Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 24, Problem 24.11P
Interpretation Introduction

Interpretation:

The reason for the fact that talose contains a smaller fraction of β-pyranose form than glucose is to be stated.

Concept introduction:

The compounds which are composed of carbon, hydrogen, and oxygen possessing the general formula, Cx(H2O)y are known as carbohydrates. These are the organic compounds obtained from the green plants. The basic sugar or carbohydrate needed by a living organism as a source of energy is known as glucose with the molecular formula, C6H12O6.

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Provide an explanation for the fact that α-D-mannose is more stable thanβ-D-mannose, whereas the opposite is true for glucose.
Which statement about saccharides is correct? (A). Alpha anomers are more common than beta anoomers. (B). Two monosaccharides can form a disaccharide and oxygen. (C). Polysaccharides with alpha or beta glycosidic linkages have the different properties. (D). Disaccharides can be cyclic or acyclic.
In addition to lactose, D-galactose and D-glucose can form different heterodisaccharides. Draw the structures (Haworth projections) of the (i) a-glucose-(1→1) -a-galactose and ii) a- glucose-(1→3)-?-galactose, two examples of heterodisaccharides that can form.
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