CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
4th Edition
ISBN: 9781260562620
Author: SMITH
Publisher: MCG
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Chapter 23, Problem 38P
When a substrate is reduced, is
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Is
FAD + 2H=FADH2
an oxidation or reduction reaction?
Consider this chemical reaction. What chemical is the oxidizing agent?
COO™
HIC-H
HIC-H FAD FADH₂
COO™
succinate
FADH2
succinate
FAD
fumarate
succinate
dehydrogenase
COO™
H-C
-H
COO
fumarate
Refer to the following reaction. The substrate of this reaction is called
through a mechanism called "Feed Forward Activation".
(A) Phosphoenolpyruvate, Fructose 1,6-bisphosphate
Lactate, NADH
OPO₂²-
ADP ATP
J = 4
O
H₂C
H₂C
2-phosphoglycerate, AMP
Glyceraldehyde 3-phosphate, ATP
and the enzyme is activated by high conc. of
Chapter 23 Solutions
CONNECT IA GENERAL ORGANIC&BIO CHEMISTRY
Ch. 23.2 - Prob. 23.1PCh. 23.3 - Prob. 23.2PCh. 23.3 - The phosphorylation of glucose to glucose...Ch. 23.3 - Prob. 23.3PCh. 23.3 - Use the values for the hydrolysis of creatine...Ch. 23.4 - Prob. 23.2PPCh. 23.4 - Prob. 23.5PCh. 23.4 - Prob. 23.6PCh. 23.4 - Prob. 23.7PCh. 23.4 - Prob. 23.8P
Ch. 23.5 - Prob. 23.3PPCh. 23.5 - Prob. 23.9PCh. 23.5 - Prob. 23.10PCh. 23.5 - Prob. 23.11PCh. 23.6 - Prob. 23.12PCh. 23.6 - At several points in the electron transport chain,...Ch. 23.6 - In which region of the mitochondrion-the matrix or...Ch. 23 - Prob. 15PCh. 23 - Explain why mitochondria are called the...Ch. 23 - Prob. 17PCh. 23 - Prob. 18PCh. 23 - Prob. 19PCh. 23 - Prob. 20PCh. 23 - What are coupled reactions and why does coupling...Ch. 23 - Prob. 22PCh. 23 - Prob. 23PCh. 23 - Prob. 24PCh. 23 - Prob. 25PCh. 23 - Prob. 26PCh. 23 - Prob. 27PCh. 23 - Prob. 28PCh. 23 - Prob. 29PCh. 23 - Prob. 30PCh. 23 - Prob. 31PCh. 23 - Prob. 32PCh. 23 - (a) Draw the structure of the high-energy...Ch. 23 - Prob. 34PCh. 23 - Classify each substance as an oxidizing agent, a...Ch. 23 - Classify each substance as an oxidizing agent, a...Ch. 23 - When a substrate is oxidized, is NAD+ oxidized or...Ch. 23 - When a substrate is reduced, is FADH2 oxidized or...Ch. 23 - Prob. 39PCh. 23 - Prob. 40PCh. 23 - Prob. 41PCh. 23 - Prob. 42PCh. 23 - Prob. 43PCh. 23 - Prob. 44PCh. 23 - Prob. 45PCh. 23 - Prob. 46PCh. 23 - The conversion of isocitrate to ketoglutarate in...Ch. 23 - Prob. 48PCh. 23 - Prob. 49PCh. 23 - Prob. 50PCh. 23 - Prob. 51PCh. 23 - What is the role of each of the following in the...Ch. 23 - What is the role of each of the following in the...Ch. 23 - Prob. 54PCh. 23 - Prob. 55PCh. 23 - Prob. 56PCh. 23 - Prob. 57PCh. 23 - Prob. 58PCh. 23 - Prob. 59PCh. 23 - Prob. 60PCh. 23 - Prob. 61PCh. 23 - Prob. 62PCh. 23 - Prob. 63PCh. 23 - Prob. 64PCh. 23 - Prob. 65PCh. 23 - Prob. 66PCh. 23 - Prob. 67PCh. 23 - Prob. 68PCh. 23 - Prob. 69PCh. 23 - Prob. 70PCh. 23 - Prob. 71PCh. 23 - Prob. 72PCh. 23 - Prob. 73PCh. 23 - Prob. 74PCh. 23 - Prob. 75CPCh. 23 - Prob. 76CP
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- Draw each of the following types of block diagrams for FAD. a. Three-subunit diagram b. Six-subunit diagramarrow_forwardName and contrast the two types of modulators.arrow_forwardPredict the function of each of the following enzymes. a. Cytochrome oxidase b. Cistrans isomerase c. Succinate dehydrogenase d. Lactasearrow_forward
- Which atoms in the flavin portion of FAD are reduced to yield FADH2?arrow_forwardWhat type of specificity (absolute, group, linkage, or stereochemical) is associated with each of the following enzymes? a. Sucrase b. A lipase c. A decarboxylase d. L-glutamate oxidasearrow_forwardSome enzymes consist of protein plus another component. Which of the terms cofactor or coenzyme correctly describes each of the following nonprotein components? a. an inorganic ion b. a nonspecific component c. an organic material d. nicotinic acid.arrow_forward
- Using the attached table below, solve for the energy (delta G) produced in each step of the electron transport chain when electrons flow from FADH2 to oxygenarrow_forwardClassify the following enzymes Ptyalin Lactase Amino peptidase Creatinephosphokinase 5-alpha reductasearrow_forwardWhat is an allosteric inhibitoarrow_forward
- What statement is TRUE about the coenzyme? CH O H CC- O NAD Isocitrate Dehydrogenase NACH + H O NAD+ is the reducing agent. NAD+ gets oxidized. O NAD+ is the oxidizing agent. NAD+ gets reduced. O NAD+ is the reducing agent. NAD+ gets reduced. O NAD+ is the oxidizing agent. NAD+ gets oxidized.arrow_forwardCalculate ΔG°′ for the oxidation of free FADH2 by O2. What is the maximum number of ATPs that can be synthesized, assuming standard conditions and 100% conservation of energy?arrow_forwardNonearrow_forward
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