At pH 9.5 which form of lysine will predominate need to be found out. Concept introduction: Amino acid has both carboxylic acid and amine functional group . In presence of acid or base either one form will predominate which depends upon the pK a value. Usually the carboxylic acid group is deprotonated first and then the amino group is deprotonated. At higher pH the carboxylic acid gets deprotonated and at lower pH the amino group gets protonated. The carboxylic acid form will predominate over carboxylate form if pH<pK a and vice-versa. The protonated form of α amino will predominate over the α amino form if pH<pK a and vice-versa. If side chain is present the same rule as above applies. To draw : To draw the form of lysine which predominates at pH of 9.5

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Chapter 25.2, Problem 1LTS

Interpretation Introduction

Interpretation:

At pH 9.5 which form of lysine will predominate need to be found out.

Concept introduction:

Amino acid has both carboxylic acid and amine functional group. In presence of acid or base either one form will predominate which depends upon the pK_a value. Usually the carboxylic acid group is deprotonated first and then the amino group is deprotonated. At higher pH the carboxylic acid gets deprotonated and at lower pH the amino group gets protonated.

The carboxylic acid form will predominate over carboxylate form if pH<pKa and vice-versa.

The protonated form of α amino will predominate over the α amino form if pH<pKa and vice-versa.

If side chain is present the same rule as above applies.

To draw: To draw the form of lysine which predominates at pH of 9.5

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