Biochemistry
Biochemistry
6th Edition
ISBN: 9781305577206
Author: Reginald H. Garrett, Charles M. Grisham
Publisher: Cengage Learning
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Chapter 25, Problem 13P
Interpretation Introduction

Interpretation:

To determine the Aspartame structure in Merck Index and to reason out why this substance should be avoided by people with phenylketonuria

Concept Introduction:

Aspartame, the artificial sweetener used in place of sugar in some of the foods and beverages is methyl ester of phenylalanine dipeptide/aspartic acid.

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TABLE 3-1 Properties and Conventions Associated with the Amino Acids pk, values Amino acid Phenylalanine Tyrosine Tryptophan 5.66 5.48 9.59 5.89 Abbreviation/ symbol 6.14 Phe F Tyr Y Trp W pk, M, (-COOH) 165 181 204 . 1.83 2.20 2.38 Using the table 3-1, calculate the pl of Tyrosine. Hint: Consider the structure and overall charge of the molecule between each pka. pK₂2 (-NH) 9.13 9.11 9.39 PKR (R group) 10.07
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