THE THERMODYNAMICS OF GASES 5. Show that the total partition function derived from equation 7.45, on the assumption that the energy of the N sub-systems is E = P+ P +P+ ... + 2m' 2m' 2m P&N PyN PEN 2m ' 2m ' 2m %3D agrees with that obtained by substituting equation 7.28 in equa- tion 7.31, i.e. VN . Z = 7.47 6. Using equation 7.3 obtain a value for log Wme in terms of the energy E and the number of systems N only. (Use must be made of the values of T and a given in Chapter 2.)

THE THERMODYNAMICS OF GASES 5. Show that the total partition function derived from equation 7.45, on the assumption that the energy of the N sub-systems is E = P+ P +P+ ... + 2m' 2m' 2m P&N PyN PEN 2m ' 2m ' 2m %3D agrees with that obtained by substituting equation 7.28 in equa- tion 7.31, i.e. VN . Z = 7.47 6. Using equation 7.3 obtain a value for log Wme in terms of the energy E and the number of systems N only. (Use must be made of the values of T and a given in Chapter 2.)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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