ORGANIC CHEMISTRY
5th Edition
ISBN: 9781259977596
Author: SMITH
Publisher: MCG
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Chapter 23, Problem 23.12P
Draw the products of each reaction. Assume excess halogen is present.
a. 
b. 
c. 
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What are the composition of the following reagents?
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d. Schiff's reagent
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B. Temperature is relatively low.
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Chapter 23 Solutions
ORGANIC CHEMISTRY
Ch. 23 - Problem 23.1 Draw the enol or keto tautomer(s) of...Ch. 23 - Prob. 23.2PCh. 23 - Problem 23.3 When phenylacetaldehyde is dissolved...Ch. 23 - Prob. 23.4PCh. 23 - Problem 23.5 Which bonds in the following...Ch. 23 - Prob. 23.6PCh. 23 - Prob. 23.7PCh. 23 - Prob. 23.8PCh. 23 - Prob. 23.9PCh. 23 - Prob. 23.10P
Ch. 23 - Problem 23.11 Draw the products of each...Ch. 23 - Problem 23.12 Draw the products of each reaction....Ch. 23 - Prob. 23.13PCh. 23 - Prob. 23.14PCh. 23 - Prob. 23.15PCh. 23 - Prob. 23.16PCh. 23 - Prob. 23.17PCh. 23 - Problem 23.18 How can pentan-2-one be converted...Ch. 23 - Problem 23.19 Identify A, B, and C, intermediates...Ch. 23 - Problem 23.20 Which of the following compounds...Ch. 23 - Problem 23.21 Draw the products of each...Ch. 23 - Prob. 23.22PCh. 23 - Prob. 23.23PCh. 23 - Prob. 23.24PCh. 23 - Prob. 23.25PCh. 23 - Prob. 23.26PCh. 23 - Prob. 23.27PCh. 23 - Prob. 23.28PCh. 23 - 23.29 Draw enol tautomer(s) for each compound....Ch. 23 - 22.30 The cis ketone A is isomerized to a trans...Ch. 23 - 23.31 Draw enol tautomer(s) for each compound.
...Ch. 23 - Prob. 23.32PCh. 23 - Prob. 23.33PCh. 23 - Prob. 23.34PCh. 23 - 23.35 Rank the labeled protons in each compound in...Ch. 23 - Prob. 23.36PCh. 23 - Prob. 23.37PCh. 23 - 23.38 Acyclovir is an effective antiviral agent...Ch. 23 - 23.39 Explain why forms two different alkylation...Ch. 23 - Prob. 23.40PCh. 23 - 23.41 Acid-catalyzed bromination of pentanone ...Ch. 23 - 23.42 Draw a stepwise mechanism for the following...Ch. 23 - Prob. 23.43PCh. 23 - Prob. 23.44PCh. 23 - 23.45 Devise a synthesis of valproic acid , a...Ch. 23 - 23.46 Synthesize each compound from diethyl...Ch. 23 - Prob. 23.47PCh. 23 - Prob. 23.48PCh. 23 - Prob. 23.49PCh. 23 - 23.50 Draw the organic products formed in each...Ch. 23 - 23.51 Draw the products formed (including...Ch. 23 - Prob. 23.52PCh. 23 - Prob. 23.53PCh. 23 - 23.54 Clopidogrel is the generic name for Plavix,...Ch. 23 - 23.55 What reaction conditions—base, solvent, and...Ch. 23 - Prob. 23.56PCh. 23 - 23.57 Draw a stepwise mechanism showing how two...Ch. 23 - 23.58 Draw a stepwise mechanism for the following...Ch. 23 - Prob. 23.59PCh. 23 - 23.60 Draw stepwise mechanisms illustrating how...Ch. 23 - Prob. 23.61PCh. 23 - Prob. 23.62PCh. 23 - 23.63 Synthesize each compound from cyclohexanone...Ch. 23 - Prob. 23.64PCh. 23 - Prob. 23.65PCh. 23 - 23.66 Synthesize (Z)-hept-5-en-2-one from ethyl...Ch. 23 - Prob. 23.67PCh. 23 - 23.68 Capsaicin, the spicy component of hot...Ch. 23 - 23.69 Treatment of W with , followed by , affords...Ch. 23 - Prob. 23.70PCh. 23 - Prob. 23.71PCh. 23 - Prob. 23.72PCh. 23 - Prob. 23.73PCh. 23 - Prob. 23.74P
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- What is the mojor product of this reaction? OTs NaOEt OEt A. OEt B. C. D.arrow_forwardClassify each reaction as oxidation, reduction, or neither.arrow_forwarda. 2. Draw the product(s) for each reaction d. b. OH a. NaH, DCM b. CH,CH₂Br OH a. PBr3, THF b. MeOH Br a. H₂O b. NaH, THF OH H₂SO4 Δarrow_forward
- 1. Draw the products of each nucleophilic substitution reaction a. b. D b OH C. d. e. f. Br 1 NaCN + NaOCH3 H₂Oarrow_forward2. What is the product(s) of the following reaction? A HN B. N A NH2 [H+] -H₂O C. D. HN 3. What is/are the product(s) of the following reaction? A. B. D [H+] -H₂O C.arrow_forwardWhat Is an Intermediate In the formation of the maļor product of this reaction? HO A. В. C. OH2 D.arrow_forward
- Draw the products of each reaction. Assume excess halogen is present.arrow_forward17. What is the missing reagent in the reaction below? aq. HCI A. CH2(COOE1)2, NaOEt C. CH2(COOE1)2, HOAC B. CH3CO2Et, NaOEt D. CH3CO,Et, HOAC 18. In several reactions of carhonyl compounds that we have studied, the reaction proceeds by carrow_forward1. For each reaction, write the letter corresponding to the type of reaction in column I and predict the MAJOR product. Draw the structure of the product in column III. A. Addition Reaction B. Electrophilic Aromatic Substitution Column I A. B. B. A. A. B. B. A. A. A. B. A. B. A. B. H₂C H3C H3C. H3C H3C H3C H3C H₂C CH3 CH3 H3C CH3 Reaction CH3 CH3 CH3 CH₂ ECH CH3 CH CH3 l CH3 CH₂ oso NH OEt CH3 CH3 orada CH3 CH3 -CH3 HNO3 H₂SO4 CH3 Br₂ DCM Br₂ hv H₂SO₂, H₂O HgSO4 Br₂ AlBr CH3 NBS hv HCI AICI Na₂Cr₂O7 H₂SO4, H₂O Br₂ FeBr H₂O* H₂ Lindlar's Catalyst 1) NaNH, 2) CH₂CH₂CH₂Br 3) H₂, Lindlar's catalyst CH3 NBS hv HNO, H₂SO4 C. Free Radical Substitution D. Redox Reaction Product (Column III)arrow_forward
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