ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
4th Edition
ISBN: 9781119659587
Author: Klein
Publisher: WILEY
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Chapter 25, Problem 65PP
Interpretation Introduction

Interpretation:

Bond-line structure of Trp-Val-Ser-Met-Gly-Glu needs to be drawn.

Concept introduction:

Bond-line structure is the representation of organic structural formulas in a shorthand manner.  In this case only the bond between carbon and other atoms are shown except hydrogen.  It is understood that all the remaining valency to be filled by hydrogen.  Apart from carbon atoms the other atoms are shown along with hydrogen.  For drawing a peptide sequence in bond-line structure the steps need to be followed are,

  • Draw the peptide with correct number of residues
  • The side chain associated with the residue has to be identified
  • Assign proper configuration for the residues

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)

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