Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 25.5, Problem 9P
The membrane phospholipids in deer have a higher degree of unsaturation in cells closer to the hoof than in cells closer to the body. Why is this trait important for survival?
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Chapter 25 Solutions
Organic Chemistry (8th Edition)
Ch. 25.1 - Prob. 1PCh. 25.3 - Which has a higher melting point, glyceryl...Ch. 25.3 - Draw the structure of an optically inactive fat...Ch. 25.3 - Draw the structure of an optically active fat...Ch. 25.5 - Do the identities of R1 and R2 in phosphatidic...Ch. 25.5 - Membranes contain proteins, Integral membrane...Ch. 25.5 - Prob. 8PCh. 25.5 - The membrane phospholipids in deer have a higher...Ch. 25.6 - Treating PGC2 with a strong base such as sodium...Ch. 25.7 - Mark off the isoprene units in menthol, -selinene,...
Ch. 25.7 - Prob. 13PCh. 25.7 - Prob. 14PCh. 25.8 - Propose mechanisms for the Claisen condensation...Ch. 25.8 - Prob. 16PCh. 25.8 - Propose a mechanism for the conversion of...Ch. 25.8 - Propose a mechanism for the biosynthesis of...Ch. 25.8 - Propose a mechanism for the conversion of the E...Ch. 25.8 - The fluoro-substitued geranyl pyrophosphate shown...Ch. 25.8 - Prob. 22PCh. 25.8 - Prob. 23PCh. 25.9 - Draw the individual 1,2-hydride and 1,2-methyl...Ch. 25.10 - Prob. 26PCh. 25.10 - Prob. 27PCh. 25.10 - The acid component of a cholesterol ester is a...Ch. 25.10 - Prob. 29PCh. 25.10 - Prob. 30PCh. 25 - Prob. 31PCh. 25 - An optically active fat, when completely...Ch. 25 - Prob. 33PCh. 25 - a. How many different triacylglycerols are there...Ch. 25 - Cardiolipins are found in heart muscles. Draw the...Ch. 25 - Nutmeg contains a simple, fully saturated...Ch. 25 - Draw the product that is obtained from the...Ch. 25 - Prob. 39PCh. 25 - Prob. 40PCh. 25 - Propose a mechanism for the biosynthesis of...Ch. 25 - 5-Androstene-3.17-dione is isomerized to...Ch. 25 - Prob. 44PCh. 25 - Eudesmol is a sesquiterpene found in eucalyptus....Ch. 25 - Prob. 46PCh. 25 - Prob. 47PCh. 25 - Diethylstilbestrol (DES) was given to pregnant...
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- The following is a block diagram for a glycerophospholipid where the building blocks are labeled with letters and the linkages between building blocks are labeled with numbers. a. Which building blocks are fatty acid residues? b. Which building blocks are alcohol residues? c. Which linkages are ester linkages? d. Which linkages involve a phosphate residue?arrow_forwardBiological waxes have a head and two tails structure. Give the chemical identity of the head and of the two tails.arrow_forward21-85 Which of the following statements is (are) consistent with what is known about membranes? (a) A membrane consists of a layer of proteins sandwiched between two layers of lipids. (b) The compositions of the inner and outer lipid layers are the same in any individual membrane. (c) Membranes contain glycolipids and glycoproteins. (d) Lipid bilayers are an important component of membranes. (e) Covalent bonding takes place between lipids and proteins in most membranes.arrow_forward
- 21-101 Glycerophospholipids tend to have both a positive charge and a negative charge in their hydrophilic portions. Does this fact help or hinder lipid packing in membranes? Explain.arrow_forwardHow does the polarity of the phosphoglycerides contribute to their function of forming cell membranes?arrow_forward6 Where is glycogen stored in the human body?arrow_forward
- What functional group is common to all saponifiable lipids?arrow_forwardWhich of the substance categories biological wax, mineral wax, bile acid, and sphingophospholipid has each of the following characteristics? More than one substance may have a given characteristic. a. Structure is based on a steroid nucleus b. A saponifiable lipid c. Contains at least one fatty acid building block d. Contains at least one amide linkagearrow_forwardGive numerical answers to the following questions about the structure of a cholesterol molecule. a. How many six-membered rings arc present? b. How many amide linkages are present? c. How many hydroxyl substituents are present? d. How many total functional groups are present?arrow_forward
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