Organic Chemistry
Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 21, Problem 64P
Interpretation Introduction

Interpretation:

The mechanism for the rearrangement that converts an α-hydroxyimine to α-aminoketone in the presence of trace amount of acid has to be given.

Concept Introduction:

Keto-enol tautomerism” is defined as the rearrangement to a chemical equilibrium between a keto form and an enol.  The enol and keto forms are said to be tautomers of each other.

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d. Draw arrow-pushing mechanism for an enzymatic retro-aldol reaction of the following hexose. Use B: and/or HA as needed. OH OH سية HO OH OH
4. Calculate the wavelength of a photon needed to excite a transition between neighbouring energy levels of a harmonic oscillator of effective mass equal to that of an oxygen atom and with a force constant of 544 N m¹.
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