Organic Chemistry Study Guide and Solutions
Organic Chemistry Study Guide and Solutions
6th Edition
ISBN: 9781936221868
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 24, Problem 24.9P
Interpretation Introduction

Interpretation:

The details of the acid-catalyzed mutarotation of glucopyranose are to be stated.

Concept introduction:

Mutarotation is the phenomenon by which the two forms of glucopyranose: α- glucopyranose and β- glucopyranose remain in equilibrium when dissolved in water. The α- glucopyranose gets converted into β- glucopyranose with time by acid-base catalyzed mutarotation of glucopyranose and vice a versa.

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2. (15 points) Draw an appropriate mechanism for the following reaction. H N. H* + H₂O
Draw a tripeptide of your choosing at pH 7. Have the N-terminus on the left and the C-terminus on the right. Then: Draw a triangle around the α-carbons. Draw a box around the R-groups. Circle the atoms capable of hydrogen bonding. Highlight the atoms involved in the formation of the peptide bonds. What type of structure have you drawn? (primary, secondary, tertiary or quaternary protein structure). make sure its a tripeptide
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