(a) Interpretation: The given reaction is to be completed. Concept introduction: Carboxylic acid is a class of organic compound that contains a − COOH group attached with a hydrocarbon chain. The name of these compounds ends with a suffix − o i c a c i d or − i c a c i d . The compounds possessing the molecular formula, R − CO − Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

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Answer 1

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carboxylic acid is a class of organic compound that contains a −COOH group attached with a hydrocarbon chain. The name of these compounds ends with a suffix −oic acid or −ic acid. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(e)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(f)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(g)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carbonate is a salt of carbonic acid having formula, CO32−. It decomposes on heating and releases carbon dioxide gas. It may be acidic or basic in nature. A glycol is defined as the molecule that contains two hydroxyl groups attached to different carbons. They are usually known as vicinal alcohols. Ethylene glycol is the first member of the glycol series-it is used as an antifreeze agent.

Interpretation Introduction

(h)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The organic compound phthalic anhydride is derived from phthalic acid. It is used in the formation of plasticizers. It is used as a precursor for the synthesis of phthalate ester when reacted with an alcohol. It is also used in pharmaceuticals company.

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Draw a mechanism for the following synthetic transformation including reagents and any isolable intermediates throughout the process. Please clearly indicate bond cleavage/formation using curly arrows. MeO2C

CHEM 310 Quiz 8 Organic Chemistry II Due: Tuesday, April 25th, at 11:59 pm. This quiz is open textbook / open notes - but you must work alone. You cannot use the internet or the solutions manual for the book. Scan in your work and record an explanation of your mechanism. You may record this any way that you like. One way would be to start an individual Zoom meeting, start recording, "share your screen" and then talk through the problem. This will be converted to an .mp4 file that you can upload into Canvas using the "record/upload media" feature. Pyridine, benzoic acid and benzene are dissolved in ethyl acetate. Design and provide a plan / flow chart for separating and isolating each of these components. Pyridine and benzene are liquids at room temperature. Benzoic acid is a solid. You have ethyl acetate, 2M NaOH, 2M HCI and anhydrous MgSO4 available, as well as all the glassware and equipment that you used in the organic lab this year. Provide accurate acid/base reactions for any…

Answer 2

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Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carboxylic acid is a class of organic compound that contains a −COOH group attached with a hydrocarbon chain. The name of these compounds ends with a suffix −oic acid or −ic acid. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(e)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(f)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(g)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carbonate is a salt of carbonic acid having formula, CO32−. It decomposes on heating and releases carbon dioxide gas. It may be acidic or basic in nature. A glycol is defined as the molecule that contains two hydroxyl groups attached to different carbons. They are usually known as vicinal alcohols. Ethylene glycol is the first member of the glycol series-it is used as an antifreeze agent.

Interpretation Introduction

(h)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The organic compound phthalic anhydride is derived from phthalic acid. It is used in the formation of plasticizers. It is used as a precursor for the synthesis of phthalate ester when reacted with an alcohol. It is also used in pharmaceuticals company.

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Answer 3

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carboxylic acid is a class of organic compound that contains a −COOH group attached with a hydrocarbon chain. The name of these compounds ends with a suffix −oic acid or −ic acid. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(e)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(f)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(g)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carbonate is a salt of carbonic acid having formula, CO32−. It decomposes on heating and releases carbon dioxide gas. It may be acidic or basic in nature. A glycol is defined as the molecule that contains two hydroxyl groups attached to different carbons. They are usually known as vicinal alcohols. Ethylene glycol is the first member of the glycol series-it is used as an antifreeze agent.

Interpretation Introduction

(h)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The organic compound phthalic anhydride is derived from phthalic acid. It is used in the formation of plasticizers. It is used as a precursor for the synthesis of phthalate ester when reacted with an alcohol. It is also used in pharmaceuticals company.

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Answer 4

Question

Definition Definition Class of organic compounds that contain a carboxyl group ( - COOH ) and has a general formula R - COOH or R - CO 2 H , where R refers to the alkyl, alkenyl, aryl, or other groups. They can undergo different chemical reactions, such as acid-base reactions, esterification, and oxidation. These are essential components of living organisms, playing important roles in metabolic processes, signaling, and as pharmaceuticals.

