ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)
4th Edition
ISBN: 9781119659587
Author: Klein
Publisher: WILEY
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Chapter 25, Problem 44PP
Interpretation Introduction

Interpretation:

All stereoisomers of L-isoleucine has to be drawn along with chiral information.

Concept introduction:

Stereoisomers are the compounds which have the same structural entry but differ in the configuration at the chiral centers.  If a compound has only one stereo center then that compound has one stereoisomer.  If it has two stereocenters then that compound has four stereoisomers.  The number of stereoisomers possible can be found out by a formula,

Number of stereoisomers = (2)number of stereocenters

To draw : To draw all the stereoisomers of isoleucine

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?
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Chapter 25 Solutions

ORGANIC CHEMISTRY-STUD.SOLNS.MAN+SG(LL)

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