Concept explainers
Give the structure corresponding to each name.
a. cyclohexyl propanoate
b. cyclohexanecarboxamide
c.
d. Vinyl acetate
e. Benzoic propanoic anhydride
f.
g. octyl butanoate
h. N, N-dibenzylformamide
(a)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is
Explanation of Solution
The given name indicates that compound contains ester (name ends with –ate) as the functional group, and propane as the longest carbon chain with one cyclohexyl substitution as
Thus, the structure corresponding to the given name is,
Figure 1
The structure corresponding to the given name is drawn in Figure 1.
(b)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains amide (name ends with -amide) as the functional group. This amide group is derived from cyclohexylcarboxylic acid, and bonded to cyclohexane ring.
Thus, the structure corresponding to given name is,
Figure 2
The structure corresponding to the given name is drawn in Figure 2.
(c)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains cyano (name ends with -nitrile) as the functional group, and heptane as the longest carbon chain with one methyl substitution at
Thus, the structure corresponding to given name is,
Figure 3
The structure corresponding to the given name is drawn in Figure 3.
(d)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains ester (name ends with -ate) as the functional group, and an acetate group is bonded to a vinyl group
Thus, the structure corresponding to the given name is,
Figure 4
The structure corresponding to the given name is drawn in Figure 4.
Interpretation: The structure corresponding to the given name is to be drawn.
(e)
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains anhydride (name ends with -anhydride) as the functional group. This anhydride compound is derived from benzoic acid and propanoic acid.
Thus, the structure corresponding to the given name is,
Figure 5
The structure corresponding to the given name is drawn in Figure 5.
Interpretation: The structure corresponding to the given name is to be drawn.
(f)
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains acid chloride (name ends with -yl chloride) as the functional group, and hexane as the longest carbon chain with one methyl substitution at
Thus, the structure corresponding to the given name is,
Figure 6
The structure corresponding to the given name is drawn in Figure 6.
Interpretation: The structure corresponding to the given name is to be drawn.
(g)
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains ester (name ends with –ate) as the functional group, and butane as the longest carbon chain with one octyl substitution as
Thus, the structure corresponding to the given name is,
Figure 7
The structure corresponding to the given name is drawn in Figure 7.
(h)
Interpretation: The structure corresponding to the given name is to be drawn.
Concept introduction: One should follow the given steps to draw the structure of a compound from its name. The first step is identification of parent name and functional group found at the end of the name. The second step is numbering of carbon skeleton in the direction, where functional group gets a lower number. The third step is addition of substituents at appropriate atoms.
Answer to Problem 22.41P
The structure corresponding to the given name is,
Explanation of Solution
The given name indicates that compound contains amide (name ends with -amide) as the functional group. This amide group is derived from formic acid, and bonded to two benzyl groups.
Thus, the structure corresponding to the given name is,
Figure 8
The structure corresponding to the given name is drawn in Figure 8.
Want to see more full solutions like this?
Chapter 22 Solutions
Package: Loose Leaf for Organic Chemistry with Biological Topics with Connect Access Card
- Draw the structure corresponding to each name. a. 3,3-dimethylpentanoic acid b. 4-chloro-3-phenylheptanoic acid c. (2R)-2-chloropropanoic acid d. B,B-dichloropropionic acid e. m-hydroxybenzoic acid f. o-chlorobenzoic acid i. 2,2-dichloropentanedioic acid j. 4-isopropyl-2-methyloctanedioic acid g. potassium acetate h. sodium a-bromobutyratearrow_forwardDraw the structure corresponding to each name.a. 5-methylheptanoyl chlorideb. isopropyl propanoatec. acetic formic anhydrided. N-isobutyl-N-methylbutanamidee. 3-methylpentanenitrilef. o-cyanobenzoic acidg. sec-butyl 2-methylhexanoateh. N-ethylhexanamidearrow_forwardDraw the structure corresponding to each name. a. 1-decanamine b. tricyclohexylamine c. p-bromoaniline d. 3-aminobutanoic acid e. N,N-dipropyl-2-octanamine f. N-ethylhexylaminearrow_forward
- 6. Draw the structure of the following compounds. a. cyclobutanecarboxylic acid b. 3,3-dimethylpentanedioic acid c. 4-aminopentanoic acid d. 2-methylcyclohexanecarboxylic acid e. m-chlorobenzoic acidarrow_forwardCyclopentanone is treated with chlorine (Cl2) in the presence of acid (H*). What product is formed? A. Chlorocyclopentane B. 1-chloro-1-hydroxycyclopentane C. 2-chlorocyclopentanone D. 3-chlorocyclopentanonearrow_forwardReduction of an alkyl azide results in the formation of —-. A. an imine B. an oxime C. a tertiary amine D. a secondary amine E. a primary aminearrow_forward
- 1. An alkene reacts with water with an acid catalyst results into a formation of: A. Aldehyde B. Ketone C. Alcohol D. Ester 2. 3-Methylhexanal with K2Cr2O7 will yield: A. 3-Methyl-1-hexanol B. 3-Methylhexanoic acid C. 3-Methyl-1-hexanone D. 3-Methyl-1-hexanethiol 3. This is a reverse process of Hydration reaction: A. Oxidation reaction B. Reduction reaction C. Dehydration reaction D. Hydration reaction 4. Acetic acid reacts with a strong base forms: A. Salt B. Water C. Salt and Water D. No reaction 5. Ketones can be further oxidized with benedict's solution into: A. Alcohol B. Aldehyde C. Catalysts D. No reactionarrow_forward1. Cite some reactions in which formaldehyde behaves differently from other aldehydes. 2. Give some biological and medical applications of: a. formalin b. chloral c. urotropinearrow_forwardон C-H ÓR Compound that contains a group like that shown above. a. acetal Ob. aldehyde c. Benedict's reagent d. carbonyl Oe. hemiacetal Of. hemiketal Og. hydrolysis h. ketal i. ketone Oj. Tollen's reagent 2.arrow_forward
- 1. Give the structure corresponding to each name. a. 4-ethyl-3-heptanol b. 3-chloro-1,2-propanediol c. diisobutyl ether d. 1,2-epoxy-1,3,3-trimethylcyclohexane e. 1-ethoxy-3-ethylheptanearrow_forward1. Which carbonyl group of the given compound is most reactive for nucleophilic addition reaction? a. All have equal reactivity b. Carbonyl Group 1 c. Carbonyl Group 2 d. Carbonyl Group 2. An aldehyde commonly exhibits a nucleophilic addition type of reaction. When a nucleophile attacks a carbonyl carbon, what happens to the oxygen atom in the structure? Refer to the structure below. ~ a. Oxygen atom becomes more electronegative. b. Oxygen atom obtains a net negative charge. c. Oxygen atom transforms to an alkoxide group. d. Oxygen atom acts as the new electrophile. 3. Assign the trivial name of the structure below. a. Diphenylketone b. Benzyl phenylketone c. Diphenyl aldehyde d. Benzyl phenyl aldehydearrow_forward2. Draw out the following compounds. a. N-methylaniline b. Triisopropylamine c. N,N-dipropylhexylamine d. 1,5-pentanediamine (Also known as Cadaverine for its smell)arrow_forward
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY