(a) Interpretation: The stepwise mechanism to explain the given result is to be drawn. Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

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Answer 1

Question

Chapter 23, Problem 23.74P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism to explain the given result is to be drawn.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

Interpretation Introduction

(b)

Interpretation: The validation of the fact that optically pure isomer is obtained regardless of the amount of base used in litorene is to be stated with an explanation.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

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Use the systematic treatment of equilibrium to determine the pH and the concentrations of all species in a saturated aqueous solution of SrF2. Do not include activity coefficients. The solubility of SrF2 is governed by Ksp for the salt, hydrolysis of F- and of Sr2+, and by ion pairing between Sr2 + and F-. PK(SrF2) = 8.58, PK(HF) = 3.17, pkw = 14.00, pk for the formation of (SrOH+) = 13.18, pk for the formation of (SrF+) = 0.14 Show all your work and upload your answers here. 1 - Write the pertinent reactions. 2 - Write mass balance and charge balance equations. 3 - Write the equilibrium constant expressions. 4 - Count the equations and unknowns. 5- If the problem is solvable make suitable approximations and find the concentrations and the pH.

Answer 2

Question

Chapter 23, Problem 23.74P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism to explain the given result is to be drawn.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

Interpretation Introduction

(b)

Interpretation: The validation of the fact that optically pure isomer is obtained regardless of the amount of base used in litorene is to be stated with an explanation.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

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Answer 3

Question

Chapter 23, Problem 23.74P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism to explain the given result is to be drawn.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

Interpretation Introduction

(b)

Interpretation: The validation of the fact that optically pure isomer is obtained regardless of the amount of base used in litorene is to be stated with an explanation.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

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Answer 4

Question

Chapter 23, Problem 23.74P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism to explain the given result is to be drawn.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

Interpretation Introduction

(b)

Interpretation: The validation of the fact that optically pure isomer is obtained regardless of the amount of base used in litorene is to be stated with an explanation.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

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Answer 5

Chapter 23, Problem 23.74P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism to explain the given result is to be drawn.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

Interpretation Introduction

(b)

Interpretation: The validation of the fact that optically pure isomer is obtained regardless of the amount of base used in litorene is to be stated with an explanation.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

Answer 6

Chapter 23, Problem 23.74P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism to explain the given result is to be drawn.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

Answer 7

Chapter 23, Problem 23.74P

Interpretation Introduction

(a)

Interpretation: The stepwise mechanism to explain the given result is to be drawn.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

Answer 8

Interpretation Introduction

(b)

Interpretation: The validation of the fact that optically pure isomer is obtained regardless of the amount of base used in litorene is to be stated with an explanation.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

Answer 9

Interpretation Introduction

(b)

Interpretation: The validation of the fact that optically pure isomer is obtained regardless of the amount of base used in litorene is to be stated with an explanation.

Concept introduction: Carbonyl compounds in presence of base, loses its alpha hydrogen to form enolate. Enolates have negatively charged oxygen with adjacent carbon-carbon double bond. Enolates are resonance stabilized species.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 23 - Problem 23.1 Draw the enol or keto tautomer(s) of...Ch. 23 - Prob. 23.2P Ch. 23 - Problem 23.3 When phenylacetaldehyde is dissolved...Ch. 23 - Prob. 23.4P Ch. 23 - Problem 23.5 Which bonds in the following...Ch. 23 - Prob. 23.6P Ch. 23 - Prob. 23.7P Ch. 23 - Prob. 23.8P Ch. 23 - Prob. 23.9P Ch. 23 - Prob. 23.10P

Solution Summary: The author explains the stepwise mechanism to explain the given result. Carbonyl compounds in presence of base, lose their alpha hydrogen to form enolate.

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Chapter 23 Solutions