Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 21.3, Problem 6P

a)

Interpretation Introduction

Interpretation:

The systematic name of the given compound and the configuration (R or S) of each asymmetric center is to be stated.

Concept Introduction:

Carbohydrates are the polyhydroxy ketones or polyhydroxy aldehydes and they are represented by Fischer projections.  Polyhydroxy aldehydes are known as aldoses and polyhydroxy ketones are known as ketoses.

The isomer present in the clockwise direction when the highest priority group is place next to the highest priority substituent has the R configuration

The isomer present in the anticlockwise direction when the highest priority group is place next to the highest priority substituent has the S configuration

b)

Interpretation Introduction

Interpretation:

The systematic name of the given compound and the configuration ( R or S) of each asymmetric center is to be stated.

Concept Introduction:

Carbohydrates are the polyhydroxy ketones or polyhydroxy aldehydes and they are represented by Fischer projections.  Polyhydroxy aldehydes are known as aldoses and polyhydroxy ketones are known as ketoses.

The isomer present in the clockwise direction when the highest priority group is place next to the highest priority substituent has the R configuration

The isomer present in the anticlockwise direction when the highest priority group is place next to the highest priority substituent has the S configuration

c)

Interpretation Introduction

Interpretation:

The systematic name of the given compound and the configuration ( R or S) of each asymmetric center is to be stated.

Concept Introduction:

Carbohydrates are the polyhydroxy ketones or polyhydroxy aldehydes and they are represented by Fischer projections.  Polyhydroxy aldehydes are known as aldoses and polyhydroxy ketones are known as ketoses.

The isomer present in the clockwise direction when the highest priority group is place next to the highest priority substituent has the R configuration

The isomer present in the anticlockwise direction when the highest priority group is place next to the highest priority substituent has the S configuration

d)

Interpretation Introduction

Interpretation: The systematic name of the given compound and the configuration ( R or S) of each asymmetric center is to be stated.

Concept Introduction:

Carbohydrates are the polyhydroxy ketones or polyhydroxy aldehydes and they are represented by Fischer projections.  Polyhydroxy aldehydes are known as aldoses and polyhydroxy ketones are known as ketoses.

The isomer present in the clockwise direction when the highest priority group is place next to the highest priority substituent has the R configuration

The isomer present in the anticlockwise direction when the highest priority group is place next to the highest priority substituent has the S configuration

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(f) SO: Best Lewis Structure 3 e group geometry:_ shape/molecular geometry:, (g) CF2CF2 Best Lewis Structure polarity: e group arrangement:_ shape/molecular geometry: (h) (NH4)2SO4 Best Lewis Structure polarity: e group arrangement: shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles): Sketch (with angles):
1. Problem Set 3b Chem 141 For each of the following compounds draw the BEST Lewis Structure then sketch the molecule (showing bond angles). Identify (i) electron group geometry (ii) shape around EACH central atom (iii) whether the molecule is polar or non-polar (iv) (a) SeF4 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: (b) AsOBr3 Best Lewis Structure e group arrangement:_ shape/molecular geometry: polarity: Sketch (with angles): Sketch (with angles):
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