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Concept explainers
(a)
Interpretation: The carbonyl and nitrogen compounds needed to prepare the given compound using reductive amination are to be determined.
Concept introduction: The conversion of
(b)
Interpretation: The carbonyl and nitrogen compounds needed to prepare the given compound using reductive amination are to be determined.
Concept introduction: The conversion of aldehydes and ketones into amines is known as reductive amination. The first step is the formation of imines using aldehydes or ketones and amines. The second step involves the reduction of imine to form amine. The best reagent for this reaction is sodiumcyanoborohydride.
(c)
Interpretation: The carbonyl and nitrogen compounds needed to prepare the given compound using reductive amination are to be determined.
Concept introduction: The conversion of aldehydes and ketones into amines is known as reductive amination. The first step is the formation of imines using aldehydes or ketones and amines. The second step involves the reduction of imine to form amine. The best reagent for this reaction is sodiumcyanoborohydride.
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Chapter 25 Solutions
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
- Maraviroc, a drug used to treat HIV, is prepared by reductive amination of aldehyde A with amine B. What is the structure of maraviroc, if the most basic N atom of amine B is used in reductive amination?arrow_forwardThe order of increasing acidity is Phenol < meta-cyanophenol < ortho-cyanophenol 1.how about para-cyanophenol??does it has higher acidicity than both ortho-cyanophenol and meta cyanophenol or lower?? 2.why does ortho-cyanophenol have higher acidicity than meta cyanophenol?? 3. why doesmeta cyanophenol have higher acidicity than Phenolarrow_forwardExplain why imidazolides are much more reactive than other amides in nucleophilic acyl substitution.arrow_forward
- 12) Which compound is stronger base? a) b) D A d) all the samearrow_forwardProblem 22 of 44 Draw the major product of this reaction. Ignore inorganic byproducts. Submit Assume that the water side product is continuously removed to drive the reaction toward products. PhNHNH2, TSOH Select to Drawarrow_forward16.41) Give on IUPAC or common home for each compound. 2 b. in O d. Hon de jha ok C. e- ion ganho-to- 0 y. ho Y 2-ethylbutonoyl chloride methyl benzoate N-ethyl-N-methylpropion amide ethyl formale benzoic propionic anhydride isopropyl 3-ethyl hexanoatearrow_forward
- Devise a synthesis of each compound from the given starting material(s). Albuterol is a bronchodilator and proparacaine is a local anesthetic.arrow_forwardDevise a synthesis of each compound from aniline (C6H5NH2).arrow_forwardWhich compound is stronger base in each set of compounds? a. (i) HOCH2CH2NH2 or (ii)CH3CH2NH2 b. (i) (ii) orarrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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