(a) Interpretation: The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn. Concept introduction: The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

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Answer 1

Question

Chapter 22, Problem 22.38P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the formation of the valproic acid from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Interpretation Introduction

(c)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

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(9 Pts) In one of the two Rare Earth element rows of the periodic table, identify an exception tothe general ionization energy (IE) trend. For the two elements involved, answer the followingquestions. Be sure to cite sources for all physical data that you use.a. (2 pts) Identify the two elements and write their electronic configurations.b. (2 pts) Based on their configurations, propose a reason for the IE trend exception.c. (5 pts) Calculate effective nuclear charges for the last electron in each element and theAllred-Rochow electronegativity values for the two elements. Can any of these valuesexplain the IE trend exception? Explain how (not) – include a description of how IErelates to electronegativity.

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Answer 2

Question

Chapter 22, Problem 22.38P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the formation of the valproic acid from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Interpretation Introduction

(c)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

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Answer 3

Question

Chapter 22, Problem 22.38P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the formation of the valproic acid from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Interpretation Introduction

(c)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

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Answer 4

Question

Chapter 22, Problem 22.38P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the formation of the valproic acid from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Interpretation Introduction

(c)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

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Answer 5

Chapter 22, Problem 22.38P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the formation of the valproic acid from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Interpretation Introduction

(c)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Answer 6

Chapter 22, Problem 22.38P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Answer 7

Chapter 22, Problem 22.38P

Interpretation Introduction

(a)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the formation of the valproic acid from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The synthesis route for the formation of the valproic acid from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The synthesis route for the formation of the given compound from either diethyl malonate or ethyl acetate is to be drawn.

Concept introduction:

The chemical reaction in which an electrophilic group is replaced by another functional group is known as the electrophilic substitution reaction. When the electrophilic substitution happens on an aromatic ring such as benzene then the reaction is known as electrophilic aromatic substitution reaction.

Answer 12

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Answer 13

Expert Solution & Answer

Answer 14

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Answer 15

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

Solution Summary: The author explains the synthesis route for the formation of valproic acid from diethyl malonate or ethlyl acetate.

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Chapter 22 Solutions