Concept explainers
(a)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 1
Explanation of Solution
The name of the given molecule suggests that a nitrogen atom is bonded to cyclopentane and isobutyl group. Cyclopentane consists of five carbon atoms. Therefore, the structure of the given compound is,
Figure 1
The structure that corresponds to the given name is shown in Figure 1.
(b)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 2
Explanation of Solution
The name of the given compound is tri-tert-butylamine. Prefix ‘tri’ shows that a nitrogen atom is bonded to three tert-butyl groups. Therefore, the structure of the given compound is,
Figure 2
The structure that corresponds to the given name is shown in Figure 2.
(c)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 3
Explanation of Solution
The name of the given compound is N, N-diisopropylaniline. Prefix ‘di’ shows that a nitrogen atom is bonded to two isopropyl groups and it is bonded to six membered
Figure 3
The structure that corresponds to the given name is shown in Figure 3.
(d)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 4
Explanation of Solution
The name of the given compound is N-methylpyrrole. Pyrrole is the parent chain of the given compound. It is an aromatic five membered ring which contains nitrogen atom and two double bonds. The nitrogen atom is bonded to methyl group. Therefore, the structure of the given compound is,
Figure 4
The structure that corresponds to the given name is shown in Figure 4.
(e)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 5
Explanation of Solution
The name of the given compound is N-methylcyclopentanamine. The name suggests that nitrogen atom is bonded to cyclopentane and methyl group. Therefore, the structure of the given compound is,
Figure 5
The structure that corresponds to the given name is shown in Figure 5.
(f)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 6
Explanation of Solution
The name of the given compound is
Figure 6
The structure that corresponds to the given name is shown in Figure 6.
(g)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 7
Explanation of Solution
The name of the given compound is
Figure 7
The structure that corresponds to the given name is shown in Figure 7.
(h)
Interpretation: The structure that corresponds to the given name is to be drawn.
Concept introduction: One should follow the given three steps to derive the structure of the compound from its IUPAC name. The first step involves the identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in either direction. The third step is addition of substituents at appropriate carbon atoms.
Answer to Problem 25.39P
The structure that corresponds to the given name is,
Figure 8
Explanation of Solution
The name of the given compound is (S)-heptan-
Figure 8
The structure that corresponds to the given name is shown in Figure 8.
Want to see more full solutions like this?
Chapter 25 Solutions
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
- Reduction of an alkyl azide results in the formation of —-. A. an imine B. an oxime C. a tertiary amine D. a secondary amine E. a primary aminearrow_forward19. Which of the following best describes the molecule shown below? H. CH3 N. A. Secondary amine 8. Methylaminocyclohexane C. Cyclocarboxylic acid D. A cycloalkanearrow_forward2. Draw out the following compounds. a. N-methylaniline b. Triisopropylamine c. N,N-dipropylhexylamine d. 1,5-pentanediamine (Also known as Cadaverine for its smell)arrow_forward
- Instructions: DRAW a structure corresponding to each name a. 3-hexanamine b. N-methylpentylamine c. p-nitroaniline d. N-methylpiperidine e. N,N-dimethylethylamine f. 2-aminocyclohexanone g. 1-propylcyclohexanamine h. N-propylanilinearrow_forward1. What is the product of the reaction? 1) LAH 2) Hо* но OH а. b. OH с. HO. HO. d. 2. Which amine is expected to be least soluble in HzO? `NH2 а. c. N. b. d. ZIarrow_forwardInstructions: Give an acceptable name for eachester. A. CH, CH2)CO,CH, B. COCHỊCH, C. CH₂CH₂CH₂CH₂COOCH₂CH₂CH₂ Instructions: Give the structure corresponding to each name. a. propyl propanoate b. butyl acetate c. ethyl hexanoate d. methyl benzoate Instructions: Give an acceptable name for each amide A. CH₂CH₂CH₂CH₂ NH₂ Instructions: Draw the structure of each amide. A. N,N-dimethylacetamidearrow_forward
- 1. Draw the skeletal structure corresponding to each of the following namesarrow_forwardErythronolide B is the biological precursor of erythromycin, a broad-spectrum antibiotic. What functional group Erythronolide B does contain? a. b. H₂CH₂C C. H₂C 1 H₂C 2 3 4 O Amide d. Amine OH Erythronolide B Ketone Aldehyde a CH₂ b C d CH₂ OH JCH₂ 'OH OHarrow_forwardAmines will not react with which of the follow ing? alkyl halides b. carboxylic acids 52. а. с. Ketones d. hydrogen chloride Which statement below is incorrect? the smallest aldehyde has the formula HCOH a carbonyl carbon cons ists of a carbon-oxygen double bond in an aldehyde, the carbonyl carbon is always bonded to a hydrogen atom d. 53. а. b. с. Ketones are more soluble in water than alcohols with the equiva lent number of carbonsarrow_forward
- which amines are primary, secondary, tertiary or quaternaryarrow_forward1. Complete each of the following by supplying the missing reagents. Draw thestructures of each of the reactants and products.a. N-methylpropanamide + ? → methanamine + ?b. Formamide + strong acid → ? + ? 2. Write the structure of the following: N-Propylhexanamide Propionamide N-Methylpropanamidearrow_forwardDraw the structure corresponding to each name. a. 2-hydroxyheptanoic acid b. 4-chlorononanoic acid c. 3,4-dibromobenzoic acid d. lithium propanoate e. 2,2-dibromobutanoic acid f. ethyl 2-methylpropanoatearrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning