Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 24, Problem 24.29P
Interpretation Introduction

Interpretation:

The structure of two aldoses obtained from the given illustration is to be assigned.

Concept Introduction:

In Ruff degradation reaction, aldose is oxidized to aldonic acid. Calcium salts of aldonic acid react with ferric ion and hydrogen peroxide to give decarboxylated calcium salts of aldonic acid. The C2 carbon of aldose oxidizes to aldehyde group.

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