(a) Interpretation: The enol structure of the compound nitromethane is to be drawn. Concept introduction: In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α -hydrogen.

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Answer 1

Question

Chapter 22, Problem 22.9P

Interpretation Introduction

(a)

Interpretation:

The enol structure of the compound nitromethane is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

Interpretation Introduction

(b)

Interpretation:

The enol structure of the compound benzamide is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

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Answer 2

Question

Chapter 22, Problem 22.9P

Interpretation Introduction

(a)

Interpretation:

The enol structure of the compound nitromethane is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

Interpretation Introduction

(b)

Interpretation:

The enol structure of the compound benzamide is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

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Answer 3

Question

Chapter 22, Problem 22.9P

Interpretation Introduction

(a)

Interpretation:

The enol structure of the compound nitromethane is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

Interpretation Introduction

(b)

Interpretation:

The enol structure of the compound benzamide is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

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Answer 4

Question

Chapter 22, Problem 22.9P

Interpretation Introduction

(a)

Interpretation:

The enol structure of the compound nitromethane is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

Interpretation Introduction

(b)

Interpretation:

The enol structure of the compound benzamide is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

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Answer 5

Chapter 22, Problem 22.9P

Interpretation Introduction

(a)

Interpretation:

The enol structure of the compound nitromethane is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

Interpretation Introduction

(b)

Interpretation:

The enol structure of the compound benzamide is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

Answer 6

Chapter 22, Problem 22.9P

Interpretation Introduction

(a)

Interpretation:

The enol structure of the compound nitromethane is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

Answer 7

Chapter 22, Problem 22.9P

Interpretation Introduction

(a)

Interpretation:

The enol structure of the compound nitromethane is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The enol structure of the compound benzamide is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The enol structure of the compound benzamide is to be drawn.

Concept introduction:

In keto-enol tautomerism, the keto-enol forms of a compound are present in equilibrium with each other. Keto and enol forms both are tautomers of each other, they are inter-convertible to each other by the transfer of α-hydrogen.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author illustrates how the enol structure of the compound nitromethane is to be drawn.

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Chapter 22 Solutions