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carboxylic acid is a class of organic compound that contains a −COOH group attached with a hydrocarbon chain. The name of these compounds ends with a suffix −oic acid or −ic acid. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(e)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(f)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(g)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carbonate is a salt of carbonic acid having formula, CO32−. It decomposes on heating and releases carbon dioxide gas. It may be acidic or basic in nature. A glycol is defined as the molecule that contains two hydroxyl groups attached to different carbons. They are usually known as vicinal alcohols. Ethylene glycol is the first member of the glycol series-it is used as an antifreeze agent.

Interpretation Introduction

(h)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The organic compound phthalic anhydride is derived from phthalic acid. It is used in the formation of plasticizers. It is used as a precursor for the synthesis of phthalate ester when reacted with an alcohol. It is also used in pharmaceuticals company.

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Answer 5

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carboxylic acid is a class of organic compound that contains a −COOH group attached with a hydrocarbon chain. The name of these compounds ends with a suffix −oic acid or −ic acid. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(e)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(f)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Interpretation Introduction

(g)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carbonate is a salt of carbonic acid having formula, CO32−. It decomposes on heating and releases carbon dioxide gas. It may be acidic or basic in nature. A glycol is defined as the molecule that contains two hydroxyl groups attached to different carbons. They are usually known as vicinal alcohols. Ethylene glycol is the first member of the glycol series-it is used as an antifreeze agent.

Interpretation Introduction

(h)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The organic compound phthalic anhydride is derived from phthalic acid. It is used in the formation of plasticizers. It is used as a precursor for the synthesis of phthalate ester when reacted with an alcohol. It is also used in pharmaceuticals company.

Answer 6

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carboxylic acid is a class of organic compound that contains a −COOH group attached with a hydrocarbon chain. The name of these compounds ends with a suffix −oic acid or −ic acid. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Answer 7

Chapter 21, Problem 21.16P

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carboxylic acid is a class of organic compound that contains a −COOH group attached with a hydrocarbon chain. The name of these compounds ends with a suffix −oic acid or −ic acid. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Answer 16

Interpretation Introduction

(f)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Answer 17

Interpretation Introduction

(f)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Phosgene has a molecular formula Cl−CO−Cl. It is used to prepare plastics and it is one of the poisonous gas. The compounds possessing the molecular formula, R−CO−Cl are known as acid chloride. In acid chlorides, the reactivity is very high because of which they are used in many organic reactions. These are derivatives of carboxylic acid.

Answer 18

Interpretation Introduction

(g)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carbonate is a salt of carbonic acid having formula, CO32−. It decomposes on heating and releases carbon dioxide gas. It may be acidic or basic in nature. A glycol is defined as the molecule that contains two hydroxyl groups attached to different carbons. They are usually known as vicinal alcohols. Ethylene glycol is the first member of the glycol series-it is used as an antifreeze agent.

Answer 19

Interpretation Introduction

(g)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Carbonate is a salt of carbonic acid having formula, CO32−. It decomposes on heating and releases carbon dioxide gas. It may be acidic or basic in nature. A glycol is defined as the molecule that contains two hydroxyl groups attached to different carbons. They are usually known as vicinal alcohols. Ethylene glycol is the first member of the glycol series-it is used as an antifreeze agent.

Answer 20

Interpretation Introduction

(h)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The organic compound phthalic anhydride is derived from phthalic acid. It is used in the formation of plasticizers. It is used as a precursor for the synthesis of phthalate ester when reacted with an alcohol. It is also used in pharmaceuticals company.

Answer 21

Interpretation Introduction

(h)

Interpretation:

The given reaction is to be completed.

Concept introduction:

The organic compound phthalic anhydride is derived from phthalic acid. It is used in the formation of plasticizers. It is used as a precursor for the synthesis of phthalate ester when reacted with an alcohol. It is also used in pharmaceuticals company.

Answer 22

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Answer 23

Expert Solution & Answer

Answer 24

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Answer 25

Ch. 21 - Prob. 21.1P Ch. 21 - Prob. 21.2P Ch. 21 - Prob. 21.3P Ch. 21 - Prob. 21.4P Ch. 21 - Prob. 21.5P Ch. 21 - Prob. 21.6P Ch. 21 - Prob. 21.7P Ch. 21 - Prob. 21.8P Ch. 21 - Prob. 21.9P Ch. 21 - Prob. 21.10P

Solution Summary: The author explains that the reaction of cyclopropanoyl chloride with pyridine and ethers results in the formation of ester.

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Chapter 21 Solutions