Quantum mechanics. In translational motion, the summation is replaced by an integral when evaluating the partition function. This is correct becausea) the spacing of the translational energy levels is very small compared to the product kTb) the spacing of the translational energy levels is comparable to the product kTc) the spacing of the translational energy levels is very large compared to the product kT

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter17: Statistical Thermodynamics: Introduction
Section: Chapter Questions
Problem 17.41E
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Quantum mechanics. In translational motion, the summation is replaced by an integral when evaluating the partition function. This is correct because
a) the spacing of the translational energy levels is very small compared to the product kT
b) the spacing of the translational energy levels is comparable to the product kT
c) the spacing of the translational energy levels is very large compared to the product kT

 

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