Procedure The stoichiometry of the reaction you will explore today is: 21¯ + S₂Ox²¯ = Iz (a) = 2 SO For the reaction between two iodides and a persulfate, a possible sequence would be the following: mechanism 1 I¯ + SO² = SO₁ +SOI SOI¯ + I = I2() + SO2 For mechanism 1, if the first step is rate determining, then the rate expression is just the rate expression for the first step. rate = K [I^] [S₂O,²] A second possible sequence is: mechanism 2 21 122 + S₂O²=12 (9) +2 SO42 If the first step is the rate determining step: rate expression for mechanism 2-a rate == K [I] [S₂O%²] ANSWERS FOR 3 and 4 Rate law of the reaction: EDEL'T 2-70.1502 Rate = k [I][S.O.²]" * (x)=1.7303, (y) = 0.8502 2. Based on your answers to 3 and 4 and the information in the procedure section, write down a mechanism consistent with your results and indicate which step is the rate determining step.

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Chapter12: Chemical Kinetics
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Procedure
The stoichiometry of the reaction you will explore today is:
21¯ + S₂Ox²¯ = Iz (a) = 2 SO
For the reaction between two iodides and a persulfate, a possible sequence would be the
following:
mechanism 1
I¯ + SO² = SO₁ +SOI
SOI¯ + I = I2() + SO2
For mechanism 1, if the first step is rate determining, then the rate expression is just the rate
expression for the first step.
rate = K [I^] [S₂O,²]
A second possible sequence is:
mechanism 2
21 122
+ S₂O²=12 (9) +2 SO42
If the first step is the rate determining step:
rate expression for mechanism 2-a
rate == K [I] [S₂O%²]
ANSWERS FOR 3 and 4
Rate law of the reaction:
EDEL'T
2-70.1502
Rate = k [I][S.O.²]" *
(x)=1.7303, (y) = 0.8502
2. Based on your answers to 3 and 4 and the information in the procedure section, write down a
mechanism consistent with your results and indicate which step is the rate determining step.
Transcribed Image Text:Procedure The stoichiometry of the reaction you will explore today is: 21¯ + S₂Ox²¯ = Iz (a) = 2 SO For the reaction between two iodides and a persulfate, a possible sequence would be the following: mechanism 1 I¯ + SO² = SO₁ +SOI SOI¯ + I = I2() + SO2 For mechanism 1, if the first step is rate determining, then the rate expression is just the rate expression for the first step. rate = K [I^] [S₂O,²] A second possible sequence is: mechanism 2 21 122 + S₂O²=12 (9) +2 SO42 If the first step is the rate determining step: rate expression for mechanism 2-a rate == K [I] [S₂O%²] ANSWERS FOR 3 and 4 Rate law of the reaction: EDEL'T 2-70.1502 Rate = k [I][S.O.²]" * (x)=1.7303, (y) = 0.8502 2. Based on your answers to 3 and 4 and the information in the procedure section, write down a mechanism consistent with your results and indicate which step is the rate determining step.
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