3. Using the energy data provided in table 1, please determine the AG values for the D and L enantiomers of threonine in kcal/mol. 1 Hartree (Eh) = 627.5 kcal/mol. AGEnantiomers = GL-GD 4. Using the energy data provided in table 1, please determine the AG between L- Threonine and L-Allothreonine in kcal/mol. 1 Hartree (Eh) = 627.5 kcal/mol. Is this number what you would have expected when compared to the AG value between the enantiomers of threonine? Explain. AGDiastereomers = GLThreonine-GLAllothreonine
3. Using the energy data provided in table 1, please determine the AG values for the D and L enantiomers of threonine in kcal/mol. 1 Hartree (Eh) = 627.5 kcal/mol. AGEnantiomers = GL-GD 4. Using the energy data provided in table 1, please determine the AG between L- Threonine and L-Allothreonine in kcal/mol. 1 Hartree (Eh) = 627.5 kcal/mol. Is this number what you would have expected when compared to the AG value between the enantiomers of threonine? Explain. AGDiastereomers = GLThreonine-GLAllothreonine
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Part 2: Examining the Energy Differences Between Enantiomers and Diastereomers**
3. Using the energy data provided in Table 1, please determine the ΔG values for the D and L enantiomers of threonine in kcal/mol. 1 Hartree (Eh) = 627.5 kcal/mol.
\[
\Delta G_{\text{Enantiomers}} = G_L - G_D
\]
4. Using the energy data provided in Table 1, please determine the ΔG between L-Threonine and L-Allothreonine in kcal/mol. 1 Hartree (Eh) = 627.5 kcal/mol. Is this number what you would have expected when compared to the ΔG value between the enantiomers of threonine? Explain.
\[
\Delta G_{\text{Diastereomers}} = G_{L\text{Threonine}} - G_{L\text{Allothreonine}}
\]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F09c533f0-773b-4ddb-abaf-f88b025c7ffb%2F15aa46a8-7c23-4b37-a255-ff08f91cfc82%2F7s6d6xm_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Part 2: Examining the Energy Differences Between Enantiomers and Diastereomers**
3. Using the energy data provided in Table 1, please determine the ΔG values for the D and L enantiomers of threonine in kcal/mol. 1 Hartree (Eh) = 627.5 kcal/mol.
\[
\Delta G_{\text{Enantiomers}} = G_L - G_D
\]
4. Using the energy data provided in Table 1, please determine the ΔG between L-Threonine and L-Allothreonine in kcal/mol. 1 Hartree (Eh) = 627.5 kcal/mol. Is this number what you would have expected when compared to the ΔG value between the enantiomers of threonine? Explain.
\[
\Delta G_{\text{Diastereomers}} = G_{L\text{Threonine}} - G_{L\text{Allothreonine}}
\]

Transcribed Image Text:**Table 1. Summary of Ground State Gibbs Free Energy Values for Threonine and Allothreonine**
| Species | Gibbs Free Energy, Eh |
|-------------------|------------------------|
| L-Threonine | -437.599724 |
| D-Threonine | -437.599618 |
| L-Allothreonine | -437.609162 |
| D-Allothreonine | -437.609163 |
This table provides a summary of the ground state Gibbs free energy values, measured in Eh, for four different species: L-Threonine, D-Threonine, L-Allothreonine, and D-Allothreonine. These values reflect the thermodynamic stability of each species under standard conditions.
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