Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 25, Problem 36P
Nutmeg contains a simple, fully saturated triacylglycerol with a molecular weight of 722. Draw its structure.
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Nutmeg contains a simple, fully saturated triacylglycerol with a molecular weight of 722. Draw its structure.
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A mixed triacylglycerol that contains one saturated 8-carbon fatty acid chain and two 6-carbon fatty acid chains with 2 trans double bonds each.
4. The ester you drew in Question #1 has a melting point range of 32-35 °C. The methyl ester of mono-unsaturated
palmitoleic acid (IUPAC name: hexadec-9enoic acid) has a considerably lower melting point range: -0.5-+0.5 °C.
a) Explain what it means for a fatty acid to the "mono-unsaturated."
b) Illustrate your explanation by drawing the structure of the methyl ester of octadec-11-enoic acid. (Be sure to draw
the geometric stereoisomer that is commonly found in nature.)
Chapter 25 Solutions
Organic Chemistry (8th Edition)
Ch. 25.1 - Prob. 1PCh. 25.3 - Which has a higher melting point, glyceryl...Ch. 25.3 - Draw the structure of an optically inactive fat...Ch. 25.3 - Draw the structure of an optically active fat...Ch. 25.5 - Do the identities of R1 and R2 in phosphatidic...Ch. 25.5 - Membranes contain proteins, Integral membrane...Ch. 25.5 - Prob. 8PCh. 25.5 - The membrane phospholipids in deer have a higher...Ch. 25.6 - Treating PGC2 with a strong base such as sodium...Ch. 25.7 - Mark off the isoprene units in menthol, -selinene,...
Ch. 25.7 - Prob. 13PCh. 25.7 - Prob. 14PCh. 25.8 - Propose mechanisms for the Claisen condensation...Ch. 25.8 - Prob. 16PCh. 25.8 - Propose a mechanism for the conversion of...Ch. 25.8 - Propose a mechanism for the biosynthesis of...Ch. 25.8 - Propose a mechanism for the conversion of the E...Ch. 25.8 - The fluoro-substitued geranyl pyrophosphate shown...Ch. 25.8 - Prob. 22PCh. 25.8 - Prob. 23PCh. 25.9 - Draw the individual 1,2-hydride and 1,2-methyl...Ch. 25.10 - Prob. 26PCh. 25.10 - Prob. 27PCh. 25.10 - The acid component of a cholesterol ester is a...Ch. 25.10 - Prob. 29PCh. 25.10 - Prob. 30PCh. 25 - Prob. 31PCh. 25 - An optically active fat, when completely...Ch. 25 - Prob. 33PCh. 25 - a. How many different triacylglycerols are there...Ch. 25 - Cardiolipins are found in heart muscles. Draw the...Ch. 25 - Nutmeg contains a simple, fully saturated...Ch. 25 - Draw the product that is obtained from the...Ch. 25 - Prob. 39PCh. 25 - Prob. 40PCh. 25 - Propose a mechanism for the biosynthesis of...Ch. 25 - 5-Androstene-3.17-dione is isomerized to...Ch. 25 - Prob. 44PCh. 25 - Eudesmol is a sesquiterpene found in eucalyptus....Ch. 25 - Prob. 46PCh. 25 - Prob. 47PCh. 25 - Diethylstilbestrol (DES) was given to pregnant...
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- V F2 # 3 E 80 F3 What is the difference between integral and peripheral proteins? $ 4 F4 R A) Integral proteins are required for the cell to function, while peripheral proteins are accessory. B) Integral proteins are found on the outside of the cell, while peripheral proteins are found on the inside of the cell. C) Integral proteins extend through the lipid bilayer, and peripheral proteins are just on the surface of the inside or outside of the cell. Question 11 of 19 D) Integral proteins are found on the inside of the cell, while peripheral proteins are found on the outside of the cell. E) Integral proteins are channel proteins and peripheral proteins act as enzymes. % 5 F5 T <6 MacBook Air F6 Y & 7 ♡ F7 U * 8 DII F8 1 ( - 9 F9 0 O F10arrow_forwardChetoarrow_forwardA lipid has the following structure: CH2-O-CH2-(CH2)16CH3 0 CH-O-C-(CH2)4CH=CHCH2CH=CH(CH2)7CH3 0 || CH2-O-C-(CH2)4CH-CHCH2CH=CH(CH2)7CH3 Which of the statements are true or false about the structure above Both this structure and a wax contain one or more carboxyl groups This lipid and a prostaglandin can both be hydrolyzed in acid to create fatty acids This lipid and a thromboxane can both be hydrolyzed in base to produce soaps Both this lipid and a terpene can be very hydrophobic molecules Based on its structural similarity to other lipids, this lipid most likely functions as a membrane component Both this structure and a wax contain one or more ester bonds This lipid and an arachidonic acid both contain glycerol and hydrocarbon chains Based on its structural similarity to other lipids, this lipid most likely functions as an energy storage molecule Both this lipid and a terpene can contain isoprene This lipid and a leukotriene are both polyunsaturated molecules Both this structure…arrow_forward
- Explain why cholesterol, a compound with molecular formula C 27H 46O and one OH group, is soluble in CCl 4 but insoluble in water.arrow_forward2 bonds to a glycerol molecule? 12. Detergent molecules are phospholipidlike molecules with highly polar heads and nonpolar tails. Why is it a good idea to wear rubber gloves when washing dishes using detergents? 3 4 O M T MacBo G Search dr type URL 5arrow_forwardDraw the skeletal ("line") structure of an omega-6 monounsaturated fatty acid with 12 carbons. Give detailed Solution with explanation needed, don't give Handwritten answer.arrow_forward
- Please don't provide handwriting solutionarrow_forwardChoose the best classification for the molecule shown below. OH NH A) glycerophospholipid B) fatty acid C) steroids D) triglyceride E) sphingolipidarrow_forward11. If in lab you run out of dichloromethane (CH₂Cl₂), but you have carbon tetra- chloride (CC14) and acetone (C3H6O), would you predict that either, neither or both work to achieve this lipid extraction from water? Draw the Lewis struc- tures and use molecular shape, molecular polarity and intermolecular forces between (including between solvent and water) in your explanation.arrow_forward
- Consider we have a fatty acid that is described by 20:3 (8, 11, 14), what is its structure going to be? Draw its structure and identify what type of omega it is.arrow_forwardDraw a skeletal structure for each fatty acid. (b) Label the hydrophobic and hydrophilic portions of each molecule. (c) Without referring to Table 19.2 , which fatty acid has the higher melting point, A or B? Explain your choice. CH3(CH2)16COOH CH3(CH2)4CH CHCH2CH CH(CH2)7COOHarrow_forwardDraw the skeletal ("line") structure of a saturated fatty acid with 8 carbons. Continue 143 Click and drag to start drawing a structure. D с с X S e ->>arrow_forward
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