(a) Interpretation: The given reaction is to be completed and the reasoning is to be explained. Concept Introduction: The α , β -unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

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Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

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Answer the followings: 1- What is the IP for a amino acid? Give example. 2- What are the types of amino acids? 3- What are the structures of protein? 4- The N-Terminal analysis by the Edman method shows saralasin contains sarcosine at the N- terminus. Partial hydrolysis of saralasin with dilute hydrochloric acid yields the following fragments: Tyr-Val-His Sar-Arg-Val His-Pro-Ala Val-Tyr-Val Arg-Val-Tyr What is the structure of saralasin? 5. MATCH a term from the list below to each definition. Place the letter of the term in the blank to the left of the definition. a. Ligases b. Fibrous proteins c. Conjugated protein d. Hydrolases a. b. C. e. Simple protein f. Globular proteins g. Lyases h. Transferases Proteins that are tough and insoluble in water. Enzymes that catalyze the breaking away of a small molecule such as from a substrate. Enzymes that catalyze the bonding together of two substrates.

Answer the followings (Four): 1-What is the difference(s) between FOUR: a. Glyceride and phosphoglyceride. b. Wax and fat. c. Soap and fatty acid. d. HDL and LDL cholesterol e. Phospho lipids and sphingosine. 2-What are the types of lipids? 3-What are the main lipid components of membrane structures? 4-How could lipids play important rules as signaling molecules and building units? 5. The Structure variety of Lipids makes them to play significant rules in our body. Conclude briefly on this statement.

HO IV но. = HO но. HO. HO но. зад надо What is the product of the following reaction?

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

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Answer 5

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Answer 6

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Answer 7

Chapter 22, Problem 22.53P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed and the reasoning is to be explained.

Concept Introduction:

The α,β-unsaturated esters or ketones give specifically conjugate addition on reaction with the Lithium dialkylcuprate compounds. The conjugate addition reaction is promoted by the presence of copper in the reagent.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 22 - Prob. 22.1P Ch. 22 - Prob. 22.2P Ch. 22 - Prob. 22.3P Ch. 22 - Prob. 22.4P Ch. 22 - Prob. 22.5P Ch. 22 - Prob. 22.6P Ch. 22 - Prob. 22.7P Ch. 22 - Prob. 22.8P Ch. 22 - Prob. 22.9P Ch. 22 - Prob. 22.10P

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Chapter 22 Solutions