he lowest electronic levels for 14N 160 have the following characteristics: Calculate, for 5000 k, using statistics. A) The fraction of molecules in the 3 electronic levels B) The partition functions for the 3 electronic levels Qti, Qvib, Qrot, and the total partition function. C) The energies Eti, Evib, Etot, for the 3 electronic levels and the total energy and compare with the classical prediction. D) The fraction of molecules in the state J = 2, V = 2 of the second electronic level. Eye /cm-1 Ge wavelength/cm-1 Radius /10-10 0 2 1904.04 1.15077 43845.88 1 2374.31 1.0634 45793.78 2 1037.20 1.4167

he lowest electronic levels for 14N 160 have the following characteristics: Calculate, for 5000 k, using statistics. A) The fraction of molecules in the 3 electronic levels B) The partition functions for the 3 electronic levels Qti, Qvib, Qrot, and the total partition function. C) The energies Eti, Evib, Etot, for the 3 electronic levels and the total energy and compare with the classical prediction. D) The fraction of molecules in the state J = 2, V = 2 of the second electronic level. Eye /cm-1 Ge wavelength/cm-1 Radius /10-10 0 2 1904.04 1.15077 43845.88 1 2374.31 1.0634 45793.78 2 1037.20 1.4167

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

Derivation Calculate the entropy of HBr at 298 K and 1.00 bar, given that the bond length is 1.41 Å and the masses of ¹H and 79Br are 1.008 amu and 78.92 amu, respectively. The vibrational wavenumber is 2649 cm-¹. Step 1 of 7 Provide the equation needed to calculate the translational contribution to the total entropy. (Use the following as necessary: h, kB, m to represent the mass, P, T, and T.) (²³1) (2πmkT) h³ Strans = R In kµT (²/2) e P (2πmkBT) ³ kBT h³ P Step 2 of 7 Substitute numerical values into the equation from Step 1 to obtain a numerical calculation for the translational entropy contribution. Strans = 163.61 163.484901080763 J.K-1.mol-1 Step 3 of 7 Provide the equation needed to calculate the rotational contribution to the total entropy. (Use the following as necessary: h, I, kB, 7, σ, and T.) Srot = R In 8n²lkpT oh² + R 87² IkBT oh² Step 4 of 7 Substitute numerical values into the equation from Step 3 to obtain a numerical calculation for the rotational entropy…
Res translational degrees rotational degrees electronic energetic degrees vibrational degrees Contribution is equal to the theorem's prediction Contribution is not equal to the theorem's prediction
The NO molecule has a doubly degenerate electronic ground state and a doubly degenerate excited state at 121 cm-1. Calculate and plot the electronic contribution to the molar heat capacity of the molecule up to 400 K.
Step 1 of 7 Give the equation for the Helmholtz energy, A. (Use the following as necessary: S, T, and U.) A = U-TS U-TS Give the equation for entropy that contains the canonical partition function, Q. (Use the following as necessary: E, kB, Q, and T.) E S = kaln(Q)+ E T kB ln (Q) + 4 Step 2 of 7 We only need to consider the translational translational partition function for an ideal monatomic gas, so E = U - Uo. Combine this equation with the equations for S and A from Step 1. (Use the following as necessary: kB, Q, T, U, and Up.) A = -Tk ln(Q) + U₁ U₁ - kBT ln(Q) Step 3 of 7 Substitute the equation from Step 2 into the given equation for P and complete the partial derivative. (Use the following as necessary: KB, Q, T, U, and Up.) P = -(3x), ・ (a In (@)), · KB¹ KBT Step 4 of 7 For an ideal monatomic gas, the following is true. (Use the following as necessary: T, U, and V.) UT 0 Step 5 of 7 Give the equation for the canonical partition function Q. Remember that only the translational…
Suppose the system has two microstates: one ground state and one excited state. If, at temperature 100K, the ground state is twice more likely to realize, the energy difference between the excited microstates and the ground state is, in Joules. Multiply your answer by 1022 before entering it.
How??
2. Calculate the total molar entropy of HF at 298K. The vibrational frequency is 3960 cm-1 and the rotational constant is 20.6 cm-1.
EXERSICE 2 A system is characterized by two non-degenerate energy levels. At a temperature of 300 K, the probability of the first energy level is p₁ level p2 600 K. = 0.8 and of the second energy = 0.2. Calculate the probabilities of the two energy plants at a temperature of
Differentiate between distribution ratio (D) and partition coefficient (K,).
1. Write down the equation used to account for the variation of molar heat capacity of a material at constant pressure with temperature assuming that the temperature range is significant.
Don't give handwritten answers otherwise I will dislike
Please answer all questions and please provide reasonings for using the certain equations.