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Concept explainers
(a)
Interpretation: The given compounds are to be arranged in order of increasing basicity.
Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electrons are termed as bases and the electron acceptors are known as acids.
(b)
Interpretation: The given compounds are to be arranged in order of increasing basicity.
Concept introduction: According to Lewis acid-base theory, the compounds which can donate its lone pair of electrons are termed as bases and the electron acceptors are known as acids. Amines act like a base as the nitrogen atom contains one lone pair of electrons.
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Chapter 25 Solutions
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
- Rank the attached ions in order of increasing basicity.arrow_forwardAmphetamine is a powerful stimulant of the central nervous system. (a) Which proton in amphetamine is most acidic? (b) What products are formed when amphetamine is treated with NaH? (c) What products are formed when amphetamine is treatedarrow_forwardA. Compound II is more basic than compound I. B. Compound I is more basic than compound II. C. Cannot be compared D. Both compounds have the same basicityarrow_forward
- Decide which N atom in each molecule is most basic, and draw theproduct formed when each compound is treated with CH3CO2H.Zolpidem (trade name Ambien) is used to treat insomnia, whereasaripiprazole (trade name Abilify) is used to treat depression,schizophrenia, and bipolar disorders.arrow_forwardWhat carbonyl compound and amine or alcohol are needed to prepare each product?arrow_forwardWhat carbonyl compound and amine are formed by the hydrolysis of each compound?arrow_forward
- Rank the labeled N atoms in the anticancer drug imatinib (trade nameGleevec) in order of increasing basicity. Imatinib, sold as a salt withmethanesulfonic acid (CH3SO3H), is used for the treatment of chronicmyeloid leukemia as well as certain gastrointestinal tumors.arrow_forwardDraw the conjugate acid of each base. H. H. draw structure. draw structure H.C draw structurearrow_forward6.58 Rank the following species from weakest base to strongest base. B Но. E. Garrow_forward
- 18.64 The following two compounds each exhibit two heteroatoms (one nitrogen atom and one oxygen atom). :0 Compound A -N Compound B O In compound A, the lone pair on the nitrogen atom is more likely to function as a base. However, in compound B, the lone pair on the oxygen atom is more likely to function as a base. Explain this difference.arrow_forwardVarenicline (trade name Chantix) is a drug used to help smokers quittheir habit. (a) Which N atom in varenicline is most basic? Explain your choice. (b) What product is formed when varenicline is treated with HCl?arrow_forward&:&::&&:&;;&arrow_forward
- Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
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