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General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Question
Chapter 22, Problem 22.53P
Interpretation Introduction
Interpretation:
The base pairs which are same in all the three settings, namely, complementary base pairing occurs between two strands of DNA, between two different sites on an RNA molecule, and between one strand of DNA and one strand of RNA should be determined.
Concept Introduction:
Complementary base pairing is the standard arrangements of bases in nucleotides which relates to their opposite pairing.
DNA molecules consist of 2 DNA strands, which bind with base pairs as below.
Adenine (A) pairs with Thymine (T).
Cytosine (C) pairs with Guanine (G).
RNA molecules consist of one RNA strand, which binds with base pairs as below.
Adenine (A) pairs with Uracil (U).
Cytosine (C) pairs with Guanine (G).
Expert Solution & Answer
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Students have asked these similar questions
Complete the following table. The only density needed is already given. Show your
calculations in a neat and easy-to-follow manner in the space below the table. All units
should be included and significant figures should be given close attention. Be sure to notice
that the amount of material should be in millimoles rather than moles, and the theoretical
mass of the product should in milligrams rather than grams.
LOCH 3
+
H2SO4
HNO 3
O=C-OCH 3
NO2
x
H₂O
F.W.
4.0 mL 1.3 M
amount
0.50 mL
in H2SO4
mg Theoretical
Theoretical
mmoles
density
1.09
Kumada Coupling:
1. m-Diisobutylbenzene below could hypothetically be synthesized by Friedel-Crafts reaction. Write out the reaction with a
mechanism and give two reasons why you would NOT get the desired product.
Draw the reaction (NOT a mechanism) for a Kumada coupling to produce the molecule above from m-dichlorobenzene.
Calculate the theoretical yield for the reaction in question 2 using 1.5 g of p-dichlorobenzene and 3.0 mL isobutyl bromide.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Wintergreen from Aspirin:
1. In isolating the salicylic acid, why is it important to press out as much of the water as possible?
2. Write the mechanism of the esterification reaction you did.
3.
What characteristic absorption band changes would you expect in the IR spectrum on going from aspirin to salicyclic acid and
then to methyl salicylate as you did in the experiment today? Give approximate wavenumbers associated with each functional
group change.
What signals appeared/disappeared/shifted that indicate that you have your intended product and not starting material? What
other impurities are present in your product and how do you know?
Chapter 22 Solutions
General, Organic, & Biological Chemistry
Ch. 22.1 - Prob. 22.1PCh. 22.1 - Prob. 22.2PCh. 22.1 - Prob. 22.3PCh. 22.1 - Prob. 22.4PCh. 22.1 - Label each statement about the compound...Ch. 22.1 - Draw the structure of each nucleotide: (a) UMP;...Ch. 22.1 - Give the name that corresponds to each...Ch. 22.2 - Draw the structure of a dinucleotide formed by...Ch. 22.2 - Draw the structure of each polynucleotide: (a) CU;...Ch. 22.2 - Label each statement about the polynucleotide...
Ch. 22.3 - Write the complementary strand for each of the...Ch. 22.4 - What is the sequence of a newly synthesized DNA...Ch. 22.6 - For each DNA segment: [1] What is the sequence of...Ch. 22.6 - Prob. 22.14PCh. 22.7 - What amino acid is coded for by each codon? GCC...Ch. 22.7 - What codons code for each amino acid? a. glycine...Ch. 22.7 - Drive the amino acid sequence that is coded for by...Ch. 22.7 - Write a possible mRNA sequence that codes for each...Ch. 22.7 - Considering the given sequence of nucleotides in...Ch. 22.8 - Prob. 22.20PCh. 22.8 - Prob. 22.21PCh. 22.8 - Prob. 22.22PCh. 22.9 - Prob. 22.23PCh. 22.9 - Prob. 22.24PCh. 22.10 - Prob. 22.25PCh. 22.11 - Prob. 22.26PCh. 22 - Label each statement as pertaining to DNA, RNA, or...Ch. 22 - Label each statement as pertaining to DNA, RNA, or...Ch. 22 - Prob. 22.29PCh. 22 - (a) Give the name of each compound shown as a...Ch. 22 - Prob. 22.31PCh. 22 - Prob. 22.32PCh. 22 - Prob. 22.33PCh. 22 - Prob. 22.34PCh. 22 - Prob. 22.35PCh. 22 - Draw the structure of each of the following: a...Ch. 22 - Prob. 22.37PCh. 22 - Prob. 22.38PCh. 22 - Prob. 22.39PCh. 22 - Prob. 22.40PCh. 22 - Prob. 22.41PCh. 22 - Draw the structures of the two possible...Ch. 22 - Prob. 22.43PCh. 22 - Draw the structure of each dinucleotide and...Ch. 22 - Draw the deoxyribonucleotide TGA. Label the 5 and...Ch. 22 - Draw the ribonucleotide CGU. Label the 5 and 3...Ch. 22 - Prob. 22.47PCh. 22 - Describe in detail the DNA double helix with...Ch. 22 - Write the sequence of the complementary strand of...Ch. 22 - Prob. 22.50PCh. 22 - Prob. 22.51PCh. 22 - Prob. 22.52PCh. 22 - Prob. 22.53PCh. 22 - Prob. 22.54PCh. 22 - Prob. 22.55PCh. 22 - Prob. 22.56PCh. 22 - Prob. 22.57PCh. 22 - Prob. 22.58PCh. 22 - Prob. 22.59PCh. 22 - Prob. 22.60PCh. 22 - Prob. 22.61PCh. 22 - What mRNA is transcribed from each DNA sequence in...Ch. 22 - Prob. 22.63PCh. 22 - Prob. 22.64PCh. 22 - For each codon, give its anticodon and the amino...Ch. 22 - Prob. 22.66PCh. 22 - Fill in the missing information in the schematic...Ch. 22 - Fill in the missing information in the schematic...Ch. 22 - Derive the amino acid sequence that is coded for...Ch. 22 - Prob. 22.70PCh. 22 - Prob. 22.71PCh. 22 - Prob. 22.72PCh. 22 - Prob. 22.73PCh. 22 - Prob. 22.74PCh. 22 - Consider the following mRNA sequence: .
a. What...Ch. 22 - Consider the following mRNA sequence:...Ch. 22 - Consider the following sequence of DNA:...Ch. 22 - Consider the following sequence of DNA: .
a. What...Ch. 22 - Prob. 22.79PCh. 22 - Prob. 22.80PCh. 22 - Prob. 22.81PCh. 22 - Prob. 22.82PCh. 22 - Prob. 22.83PCh. 22 - With reference to the gel in Problem 22.83: which...Ch. 22 - Prob. 22.85PCh. 22 - Prob. 22.86PCh. 22 - Prob. 22.87PCh. 22 - Prob. 22.88PCh. 22 - Prob. 22.89PCh. 22 - Prob. 22.90PCh. 22 - Prob. 22.91PCh. 22 - Fill in the base, codon, anticodon, or amino acid...Ch. 22 - Fill in the base, codon, anticodon, or amino acid...Ch. 22 - Fill in the base, codon, anticodon, or amino acid...Ch. 22 - Prob. 22.95PCh. 22 - If a single strand of a gene contains 678 bases,...Ch. 22 - Prob. 22.97PCh. 22 - Prob. 22.98PCh. 22 - Prob. 22.99CPCh. 22 - Prob. 22.100CP
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