The translational canonical partition function Qtrs of an ideal monoatomic gas is given by: 3N 2T (alnQtrs ƏT A = Justify mathematically why the translational contribution to the molar constant-volume heat capacity is: 3 Cv=3Nk - Nk Derive an expression for pressure in terms of the canonical partition function Q, and then obtain an expression for the Gibbs energy in terms of the canonical partition function Q. ibl. (id 1) D n
The translational canonical partition function Qtrs of an ideal monoatomic gas is given by: 3N 2T (alnQtrs ƏT A = Justify mathematically why the translational contribution to the molar constant-volume heat capacity is: 3 Cv=3Nk - Nk Derive an expression for pressure in terms of the canonical partition function Q, and then obtain an expression for the Gibbs energy in terms of the canonical partition function Q. ibl. (id 1) D n
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please answer all questions and please provide reasonings for using the certain equations.
Transcribed Image Text:The translational canonical partition function Qtrs of an ideal monoatomic gas is given by:
3N
alnQtrs
ƏT
V
Cy
=
Justify mathematically why the translational contribution to the molar constant-volume
heat capacity is:
= 3Nk
27
312
Nk
Derive an expression for pressure in terms of the canonical partition function Q, and
then obtain an expression for the Gibbs energy in terms of the canonical partition
function Q.
Consider the mixing of two perfectly miscible (ideal) organic solvents A and B. Calculate
their respective mole fractions needed to obtain the greatest entropy of mixing.
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