The difference in basicity between ortho- or para- and meta-nitroanilines has to be discussed Concept Introduction : Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If the delocalization of electrons within molecules is more, the compound is less basic and vice versa. To find: para-nitroaniline is an order of magnitude less basic than meta-nitroaniline. Find the reason for the given statement Find the delocalization behavior of para-nitroaniline

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Answer 1

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Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 22, Problem 51PP

(a)

Interpretation Introduction

Interpretation: The difference in basicity between ortho- or para- and meta-nitroanilines has to be discussed

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If the delocalization of electrons within molecules is more, the compound is less basic and vice versa.

To find: para-nitroaniline is an order of magnitude less basic than meta-nitroaniline. Find the reason for the given statement

Find the delocalization behavior of para-nitroaniline

(b)

Interpretation Introduction

Interpretation: The difference in basicity between ortho- or para- and meta-nitroanilines has to be discussed

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If the delocalization of electrons within molecules is more, the compound is less basic and vice versa.

To find: Finding the basicity of ortho-nitroaniline which is closer in value to meta- or to para-nitroaniline

Find the delocalization behavior of ortho-nitroaniline

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Answer 2

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Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 22, Problem 51PP

(a)

Interpretation Introduction

Interpretation: The difference in basicity between ortho- or para- and meta-nitroanilines has to be discussed

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If the delocalization of electrons within molecules is more, the compound is less basic and vice versa.

To find: para-nitroaniline is an order of magnitude less basic than meta-nitroaniline. Find the reason for the given statement

Find the delocalization behavior of para-nitroaniline

(b)

Interpretation Introduction

Interpretation: The difference in basicity between ortho- or para- and meta-nitroanilines has to be discussed

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If the delocalization of electrons within molecules is more, the compound is less basic and vice versa.

To find: Finding the basicity of ortho-nitroaniline which is closer in value to meta- or to para-nitroaniline

Find the delocalization behavior of ortho-nitroaniline

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 22, Problem 51PP

(a)

Interpretation Introduction

Interpretation: The difference in basicity between ortho- or para- and meta-nitroanilines has to be discussed

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If the delocalization of electrons within molecules is more, the compound is less basic and vice versa.

To find: para-nitroaniline is an order of magnitude less basic than meta-nitroaniline. Find the reason for the given statement

Find the delocalization behavior of para-nitroaniline

(b)

Interpretation Introduction

Interpretation: The difference in basicity between ortho- or para- and meta-nitroanilines has to be discussed

Concept Introduction:

Resonance is a mental exercise and method within the Valence Bond Theory of bonding that describes the delocalization of electrons within molecules. The net sum of valid resonance structures is defined as a resonance hybrid, which represents the overall delocalization of electrons within the molecule. A molecule that has several resonance structures is more stable than one with fewer. If the delocalization of electrons within molecules is more, the compound is less basic and vice versa.

To find: Finding the basicity of ortho-nitroaniline which is closer in value to meta- or to para-nitroaniline

Find the delocalization behavior of ortho-nitroaniline

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Definition Definition Theory that explains how individual atomic orbitals with an unpaired electron each, come close to each other and overlap to form a molecular orbital giving a covalent bond. VBT gives a quantum mechanical approach to the formation of covalent bonds with the help of wave functions using attractive and repulsive energies when two atoms are brought from infinity to their internuclear distance.

Chapter 22, Problem 51PP

(a)

Interpretation Introduction