Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 24, Problem 24.11P
Interpretation Introduction
Interpretation:
The reason for the fact that talose contains a smaller fraction of
Concept introduction:
The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula,
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Provide an explanation for the fact that α-D-mannose is more stable thanβ-D-mannose, whereas the opposite is true for glucose.
Which statement about saccharides is correct?
(A). Alpha anomers are more common than beta anoomers.
(B). Two monosaccharides can form a disaccharide and oxygen.
(C). Polysaccharides with alpha or beta glycosidic linkages have the different properties.
(D). Disaccharides can be cyclic or acyclic.
In addition to lactose, D-galactose and D-glucose can form different heterodisaccharides. Draw the structures (Haworth projections) of the (i) a-glucose-(1→1) -a-galactose and ii) a- glucose-(1→3)-?-galactose, two examples of heterodisaccharides that can form.
Chapter 24 Solutions
Organic Chemistry Study Guide and Solutions
Ch. 24 - Prob. 24.1PCh. 24 - Prob. 24.2PCh. 24 - Prob. 24.3PCh. 24 - Prob. 24.4PCh. 24 - Prob. 24.5PCh. 24 - Prob. 24.6PCh. 24 - Prob. 24.7PCh. 24 - Prob. 24.8PCh. 24 - Prob. 24.9PCh. 24 - Prob. 24.10P
Ch. 24 - Prob. 24.11PCh. 24 - Prob. 24.12PCh. 24 - Prob. 24.13PCh. 24 - Prob. 24.14PCh. 24 - Prob. 24.15PCh. 24 - Prob. 24.16PCh. 24 - Prob. 24.17PCh. 24 - Prob. 24.18PCh. 24 - Prob. 24.19PCh. 24 - Prob. 24.20PCh. 24 - Prob. 24.21PCh. 24 - Prob. 24.22PCh. 24 - Prob. 24.23PCh. 24 - Prob. 24.24PCh. 24 - Prob. 24.25PCh. 24 - Prob. 24.26PCh. 24 - Prob. 24.27PCh. 24 - Prob. 24.28PCh. 24 - Prob. 24.29PCh. 24 - Prob. 24.30PCh. 24 - Prob. 24.31PCh. 24 - Prob. 24.32PCh. 24 - Prob. 24.33PCh. 24 - Prob. 24.34APCh. 24 - Prob. 24.35APCh. 24 - Prob. 24.36APCh. 24 - Prob. 24.37APCh. 24 - Prob. 24.38APCh. 24 - Prob. 24.39APCh. 24 - Prob. 24.40APCh. 24 - Prob. 24.41APCh. 24 - Prob. 24.42APCh. 24 - Prob. 24.43APCh. 24 - Prob. 24.44APCh. 24 - Prob. 24.45APCh. 24 - Prob. 24.46APCh. 24 - Prob. 24.47APCh. 24 - Prob. 24.49APCh. 24 - Prob. 24.50APCh. 24 - Prob. 24.51APCh. 24 - Prob. 24.52APCh. 24 - Prob. 24.53APCh. 24 - Prob. 24.54APCh. 24 - Prob. 24.55APCh. 24 - Prob. 24.56APCh. 24 - Prob. 24.57APCh. 24 - Prob. 24.58APCh. 24 - Prob. 24.59APCh. 24 - Prob. 24.60APCh. 24 - Prob. 24.61APCh. 24 - Prob. 24.62AP
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- Consider N-acetyl-d-glucosamine Q.) Draw a chair conformation for the disaccharide formed by joining two units of the pyranose form of N-acetyl-d-glucosamine by a b-1,4-glycosidic bond. If you draw this correctly, you have the structural formula for the repeating dimer of chitin, the structural polysaccharide component of the shell of lobsters and other crustaceans.arrow_forwardMonosaccharides can be categorized in terms of thenumber of carbon atoms (pentoses have five carbons andhexoses have six carbons) and according to whether theycontain an aldehyde (aldo- prefix, as in aldopentose) orketone group (keto- prefix, as in ketopentose). Classify glucoseand fructose in this way.arrow_forwardA reddish color is obtained when compound A (a disaccharide) is reacted with Benedict solution. Is this compound more likely maltose or sucrosearrow_forward
- Show the dehydration reaction of the following disaccharides and describe their functions, importance, sources and structures. a. Lactose b. Maltose C. sucrosearrow_forwardCellobiose, a disaccharide obtained by the hydrolysis of cellulose, is composed of two glucose units joined together in a 1→4-β-glycoside bond. What is the structure of cellobiose?arrow_forwardIllustrate (hand-drawn) the mechanism of intrahemiacetal or intrahemiketal formation in the following monosaccharides and identify/draw the possible products of these reactions. A. D-talose B. D-fructosearrow_forward
- Question 21 Match the structures with the description NH NH CHO CH HO CH, HO HỌ CH, NICH H. ocit, CH, он он HO но- HO HO он CH2 OH >arrow_forward1 Draw D- glucose in a Fischer Projection. 2 Draw alpha-D- glucose and in the Hayworth (ring ) structure. 3 Draw the hydrolysis of maltose- the disaccharide composed of alpha D glucose molecules. 4 What is the chemical difference between cellulose and amylose NOTE- please dont explain too much explain to the pointarrow_forwardAmygdalin is a toxic component in the pits of bitter almonds, peaches, and apricots. Q.) Name the two monosaccharide units in amygdalin and describe the glycosidic bond by which they are joined.arrow_forward
- Draw the structures (using chair conformations of pyranoses) of the following disaccharides. a-d-fructofuranosyl-b-d-mannopyranoside(arrow_forward3. HO" он HO. но, но HO OH Solanine Solanine is a naturally occurring compound that contain glycoside bonds as part of its structure. Determine the structure of aglycon and monosaccharides fomed when solanine is hydrolyzed with aqueous acid. Include all the appropriate anomers.arrow_forwardArabinoxylan is a copolymer of arabinose and xylose-two five-carbon sugars. A portion of the polysaccharide is shown here. (a) Identify and classify each glycosidic linkage. (b) Based on the structure, do you think arabinoxylan functions as a storage polysaccharide or a structural polysaccharide? Explain your reasoning. HOH,C. OH Но OH OH но но OH Но LO. Но HOH,C HOH2C НО OH OH CH,OHarrow_forward
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