Organic Chemistry (8th Edition)
8th Edition
ISBN: 9780134042282
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Textbook Question
Chapter 25, Problem 36P
Nutmeg contains a simple, fully saturated triacylglycerol with a molecular weight of 722. Draw its structure.
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Nutmeg contains a simple, fully saturated triacylglycerol with a molecular weight of 722. Draw its structure.
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Chapter 25 Solutions
Organic Chemistry (8th Edition)
Ch. 25.1 - Prob. 1PCh. 25.3 - Which has a higher melting point, glyceryl...Ch. 25.3 - Draw the structure of an optically inactive fat...Ch. 25.3 - Draw the structure of an optically active fat...Ch. 25.5 - Do the identities of R1 and R2 in phosphatidic...Ch. 25.5 - Membranes contain proteins, Integral membrane...Ch. 25.5 - Prob. 8PCh. 25.5 - The membrane phospholipids in deer have a higher...Ch. 25.6 - Treating PGC2 with a strong base such as sodium...Ch. 25.7 - Mark off the isoprene units in menthol, -selinene,...
Ch. 25.7 - Prob. 13PCh. 25.7 - Prob. 14PCh. 25.8 - Propose mechanisms for the Claisen condensation...Ch. 25.8 - Prob. 16PCh. 25.8 - Propose a mechanism for the conversion of...Ch. 25.8 - Propose a mechanism for the biosynthesis of...Ch. 25.8 - Propose a mechanism for the conversion of the E...Ch. 25.8 - The fluoro-substitued geranyl pyrophosphate shown...Ch. 25.8 - Prob. 22PCh. 25.8 - Prob. 23PCh. 25.9 - Draw the individual 1,2-hydride and 1,2-methyl...Ch. 25.10 - Prob. 26PCh. 25.10 - Prob. 27PCh. 25.10 - The acid component of a cholesterol ester is a...Ch. 25.10 - Prob. 29PCh. 25.10 - Prob. 30PCh. 25 - Prob. 31PCh. 25 - An optically active fat, when completely...Ch. 25 - Prob. 33PCh. 25 - a. How many different triacylglycerols are there...Ch. 25 - Cardiolipins are found in heart muscles. Draw the...Ch. 25 - Nutmeg contains a simple, fully saturated...Ch. 25 - Draw the product that is obtained from the...Ch. 25 - Prob. 39PCh. 25 - Prob. 40PCh. 25 - Propose a mechanism for the biosynthesis of...Ch. 25 - 5-Androstene-3.17-dione is isomerized to...Ch. 25 - Prob. 44PCh. 25 - Eudesmol is a sesquiterpene found in eucalyptus....Ch. 25 - Prob. 46PCh. 25 - Prob. 47PCh. 25 - Diethylstilbestrol (DES) was given to pregnant...
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- higher melting point)? why *What are the products of saponification (hydrolysis with NaOH as the catalyst) of 1-stearoyl-2,3-dipalmitoylglycerol. Xarrow_forwardDraw a skeletal structure for each fatty acid. (b) Label the hydrophobic and hydrophilic portions of each molecule. (c) Without referring to Table 19.2 , which fatty acid has the higher melting point, A or B? Explain your choice. CH3(CH2)16COOH CH3(CH2)4CH CHCH2CH CH(CH2)7COOHarrow_forwardTravoprost is a drug used to treat the build-up of pressure in the eye. It is administered as eye drops. HO CF3 ÕH Travoprost (pressure inside the eye, including glaucoma) a) Redraw the structure and incorporate suitable modifications or functional group(s) to: i) increase the polarity of the molecule ii) increase the lipophilicity of the molecule In each case, briefly explain what change(s) you have incorporated and the rationale behind your structural modification. b) Redraw the structure and identify 5 sites that could be targeted by metabolic enzymes, such as cytochrome P450s or transferases. Show two examples of structures arising from potential metabolic activity, using an enzyme or enzymes of your choice.arrow_forward
- 25. Which of the following statements regarding the physical properties of triacylglycerol is FALSE? -In general, the melting point of a triacylglycerol increases as the degree of unsaturation increases. -In general, the melting point of a triacylglycerol decreases as the degree of unsaturation increases. -In general, the melting point of a triacylglycerol increases as the number of carbons in the hydrocarbon chain increases. -In general, triacylglycerol with saturated fatty acids are solids are room temperature.arrow_forwardH. H. N. O. OH H. 1(f) Describe the preparation of soap from triacylglycerides. Use a reaction scheme to help you.arrow_forwarda.) Draw the line angle structural formula for the ester in jojoba wax that is formed from arachidic acid, a 20-carbon saturated fatty acid, and 1-docosanol, CH3 —(CH2)21 —OH. b.) Draw the line angle structural formula for a mixed triacylglycerol that contains two palmitic acid molecules and one oleic acid molecule on the center carbon of glycerol.arrow_forward
- Which of the following statements is true16. lodoform, which has a molecular formula of CHal, is indicative that a ketomethyl group is present. 17. Based on the physical property, hydroquinone has a lower boiling point compared to catechol. 18. When FeCl3 is used in visualizing aspirin in thin layer chromatography, the resulting spot is red in color.arrow_forward(a) Draw a skeletal structure of the anabolic steroid 4-androstene-3,17-dione, also called "andro," from the following description. Andro contains the tetracyclic steroid skeieton with carbonyl groups at C3 and C17, a double bond between C4 and C5, and methyl groups bonded to C10 and C13. (b) Add wedges and dashes for all stereogenic centers with the following information: the configuration at C10 is R, the configuration at C13 is S, and all substituents at ring fusions are trans to each other.arrow_forwardCertain omega-3 fatty acids can be found only in animal sources, such as fatty fish. Two of these are eicosapentaenoic acid (EPA) [20:5] and docosahexaenoic acid (DHA) [22:6], both of which are ω-3 fatty acids. DHA has been shown to be important in healthy brain development, so it has recently been added to infant formulas. Breast milk is rich in DHA as long as the mother maintains a healthy diet that includes fish. Draw skeletal structures of the fatty acids EPA and DHA.arrow_forward
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