Which of the following statements regarding the Helmholtz function (Helmholtz free energy) are generally true? Select one or more: a. The Helmholtz function is minimized in thermodynamic equilibrium for an isolated system whose energy E, volume V and number of particles N are constant. b. The minimization of the Helmholtz function in thermodynamic equilibrium (under the right conditions) is a consequence of the minimization of the internal energy of the system. c. The minimization of the Helmholtz function in thermodynamic equilibrium is a consequence of the maximization of the total entropy of the system and the environment. d. The Helmholtz function is minimized in thermodynamic equilibrium for a closed system whose temperature T and volume V are constant.
Which of the following statements regarding the Helmholtz function (Helmholtz free energy) are generally true? Select one or more: a. The Helmholtz function is minimized in thermodynamic equilibrium for an isolated system whose energy E, volume V and number of particles N are constant. b. The minimization of the Helmholtz function in thermodynamic equilibrium (under the right conditions) is a consequence of the minimization of the internal energy of the system. c. The minimization of the Helmholtz function in thermodynamic equilibrium is a consequence of the maximization of the total entropy of the system and the environment. d. The Helmholtz function is minimized in thermodynamic equilibrium for a closed system whose temperature T and volume V are constant.
Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter2: The First Law Of Thermodynamics
Section: Chapter Questions
Problem 2.19E: What arethe differencesbetween an open, a closed, and an isolated system?Describe an example of...
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