6 - a. Which is more electronegative, oxygen or...Ch. 2.6 - Which is a stronger acid? a. HCl or HBr b....Ch. 2.6 - a. Which of the halide ions (F, Cl, Br, and I) is...Ch. 2.6 - Which is a stronger base? a. H2O or HO b. H2O or...Ch. 2.7 - Which is a stronger acid? a. CH3OCH2CH2OH or...Ch. 2.7 - Which is a stronger base?Ch. 2.8 - Fosamax has six acidic groups. The structure of...Ch. 2.8 - Which is a stronger acid? Why?Ch. 2.10 - For each of the following compounds (shown in...Ch. 2.10 - Prob. 33PCh. 2.11 - Write the equation that shows how a buffer made by...Ch. 2.11 - What products are formed when each of the...Ch. 2 - a. List the following alcohols in order from...Ch. 2 - Which is a stronger base? a. HS or HO b. CH3O or...Ch. 2 - Prob. 40PCh. 2 - a. List the following carboxylic acids in order...Ch. 2 - For the following compound, a. draw its conjugate...Ch. 2 - List the following compounds in order from...Ch. 2 - For each of the following compounds, draw the form...Ch. 2 - Give the products of the following acidbase...Ch. 2 - Prob. 46PCh. 2 - For each compound, indicate the atom that is most...Ch. 2 - Tenormin, a member of the group of drugs known as...Ch. 2 - From which acids can HO remove a proton in a...Ch. 2 - Prob. 50PCh. 2 - Which is a stronger acid? a. CH29CHCOOH or...Ch. 2 - Prob. 52PCh. 2 - Prob. 53PCh. 2 - How could you separate a mixture of the following...Ch. 2 - Prob. 1PCh. 2 - Prob. 2PCh. 2 - Draw the products of the following acidbase...Ch. 2 - Prob. 4PCh. 2 - Prob. 5PCh. 2 - Prob. 6PCh. 2 - Prob. 7PCh. 2 - Prob. 8PCh. 2 - Prob. 9PCh. 2 - Prob. 10PCh. 2 - Prob. 11PCh. 2 - Prob. 12PCh. 2 - Prob. 13PCh. 2 - Prob. 14P
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- Which is a stronger base?a. HS− or HO− b. CH3O− or CH3N-H c. CH3OH or CH3O− d. Cl− or Br−e. CH3COO− or CF3COO− f. CH3CHClCOO− or CH3CHBrCOO−arrow_forward4. Circle the stronger acid between each pair of compounds. Give the factor that would cause this. Draw the stronger conjugate b. base of the two. a. CF3CH₂OH A OH B A LOH B LOH Draw the stronger conjugate base of the two.arrow_forwardWhich is the stronger base? a. Br− or I− b. CH3O− or CH3S− c. CH3CH2O− or CH3COO− d. H2C CH or HC C− e. FCH2CH2COO− or BrCH2CH2COO− f. ClCH2CH2O− or Cl2CHCH2O−arrow_forward
- HBr + H2O → H3O+ + Br- What is the Bronsted base in the reaction above? a. H2O b. Br- c. H3O+ d. more than one choice is correctarrow_forwardWould the carboxyl group make the 3rd option the most acidic? Or would the fluorines make the 5th one the most acidic?arrow_forwardDraw the products of each acid–base reaction. Indicate whether equilibrium favors the reactants or products.arrow_forward
- For the following molecules, identify the acidic hydrogens from among those that are bolded. For each acidic hydrogen that you identify, draw the conjugate base that results from a base removing that acidic hydrogen. For molecules with more than one acidic hydrogen, draw a separate conjugate base for each one.arrow_forwardWhich is a stronger base?arrow_forwardFor each pair of bases, identify the stronger base.arrow_forward
- Which of the following is the strongest base? O a. Cl-CH2CH2NH2 Ob. Cl-CH2CH2CH2NH2 O c. Cl-aromatic ring-NH2 O d. Cl-CH2 -NH2 O e. C12-aromatic ring -NH2arrow_forwardWhich is the stronger acid?arrow_forwardConsider the following compounds: N. 'N' A C Of the 4 compounds, would be the strongest base and + would be the weakest base. ZI ZIarrow_forward
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